trying...<BR><?xml version="1.0" ?>
<!DOCTYPE PubmedArticleSet PUBLIC "-//NLM//DTD PubMedArticle, 1st January 2024//EN" "https://dtd.nlm.nih.gov/ncbi/pubmed/out/pubmed_240101.dtd">
<PubmedArticleSet>
<PubmedArticle><MedlineCitation Status="PubMed-not-MEDLINE" Owner="NLM"><PMID Version="1">37218148</PMID><DateCompleted><Year>2023</Year><Month>06</Month><Day>05</Day></DateCompleted><DateRevised><Year>2023</Year><Month>06</Month><Day>05</Day></DateRevised><Article PubModel="Print-Electronic"><Journal><ISSN IssnType="Electronic">1520-510X</ISSN><JournalIssue CitedMedium="Internet"><Volume>62</Volume><Issue>22</Issue><PubDate><Year>2023</Year><Month>Jun</Month><Day>05</Day></PubDate></JournalIssue><Title>Inorganic chemistry</Title><ISOAbbreviation>Inorg Chem</ISOAbbreviation></Journal><ArticleTitle>Limitation of WO<sub>3</sub> in Zn-Co<sub>3</sub>O<sub>4</sub> Nanopolyhedra by the Pyrolysis of H<sub>3</sub>PW<sub>12</sub>O<sub>40</sub>@BMZIF: Synergistic Effect of Heterostructure and Oxygen Vacancies for Enhanced Nitrogen Fixation.</ArticleTitle><Pagination><StartPage>8710</StartPage><EndPage>8718</EndPage><MedlinePgn>8710-8718</MedlinePgn></Pagination><ELocationID EIdType="doi" ValidYN="Y">10.1021/acs.inorgchem.3c01016</ELocationID><Abstract><AbstractText>The photocatalytic nitrogen fixation process is a crucial step toward carbon neutrality and sustainable development. The combination of polyoxometalates and metal-organic frameworks is a viable method to achieve high-efficiency photocatalytic nitrogen fixation. In this work, we employed bimetallic ZIF (BMZIF) composed of Co<sup>2+</sup> and Zn<sup>2+</sup> encapsulated with H<sub>3</sub>PW<sub>12</sub>O<sub>40</sub> (PW<sub>12</sub>) as the precursor to synthesize Zn-doped Co<sub>3</sub>O<sub>4</sub> nanopolyhedra loaded with WO<sub>3</sub> nanoparticles. The NH<sub>3</sub> yield of WO<sub>3</sub>/Zn-Co<sub>3</sub>O<sub>4</sub>-2 with the best photocatalytic performance can reach 231.9 &#x3bc;mol g<sup>-1</sup> h<sup>-1</sup> under visible light, about 2.4 and 6.4 times those of pure Zn-Co<sub>3</sub>O<sub>4</sub> and WO<sub>3</sub>, respectively. The rhombic dodecahedral geometry of BMZIF is still maintained in the synthesized WO<sub>3</sub>/Zn-Co<sub>3</sub>O<sub>4</sub> nanopolyhedra, with the significant increase in the specific surface area after calcination showing better catalytic performance. At the same time, Zn doping and the formation of WO<sub>3</sub> nanoparticles result in abundant oxygen vacancies in WO<sub>3</sub>/Zn-Co<sub>3</sub>O<sub>4</sub> heterostructures. Oxygen vacancies can supply nitrogen with active sites for adsorption and activation and improve photocarriers' capacity for separation, which can greatly increase the effectiveness of the photocatalytic synthesis of ammonia. This work can easily synthesize the heterostructure based on n-type WO<sub>3</sub> nanoparticles and p-type Zn-doped Co<sub>3</sub>O<sub>4</sub> nanopolyhedra, and the beneficial combination of POMs and metal-organic framework provides new thinking for the synthesis of efficient nitrogen-fixing photocatalysts.</AbstractText></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Yang</LastName><ForeName>Xue</ForeName><Initials>X</Initials><AffiliationInfo><Affiliation>Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education, College of Chemistry, Northeast Normal University, Changchun 130024, P. R. China.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Li</LastName><ForeName>Mohan</ForeName><Initials>M</Initials><AffiliationInfo><Affiliation>Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education, College of Chemistry, Northeast Normal University, Changchun 130024, P. R. China.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Xu</LastName><ForeName>Lin</ForeName><Initials>L</Initials><Identifier Source="ORCID">0000-0002-8967-919X</Identifier><AffiliationInfo><Affiliation>Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education, College of Chemistry, Northeast Normal University, Changchun 130024, P. R. China.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Li</LastName><ForeName>Fengyan</ForeName><Initials>F</Initials><Identifier Source="ORCID">0000-0003-0167-4114</Identifier><AffiliationInfo><Affiliation>Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education, College of Chemistry, Northeast Normal University, Changchun 130024, P. R. China.</Affiliation></AffiliationInfo></Author></AuthorList><Language>eng</Language><PublicationTypeList><PublicationType UI="D016428">Journal Article</PublicationType></PublicationTypeList><ArticleDate DateType="Electronic"><Year>2023</Year><Month>05</Month><Day>22</Day></ArticleDate></Article><MedlineJournalInfo><Country>United States</Country><MedlineTA>Inorg Chem</MedlineTA><NlmUniqueID>0366543</NlmUniqueID><ISSNLinking>0020-1669</ISSNLinking></MedlineJournalInfo><CitationSubset>IM</CitationSubset></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="medline"><Year>2023</Year><Month>5</Month><Day>23</Day><Hour>6</Hour><Minute>43</Minute></PubMedPubDate><PubMedPubDate PubStatus="pubmed"><Year>2023</Year><Month>5</Month><Day>23</Day><Hour>6</Hour><Minute>42</Minute></PubMedPubDate><PubMedPubDate PubStatus="entrez"><Year>2023</Year><Month>5</Month><Day>23</Day><Hour>3</Hour><Minute>37</Minute></PubMedPubDate></History><PublicationStatus>ppublish</PublicationStatus><ArticleIdList><ArticleId IdType="pubmed">37218148</ArticleId><ArticleId IdType="doi">10.1021/acs.inorgchem.3c01016</ArticleId></ArticleIdList></PubmedData></PubmedArticle></PubmedArticleSet>trying2...<BR>trying...<BR><?xml version="1.0" encoding="UTF-8" ?>
<!DOCTYPE eSearchResult PUBLIC "-//NLM//DTD esearch 20060628//EN" "https://eutils.ncbi.nlm.nih.gov/eutils/dtd/20060628/esearch.dtd">
<eSearchResult><Count>10587</Count><RetMax>5</RetMax><RetStart>0</RetStart><QueryKey>1</QueryKey><WebEnv>MCID_676f0859c511c9a59a07d6b1</WebEnv><IdList>
<Id>39729147</Id>
<Id>39725643</Id>
<Id>39725141</Id>
<Id>39724855</Id>
<Id>39722789</Id>
</IdList><TranslationSet><Translation>     <From>oxygen</From>     <To>"cell respiration"[MeSH Terms] OR ("cell"[All Fields] AND "respiration"[All Fields]) OR "cell respiration"[All Fields] OR "oxygenation"[All Fields] OR "oxygen"[MeSH Terms] OR "oxygen"[All Fields] OR "oxygen's"[All Fields] OR "oxygenate"[All Fields] OR "oxygenated"[All Fields] OR "oxygenates"[All Fields] OR "oxygenating"[All Fields] OR "oxygenations"[All Fields] OR "oxygenative"[All Fields] OR "oxygenator's"[All Fields] OR "oxygenators"[MeSH Terms] OR "oxygenators"[All Fields] OR "oxygenator"[All Fields] OR "oxygene"[All Fields] OR "oxygenic"[All Fields] OR "oxygenous"[All Fields] OR "oxygens"[All Fields]</To>    </Translation><Translation>     <From>vacancies</From>     <To>"vacancies"[All Fields] OR "vacancy"[All Fields]</To>    </Translation></TranslationSet><QueryTranslation>("cell respiration"[MeSH Terms] OR ("cell"[All Fields] AND "respiration"[All Fields]) OR "cell respiration"[All Fields] OR "oxygenation"[All Fields] OR "oxygen"[MeSH Terms] OR "oxygen"[All Fields] OR "oxygen s"[All Fields] OR "oxygenate"[All Fields] OR "oxygenated"[All Fields] OR "oxygenates"[All Fields] OR "oxygenating"[All Fields] OR "oxygenations"[All Fields] OR "oxygenative"[All Fields] OR "oxygenator s"[All Fields] OR "oxygenators"[MeSH Terms] OR "oxygenators"[All Fields] OR "oxygenator"[All Fields] OR "oxygene"[All Fields] OR "oxygenic"[All Fields] OR "oxygenous"[All Fields] OR "oxygens"[All Fields]) AND ("vacancies"[All Fields] OR "vacancy"[All Fields])</QueryTranslation></eSearchResult>
trying2...<BR>trying...<BR>trying2...<BR>

<!DOCTYPE html>
  <html dir="ltr" lang="en">
  <head>
    <!-- Google tag (gtag.js) -->
    <script async src="https://www.googletagmanager.com/gtag/js?id=G-442WFVFXCC"></script>
    <script>
      window.dataLayer = window.dataLayer || [];
      function gtag(){dataLayer.push(arguments);}
      gtag('js', new Date());
    
      gtag('config', 'G-442WFVFXCC');
    </script>
  <meta charset="utf-8">
  <meta http-equiv="X-UA-Compatible" content="IE=edge"><script type="text/javascript">(window.NREUM||(NREUM={})).init={privacy:{cookies_enabled:true},ajax:{deny_list:["bam.nr-data.net"]},distributed_tracing:{enabled:true}};(window.NREUM||(NREUM={})).loader_config={agentID:"601503912",accountID:"4767844",trustKey:"4767844",xpid:"UAEBVl5XDBAFXFhUBAEPVFI=",licenseKey:"NRJS-750ae8097b9f1344f1a",applicationID:"589630826"};;/*! For license information please see nr-loader-spa-1.277.0.min.js.LICENSE.txt */
(()=>{var e,t,r={8122:(e,t,r)=>{"use strict";r.d(t,{a:()=>i});var n=r(944);function i(e,t){try{if(!e||"object"!=typeof e)return(0,n.R)(3);if(!t||"object"!=typeof t)return(0,n.R)(4);const r=Object.create(Object.getPrototypeOf(t),Object.getOwnPropertyDescriptors(t)),o=0===Object.keys(r).length?e:r;for(let a in o)if(void 0!==e[a])try{if(null===e[a]){r[a]=null;continue}Array.isArray(e[a])&&Array.isArray(t[a])?r[a]=Array.from(new Set([...e[a],...t[a]])):"object"==typeof e[a]&&"object"==typeof t[a]?r[a]=i(e[a],t[a]):r[a]=e[a]}catch(e){(0,n.R)(1,e)}return r}catch(e){(0,n.R)(2,e)}}},2555:(e,t,r)=>{"use strict";r.d(t,{Vp:()=>c,fn:()=>s,x1:()=>u});var n=r(384),i=r(8122);const o={beacon:n.NT.beacon,errorBeacon:n.NT.errorBeacon,licenseKey:void 0,applicationID:void 0,sa:void 0,queueTime:void 0,applicationTime:void 0,ttGuid:void 0,user:void 0,account:void 0,product:void 0,extra:void 0,jsAttributes:{},userAttributes:void 0,atts:void 0,transactionName:void 0,tNamePlain:void 0},a={};function s(e){try{const t=c(e);return!!t.licenseKey&&!!t.errorBeacon&&!!t.applicationID}catch(e){return!1}}function c(e){if(!e)throw new Error("All info objects require an agent identifier!");if(!a[e])throw new Error("Info for ".concat(e," was never set"));return a[e]}function u(e,t){if(!e)throw new Error("All info objects require an agent identifier!");a[e]=(0,i.a)(t,o);const r=(0,n.nY)(e);r&&(r.info=a[e])}},9417:(e,t,r)=>{"use strict";r.d(t,{D0:()=>p,gD:()=>m,xN:()=>g});var n=r(3333),i=r(993);const o=e=>{if(!e||"string"!=typeof e)return!1;try{document.createDocumentFragment().querySelector(e)}catch{return!1}return!0};var a=r(2614),s=r(944),c=r(384),u=r(8122);const d="[data-nr-mask]",l=()=>{const e={feature_flags:[],experimental:{marks:!1,measures:!1,resources:!1},mask_selector:"*",block_selector:"[data-nr-block]",mask_input_options:{color:!1,date:!1,"datetime-local":!1,email:!1,month:!1,number:!1,range:!1,search:!1,tel:!1,text:!1,time:!1,url:!1,week:!1,textarea:!1,select:!1,password:!0}};return{ajax:{deny_list:void 0,block_internal:!0,enabled:!0,harvestTimeSeconds:10,autoStart:!0},distributed_tracing:{enabled:void 0,exclude_newrelic_header:void 0,cors_use_newrelic_header:void 0,cors_use_tracecontext_headers:void 0,allowed_origins:void 0},get feature_flags(){return e.feature_flags},set feature_flags(t){e.feature_flags=t},generic_events:{enabled:!0,harvestTimeSeconds:30,autoStart:!0},harvest:{tooManyRequestsDelay:60},jserrors:{enabled:!0,harvestTimeSeconds:10,autoStart:!0},logging:{enabled:!0,harvestTimeSeconds:10,autoStart:!0,level:i.p_.INFO},metrics:{enabled:!0,autoStart:!0},obfuscate:void 0,page_action:{enabled:!0},page_view_event:{enabled:!0,autoStart:!0},page_view_timing:{enabled:!0,harvestTimeSeconds:30,autoStart:!0},performance:{get capture_marks(){return e.feature_flags.includes(n.$v.MARKS)||e.experimental.marks},set capture_marks(t){e.experimental.marks=t},get capture_measures(){return e.feature_flags.includes(n.$v.MEASURES)||e.experimental.measures},set capture_measures(t){e.experimental.measures=t},resources:{get enabled(){return e.feature_flags.includes(n.$v.RESOURCES)||e.experimental.resources},set enabled(t){e.experimental.resources=t},asset_types:[],first_party_domains:[],ignore_newrelic:!0}},privacy:{cookies_enabled:!0},proxy:{assets:void 0,beacon:void 0},session:{expiresMs:a.wk,inactiveMs:a.BB},session_replay:{autoStart:!0,enabled:!1,harvestTimeSeconds:60,preload:!1,sampling_rate:10,error_sampling_rate:100,collect_fonts:!1,inline_images:!1,fix_stylesheets:!0,mask_all_inputs:!0,get mask_text_selector(){return e.mask_selector},set mask_text_selector(t){o(t)?e.mask_selector="".concat(t,",").concat(d):""===t||null===t?e.mask_selector=d:(0,s.R)(5,t)},get block_class(){return"nr-block"},get ignore_class(){return"nr-ignore"},get mask_text_class(){return"nr-mask"},get block_selector(){return e.block_selector},set block_selector(t){o(t)?e.block_selector+=",".concat(t):""!==t&&(0,s.R)(6,t)},get mask_input_options(){return e.mask_input_options},set mask_input_options(t){t&&"object"==typeof t?e.mask_input_options={...t,password:!0}:(0,s.R)(7,t)}},session_trace:{enabled:!0,harvestTimeSeconds:10,autoStart:!0},soft_navigations:{enabled:!0,harvestTimeSeconds:10,autoStart:!0},spa:{enabled:!0,harvestTimeSeconds:10,autoStart:!0},ssl:void 0,user_actions:{enabled:!0}}},f={},h="All configuration objects require an agent identifier!";function p(e){if(!e)throw new Error(h);if(!f[e])throw new Error("Configuration for ".concat(e," was never set"));return f[e]}function g(e,t){if(!e)throw new Error(h);f[e]=(0,u.a)(t,l());const r=(0,c.nY)(e);r&&(r.init=f[e])}function m(e,t){if(!e)throw new Error(h);var r=p(e);if(r){for(var n=t.split("."),i=0;i<n.length-1;i++)if("object"!=typeof(r=r[n[i]]))return;r=r[n[n.length-1]]}return r}},5603:(e,t,r)=>{"use strict";r.d(t,{a:()=>c,o:()=>s});var n=r(384),i=r(8122);const o={accountID:void 0,trustKey:void 0,agentID:void 0,licenseKey:void 0,applicationID:void 0,xpid:void 0},a={};function s(e){if(!e)throw new Error("All loader-config objects require an agent identifier!");if(!a[e])throw new Error("LoaderConfig for ".concat(e," was never set"));return a[e]}function c(e,t){if(!e)throw new Error("All loader-config objects require an agent identifier!");a[e]=(0,i.a)(t,o);const r=(0,n.nY)(e);r&&(r.loader_config=a[e])}},3371:(e,t,r)=>{"use strict";r.d(t,{V:()=>f,f:()=>l});var n=r(8122),i=r(384),o=r(6154),a=r(9324);let s=0;const c={buildEnv:a.F3,distMethod:a.Xs,version:a.xv,originTime:o.WN},u={customTransaction:void 0,disabled:!1,isolatedBacklog:!1,loaderType:void 0,maxBytes:3e4,onerror:void 0,ptid:void 0,releaseIds:{},appMetadata:{},session:void 0,denyList:void 0,timeKeeper:void 0,obfuscator:void 0},d={};function l(e){if(!e)throw new Error("All runtime objects require an agent identifier!");if(!d[e])throw new Error("Runtime for ".concat(e," was never set"));return d[e]}function f(e,t){if(!e)throw new Error("All runtime objects require an agent identifier!");d[e]={...(0,n.a)(t,u),...c},Object.hasOwnProperty.call(d[e],"harvestCount")||Object.defineProperty(d[e],"harvestCount",{get:()=>++s});const r=(0,i.nY)(e);r&&(r.runtime=d[e])}},9324:(e,t,r)=>{"use strict";r.d(t,{F3:()=>i,Xs:()=>o,Yq:()=>a,xv:()=>n});const n="1.277.0",i="PROD",o="CDN",a="^2.0.0-alpha.17"},6154:(e,t,r)=>{"use strict";r.d(t,{A4:()=>s,OF:()=>d,RI:()=>i,WN:()=>h,bv:()=>o,gm:()=>a,lR:()=>f,m:()=>u,mw:()=>c,sb:()=>l});var n=r(1863);const i="undefined"!=typeof window&&!!window.document,o="undefined"!=typeof WorkerGlobalScope&&("undefined"!=typeof self&&self instanceof WorkerGlobalScope&&self.navigator instanceof WorkerNavigator||"undefined"!=typeof globalThis&&globalThis instanceof WorkerGlobalScope&&globalThis.navigator instanceof WorkerNavigator),a=i?window:"undefined"!=typeof WorkerGlobalScope&&("undefined"!=typeof self&&self instanceof WorkerGlobalScope&&self||"undefined"!=typeof globalThis&&globalThis instanceof WorkerGlobalScope&&globalThis),s="complete"===a?.document?.readyState,c=Boolean("hidden"===a?.document?.visibilityState),u=""+a?.location,d=/iPad|iPhone|iPod/.test(a.navigator?.userAgent),l=d&&"undefined"==typeof SharedWorker,f=(()=>{const e=a.navigator?.userAgent?.match(/Firefox[/\s](\d+\.\d+)/);return Array.isArray(e)&&e.length>=2?+e[1]:0})(),h=Date.now()-(0,n.t)()},7295:(e,t,r)=>{"use strict";r.d(t,{Xv:()=>a,gX:()=>i,iW:()=>o});var n=[];function i(e){if(!e||o(e))return!1;if(0===n.length)return!0;for(var t=0;t<n.length;t++){var r=n[t];if("*"===r.hostname)return!1;if(s(r.hostname,e.hostname)&&c(r.pathname,e.pathname))return!1}return!0}function o(e){return void 0===e.hostname}function a(e){if(n=[],e&&e.length)for(var t=0;t<e.length;t++){let r=e[t];if(!r)continue;0===r.indexOf("http://")?r=r.substring(7):0===r.indexOf("https://")&&(r=r.substring(8));const i=r.indexOf("/");let o,a;i>0?(o=r.substring(0,i),a=r.substring(i)):(o=r,a="");let[s]=o.split(":");n.push({hostname:s,pathname:a})}}function s(e,t){return!(e.length>t.length)&&t.indexOf(e)===t.length-e.length}function c(e,t){return 0===e.indexOf("/")&&(e=e.substring(1)),0===t.indexOf("/")&&(t=t.substring(1)),""===e||e===t}},1687:(e,t,r)=>{"use strict";r.d(t,{Ak:()=>c,Ze:()=>l,x3:()=>u});var n=r(7836),i=r(3606),o=r(860),a=r(2646);const s={};function c(e,t){const r={staged:!1,priority:o.P3[t]||0};d(e),s[e].get(t)||s[e].set(t,r)}function u(e,t){e&&s[e]&&(s[e].get(t)&&s[e].delete(t),h(e,t,!1),s[e].size&&f(e))}function d(e){if(!e)throw new Error("agentIdentifier required");s[e]||(s[e]=new Map)}function l(e="",t="feature",r=!1){if(d(e),!e||!s[e].get(t)||r)return h(e,t);s[e].get(t).staged=!0,f(e)}function f(e){const t=Array.from(s[e]);t.every((([e,t])=>t.staged))&&(t.sort(((e,t)=>e[1].priority-t[1].priority)),t.forEach((([t])=>{s[e].delete(t),h(e,t)})))}function h(e,t,r=!0){const o=e?n.ee.get(e):n.ee,s=i.i.handlers;if(!o.aborted&&o.backlog&&s){if(r){const e=o.backlog[t],r=s[t];if(r){for(let t=0;e&&t<e.length;++t)p(e[t],r);Object.entries(r).forEach((([e,t])=>{Object.values(t||{}).forEach((t=>{t[0]?.on&&t[0]?.context()instanceof a.y&&t[0].on(e,t[1])}))}))}}o.isolatedBacklog||delete s[t],o.backlog[t]=null,o.emit("drain-"+t,[])}}function p(e,t){var r=e[1];Object.values(t[r]||{}).forEach((t=>{var r=e[0];if(t[0]===r){var n=t[1],i=e[3],o=e[2];n.apply(i,o)}}))}},7836:(e,t,r)=>{"use strict";r.d(t,{P:()=>c,ee:()=>u});var n=r(384),i=r(8990),o=r(3371),a=r(2646),s=r(5607);const c="nr@context:".concat(s.W),u=function e(t,r){var n={},s={},d={},l=!1;try{l=16===r.length&&(0,o.f)(r).isolatedBacklog}catch(e){}var f={on:p,addEventListener:p,removeEventListener:function(e,t){var r=n[e];if(!r)return;for(var i=0;i<r.length;i++)r[i]===t&&r.splice(i,1)},emit:function(e,r,n,i,o){!1!==o&&(o=!0);if(u.aborted&&!i)return;t&&o&&t.emit(e,r,n);for(var a=h(n),c=g(e),d=c.length,l=0;l<d;l++)c[l].apply(a,r);var p=v()[s[e]];p&&p.push([f,e,r,a]);return a},get:m,listeners:g,context:h,buffer:function(e,t){const r=v();if(t=t||"feature",f.aborted)return;Object.entries(e||{}).forEach((([e,n])=>{s[n]=t,t in r||(r[t]=[])}))},abort:function(){f._aborted=!0,Object.keys(f.backlog).forEach((e=>{delete f.backlog[e]}))},isBuffering:function(e){return!!v()[s[e]]},debugId:r,backlog:l?{}:t&&"object"==typeof t.backlog?t.backlog:{},isolatedBacklog:l};return Object.defineProperty(f,"aborted",{get:()=>{let e=f._aborted||!1;return e||(t&&(e=t.aborted),e)}}),f;function h(e){return e&&e instanceof a.y?e:e?(0,i.I)(e,c,(()=>new a.y(c))):new a.y(c)}function p(e,t){n[e]=g(e).concat(t)}function g(e){return n[e]||[]}function m(t){return d[t]=d[t]||e(f,t)}function v(){return f.backlog}}(void 0,"globalEE"),d=(0,n.Zm)();d.ee||(d.ee=u)},2646:(e,t,r)=>{"use strict";r.d(t,{y:()=>n});class n{constructor(e){this.contextId=e}}},9908:(e,t,r)=>{"use strict";r.d(t,{d:()=>n,p:()=>i});var n=r(7836).ee.get("handle");function i(e,t,r,i,o){o?(o.buffer([e],i),o.emit(e,t,r)):(n.buffer([e],i),n.emit(e,t,r))}},3606:(e,t,r)=>{"use strict";r.d(t,{i:()=>o});var n=r(9908);o.on=a;var i=o.handlers={};function o(e,t,r,o){a(o||n.d,i,e,t,r)}function a(e,t,r,i,o){o||(o="feature"),e||(e=n.d);var a=t[o]=t[o]||{};(a[r]=a[r]||[]).push([e,i])}},3878:(e,t,r)=>{"use strict";function n(e,t){return{capture:e,passive:!1,signal:t}}function i(e,t,r=!1,i){window.addEventListener(e,t,n(r,i))}function o(e,t,r=!1,i){document.addEventListener(e,t,n(r,i))}r.d(t,{DD:()=>o,jT:()=>n,sp:()=>i})},5607:(e,t,r)=>{"use strict";r.d(t,{W:()=>n});const n=(0,r(9566).bz)()},9566:(e,t,r)=>{"use strict";r.d(t,{LA:()=>s,ZF:()=>c,bz:()=>a,el:()=>u});var n=r(6154);const i="xxxxxxxx-xxxx-4xxx-yxxx-xxxxxxxxxxxx";function o(e,t){return e?15&e[t]:16*Math.random()|0}function a(){const e=n.gm?.crypto||n.gm?.msCrypto;let t,r=0;return e&&e.getRandomValues&&(t=e.getRandomValues(new Uint8Array(30))),i.split("").map((e=>"x"===e?o(t,r++).toString(16):"y"===e?(3&o()|8).toString(16):e)).join("")}function s(e){const t=n.gm?.crypto||n.gm?.msCrypto;let r,i=0;t&&t.getRandomValues&&(r=t.getRandomValues(new Uint8Array(e)));const a=[];for(var s=0;s<e;s++)a.push(o(r,i++).toString(16));return a.join("")}function c(){return s(16)}function u(){return s(32)}},2614:(e,t,r)=>{"use strict";r.d(t,{BB:()=>a,H3:()=>n,g:()=>u,iL:()=>c,tS:()=>s,uh:()=>i,wk:()=>o});const n="NRBA",i="SESSION",o=144e5,a=18e5,s={STARTED:"session-started",PAUSE:"session-pause",RESET:"session-reset",RESUME:"session-resume",UPDATE:"session-update"},c={SAME_TAB:"same-tab",CROSS_TAB:"cross-tab"},u={OFF:0,FULL:1,ERROR:2}},1863:(e,t,r)=>{"use strict";function n(){return Math.floor(performance.now())}r.d(t,{t:()=>n})},7485:(e,t,r)=>{"use strict";r.d(t,{D:()=>i});var n=r(6154);function i(e){if(0===(e||"").indexOf("data:"))return{protocol:"data"};try{const t=new URL(e,location.href),r={port:t.port,hostname:t.hostname,pathname:t.pathname,search:t.search,protocol:t.protocol.slice(0,t.protocol.indexOf(":")),sameOrigin:t.protocol===n.gm?.location?.protocol&&t.host===n.gm?.location?.host};return r.port&&""!==r.port||("http:"===t.protocol&&(r.port="80"),"https:"===t.protocol&&(r.port="443")),r.pathname&&""!==r.pathname?r.pathname.startsWith("/")||(r.pathname="/".concat(r.pathname)):r.pathname="/",r}catch(e){return{}}}},944:(e,t,r)=>{"use strict";function n(e,t){"function"==typeof console.debug&&console.debug("New Relic Warning: https://github.com/newrelic/newrelic-browser-agent/blob/main/docs/warning-codes.md#".concat(e),t)}r.d(t,{R:()=>n})},5284:(e,t,r)=>{"use strict";r.d(t,{t:()=>c,B:()=>s});var n=r(7836),i=r(6154);const o="newrelic";const a=new Set,s={};function c(e,t){const r=n.ee.get(t);s[t]??={},e&&"object"==typeof e&&(a.has(t)||(r.emit("rumresp",[e]),s[t]=e,a.add(t),function(e={}){try{i.gm.dispatchEvent(new CustomEvent(o,{detail:e}))}catch(e){}}({loaded:!0})))}},8990:(e,t,r)=>{"use strict";r.d(t,{I:()=>i});var n=Object.prototype.hasOwnProperty;function i(e,t,r){if(n.call(e,t))return e[t];var i=r();if(Object.defineProperty&&Object.keys)try{return Object.defineProperty(e,t,{value:i,writable:!0,enumerable:!1}),i}catch(e){}return e[t]=i,i}},6389:(e,t,r)=>{"use strict";function n(e,t=500,r={}){const n=r?.leading||!1;let i;return(...r)=>{n&&void 0===i&&(e.apply(this,r),i=setTimeout((()=>{i=clearTimeout(i)}),t)),n||(clearTimeout(i),i=setTimeout((()=>{e.apply(this,r)}),t))}}function i(e){let t=!1;return(...r)=>{t||(t=!0,e.apply(this,r))}}r.d(t,{J:()=>i,s:()=>n})},3304:(e,t,r)=>{"use strict";r.d(t,{A:()=>o});var n=r(7836);const i=()=>{const e=new WeakSet;return(t,r)=>{if("object"==typeof r&&null!==r){if(e.has(r))return;e.add(r)}return r}};function o(e){try{return JSON.stringify(e,i())??""}catch(e){try{n.ee.emit("internal-error",[e])}catch(e){}return""}}},5289:(e,t,r)=>{"use strict";r.d(t,{GG:()=>o,sB:()=>a});var n=r(3878);function i(){return"undefined"==typeof document||"complete"===document.readyState}function o(e,t){if(i())return e();(0,n.sp)("load",e,t)}function a(e){if(i())return e();(0,n.DD)("DOMContentLoaded",e)}},384:(e,t,r)=>{"use strict";r.d(t,{NT:()=>o,US:()=>d,Zm:()=>a,bQ:()=>c,dV:()=>s,nY:()=>u,pV:()=>l});var n=r(6154),i=r(1863);const o={beacon:"bam.nr-data.net",errorBeacon:"bam.nr-data.net"};function a(){return n.gm.NREUM||(n.gm.NREUM={}),void 0===n.gm.newrelic&&(n.gm.newrelic=n.gm.NREUM),n.gm.NREUM}function s(){let e=a();return e.o||(e.o={ST:n.gm.setTimeout,SI:n.gm.setImmediate,CT:n.gm.clearTimeout,XHR:n.gm.XMLHttpRequest,REQ:n.gm.Request,EV:n.gm.Event,PR:n.gm.Promise,MO:n.gm.MutationObserver,FETCH:n.gm.fetch,WS:n.gm.WebSocket}),e}function c(e,t){let r=a();r.initializedAgents??={},t.initializedAt={ms:(0,i.t)(),date:new Date},r.initializedAgents[e]=t}function u(e){let t=a();return t.initializedAgents?.[e]}function d(e,t){a()[e]=t}function l(){return function(){let e=a();const t=e.info||{};e.info={beacon:o.beacon,errorBeacon:o.errorBeacon,...t}}(),function(){let e=a();const t=e.init||{};e.init={...t}}(),s(),function(){let e=a();const t=e.loader_config||{};e.loader_config={...t}}(),a()}},2843:(e,t,r)=>{"use strict";r.d(t,{u:()=>i});var n=r(3878);function i(e,t=!1,r,i){(0,n.DD)("visibilitychange",(function(){if(t)return void("hidden"===document.visibilityState&&e());e(document.visibilityState)}),r,i)}},8139:(e,t,r)=>{"use strict";r.d(t,{u:()=>f});var n=r(7836),i=r(3434),o=r(8990),a=r(6154);const s={},c=a.gm.XMLHttpRequest,u="addEventListener",d="removeEventListener",l="nr@wrapped:".concat(n.P);function f(e){var t=function(e){return(e||n.ee).get("events")}(e);if(s[t.debugId]++)return t;s[t.debugId]=1;var r=(0,i.YM)(t,!0);function f(e){r.inPlace(e,[u,d],"-",p)}function p(e,t){return e[1]}return"getPrototypeOf"in Object&&(a.RI&&h(document,f),c&&h(c.prototype,f),h(a.gm,f)),t.on(u+"-start",(function(e,t){var n=e[1];if(null!==n&&("function"==typeof n||"object"==typeof n)){var i=(0,o.I)(n,l,(function(){var e={object:function(){if("function"!=typeof n.handleEvent)return;return n.handleEvent.apply(n,arguments)},function:n}[typeof n];return e?r(e,"fn-",null,e.name||"anonymous"):n}));this.wrapped=e[1]=i}})),t.on(d+"-start",(function(e){e[1]=this.wrapped||e[1]})),t}function h(e,t,...r){let n=e;for(;"object"==typeof n&&!Object.prototype.hasOwnProperty.call(n,u);)n=Object.getPrototypeOf(n);n&&t(n,...r)}},3434:(e,t,r)=>{"use strict";r.d(t,{Jt:()=>o,YM:()=>c});var n=r(7836),i=r(5607);const o="nr@original:".concat(i.W);var a=Object.prototype.hasOwnProperty,s=!1;function c(e,t){return e||(e=n.ee),r.inPlace=function(e,t,n,i,o){n||(n="");const a="-"===n.charAt(0);for(let s=0;s<t.length;s++){const c=t[s],u=e[c];d(u)||(e[c]=r(u,a?c+n:n,i,c,o))}},r.flag=o,r;function r(t,r,n,s,c){return d(t)?t:(r||(r=""),nrWrapper[o]=t,function(e,t,r){if(Object.defineProperty&&Object.keys)try{return Object.keys(e).forEach((function(r){Object.defineProperty(t,r,{get:function(){return e[r]},set:function(t){return e[r]=t,t}})})),t}catch(e){u([e],r)}for(var n in e)a.call(e,n)&&(t[n]=e[n])}(t,nrWrapper,e),nrWrapper);function nrWrapper(){var o,a,d,l;try{a=this,o=[...arguments],d="function"==typeof n?n(o,a):n||{}}catch(t){u([t,"",[o,a,s],d],e)}i(r+"start",[o,a,s],d,c);try{return l=t.apply(a,o)}catch(e){throw i(r+"err",[o,a,e],d,c),e}finally{i(r+"end",[o,a,l],d,c)}}}function i(r,n,i,o){if(!s||t){var a=s;s=!0;try{e.emit(r,n,i,t,o)}catch(t){u([t,r,n,i],e)}s=a}}}function u(e,t){t||(t=n.ee);try{t.emit("internal-error",e)}catch(e){}}function d(e){return!(e&&"function"==typeof e&&e.apply&&!e[o])}},9300:(e,t,r)=>{"use strict";r.d(t,{T:()=>n});const n=r(860).K7.ajax},3333:(e,t,r)=>{"use strict";r.d(t,{$v:()=>u,TZ:()=>n,Zp:()=>i,kd:()=>c,mq:()=>s,nf:()=>a,qN:()=>o});const n=r(860).K7.genericEvents,i=["auxclick","click","copy","keydown","paste","scrollend"],o=["focus","blur"],a=4,s=1e3,c=["PageAction","UserAction","BrowserPerformance"],u={MARKS:"experimental.marks",MEASURES:"experimental.measures",RESOURCES:"experimental.resources"}},6774:(e,t,r)=>{"use strict";r.d(t,{T:()=>n});const n=r(860).K7.jserrors},993:(e,t,r)=>{"use strict";r.d(t,{ET:()=>o,TZ:()=>a,p_:()=>i});var n=r(860);const i={ERROR:"ERROR",WARN:"WARN",INFO:"INFO",DEBUG:"DEBUG",TRACE:"TRACE"},o="log",a=n.K7.logging},3785:(e,t,r)=>{"use strict";r.d(t,{R:()=>c,b:()=>u});var n=r(9908),i=r(1863),o=r(860),a=r(3969),s=r(993);function c(e,t,r={},c=s.p_.INFO){(0,n.p)(a.xV,["API/logging/".concat(c.toLowerCase(),"/called")],void 0,o.K7.metrics,e),(0,n.p)(s.ET,[(0,i.t)(),t,r,c],void 0,o.K7.logging,e)}function u(e){return"string"==typeof e&&Object.values(s.p_).some((t=>t===e.toUpperCase().trim()))}},3969:(e,t,r)=>{"use strict";r.d(t,{TZ:()=>n,XG:()=>s,rs:()=>i,xV:()=>a,z_:()=>o});const n=r(860).K7.metrics,i="sm",o="cm",a="storeSupportabilityMetrics",s="storeEventMetrics"},6630:(e,t,r)=>{"use strict";r.d(t,{T:()=>n});const n=r(860).K7.pageViewEvent},782:(e,t,r)=>{"use strict";r.d(t,{T:()=>n});const n=r(860).K7.pageViewTiming},6344:(e,t,r)=>{"use strict";r.d(t,{BB:()=>d,G4:()=>o,Qb:()=>l,TZ:()=>i,Ug:()=>a,_s:()=>s,bc:()=>u,yP:()=>c});var n=r(2614);const i=r(860).K7.sessionReplay,o={RECORD:"recordReplay",PAUSE:"pauseReplay",REPLAY_RUNNING:"replayRunning",ERROR_DURING_REPLAY:"errorDuringReplay"},a=.12,s={DomContentLoaded:0,Load:1,FullSnapshot:2,IncrementalSnapshot:3,Meta:4,Custom:5},c={[n.g.ERROR]:15e3,[n.g.FULL]:3e5,[n.g.OFF]:0},u={RESET:{message:"Session was reset",sm:"Reset"},IMPORT:{message:"Recorder failed to import",sm:"Import"},TOO_MANY:{message:"429: Too Many Requests",sm:"Too-Many"},TOO_BIG:{message:"Payload was too large",sm:"Too-Big"},CROSS_TAB:{message:"Session Entity was set to OFF on another tab",sm:"Cross-Tab"},ENTITLEMENTS:{message:"Session Replay is not allowed and will not be started",sm:"Entitlement"}},d=5e3,l={API:"api"}},5270:(e,t,r)=>{"use strict";r.d(t,{Aw:()=>c,CT:()=>u,SR:()=>s});var n=r(384),i=r(9417),o=r(7767),a=r(6154);function s(e){return!!(0,n.dV)().o.MO&&(0,o.V)(e)&&!0===(0,i.gD)(e,"session_trace.enabled")}function c(e){return!0===(0,i.gD)(e,"session_replay.preload")&&s(e)}function u(e,t){const r=t.correctAbsoluteTimestamp(e);return{originalTimestamp:e,correctedTimestamp:r,timestampDiff:e-r,originTime:a.WN,correctedOriginTime:t.correctedOriginTime,originTimeDiff:Math.floor(a.WN-t.correctedOriginTime)}}},3738:(e,t,r)=>{"use strict";r.d(t,{He:()=>i,Kp:()=>s,Lc:()=>u,Rz:()=>d,TZ:()=>n,bD:()=>o,d3:()=>a,jx:()=>l,uP:()=>c});const n=r(860).K7.sessionTrace,i="bstResource",o="resource",a="-start",s="-end",c="fn"+a,u="fn"+s,d="pushState",l=1e3},3962:(e,t,r)=>{"use strict";r.d(t,{AM:()=>o,O2:()=>c,Qu:()=>u,TZ:()=>s,ih:()=>d,pP:()=>a,tC:()=>i});var n=r(860);const i=["click","keydown","submit","popstate"],o="api",a="initialPageLoad",s=n.K7.softNav,c={INITIAL_PAGE_LOAD:"",ROUTE_CHANGE:1,UNSPECIFIED:2},u={INTERACTION:1,AJAX:2,CUSTOM_END:3,CUSTOM_TRACER:4},d={IP:"in progress",FIN:"finished",CAN:"cancelled"}},7378:(e,t,r)=>{"use strict";r.d(t,{$p:()=>x,BR:()=>b,Kp:()=>R,L3:()=>y,Lc:()=>c,NC:()=>o,SG:()=>d,TZ:()=>i,U6:()=>p,UT:()=>m,d3:()=>w,dT:()=>f,e5:()=>E,gx:()=>v,l9:()=>l,oW:()=>h,op:()=>g,rw:()=>u,tH:()=>A,uP:()=>s,wW:()=>T,xq:()=>a});var n=r(384);const i=r(860).K7.spa,o=["click","submit","keypress","keydown","keyup","change"],a=999,s="fn-start",c="fn-end",u="cb-start",d="api-ixn-",l="remaining",f="interaction",h="spaNode",p="jsonpNode",g="fetch-start",m="fetch-done",v="fetch-body-",b="jsonp-end",y=(0,n.dV)().o.ST,w="-start",R="-end",x="-body",T="cb"+R,E="jsTime",A="fetch"},4234:(e,t,r)=>{"use strict";r.d(t,{W:()=>o});var n=r(7836),i=r(1687);class o{constructor(e,t){this.agentIdentifier=e,this.ee=n.ee.get(e),this.featureName=t,this.blocked=!1}deregisterDrain(){(0,i.x3)(this.agentIdentifier,this.featureName)}}},7767:(e,t,r)=>{"use strict";r.d(t,{V:()=>o});var n=r(9417),i=r(6154);const o=e=>i.RI&&!0===(0,n.gD)(e,"privacy.cookies_enabled")},425:(e,t,r)=>{"use strict";r.d(t,{j:()=>j});var n=r(860),i=r(2555),o=r(3371),a=r(9908),s=r(7836),c=r(1687),u=r(5289),d=r(6154),l=r(944),f=r(3969),h=r(384),p=r(6344);const g=["setErrorHandler","finished","addToTrace","addRelease","recordCustomEvent","addPageAction","setCurrentRouteName","setPageViewName","setCustomAttribute","interaction","noticeError","setUserId","setApplicationVersion","start",p.G4.RECORD,p.G4.PAUSE,"log","wrapLogger"],m=["setErrorHandler","finished","addToTrace","addRelease"];var v=r(1863),b=r(2614),y=r(993),w=r(3785),R=r(2646),x=r(3434);const T=new Map;function E(e,t,r,n){if("object"!=typeof t||!t||"string"!=typeof r||!r||"function"!=typeof t[r])return(0,l.R)(29);const i=function(e){return(e||s.ee).get("logger")}(e),o=(0,x.YM)(i),a=new R.y(s.P);a.level=n.level,a.customAttributes=n.customAttributes;const c=t[r]?.[x.Jt]||t[r];return T.set(c,a),o.inPlace(t,[r],"wrap-logger-",(()=>T.get(c))),i}function A(){const e=(0,h.pV)();g.forEach((t=>{e[t]=(...r)=>function(t,...r){let n=[];return Object.values(e.initializedAgents).forEach((e=>{e&&e.api?e.exposed&&e.api[t]&&n.push(e.api[t](...r)):(0,l.R)(38,t)})),n.length>1?n:n[0]}(t,...r)}))}const S={};var N=r(9417),_=r(5603),O=r(5284);const I=e=>{const t=e.startsWith("http");e+="/",r.p=t?e:"https://"+e};let P=!1;function j(e,t={},g,R){let{init:x,info:T,loader_config:j,runtime:C={},exposed:k=!0}=t;C.loaderType=g;const L=(0,h.pV)();T||(x=L.init,T=L.info,j=L.loader_config),(0,N.xN)(e.agentIdentifier,x||{}),(0,_.a)(e.agentIdentifier,j||{}),T.jsAttributes??={},d.bv&&(T.jsAttributes.isWorker=!0),(0,i.x1)(e.agentIdentifier,T);const H=(0,N.D0)(e.agentIdentifier),M=[T.beacon,T.errorBeacon];P||(H.proxy.assets&&(I(H.proxy.assets),M.push(H.proxy.assets)),H.proxy.beacon&&M.push(H.proxy.beacon),A(),(0,h.US)("activatedFeatures",O.B),e.runSoftNavOverSpa&&=!0===H.soft_navigations.enabled&&H.feature_flags.includes("soft_nav")),C.denyList=[...H.ajax.deny_list||[],...H.ajax.block_internal?M:[]],C.ptid=e.agentIdentifier,(0,o.V)(e.agentIdentifier,C),e.ee=s.ee.get(e.agentIdentifier),void 0===e.api&&(e.api=function(e,t,h=!1){t||(0,c.Ak)(e,"api");const g={};var R=s.ee.get(e),x=R.get("tracer");S[e]=b.g.OFF,R.on(p.G4.REPLAY_RUNNING,(t=>{S[e]=t}));var T="api-",A=T+"ixn-";function N(t,r,n,o){const a=(0,i.Vp)(e);return null===r?delete a.jsAttributes[t]:(0,i.x1)(e,{...a,jsAttributes:{...a.jsAttributes,[t]:r}}),I(T,n,!0,o||null===r?"session":void 0)(t,r)}function _(){}g.log=function(e,{customAttributes:t={},level:r=y.p_.INFO}={}){(0,a.p)(f.xV,["API/log/called"],void 0,n.K7.metrics,R),(0,w.R)(R,e,t,r)},g.wrapLogger=(e,t,{customAttributes:r={},level:i=y.p_.INFO}={})=>{(0,a.p)(f.xV,["API/wrapLogger/called"],void 0,n.K7.metrics,R),E(R,e,t,{customAttributes:r,level:i})},m.forEach((e=>{g[e]=I(T,e,!0,"api")})),g.addPageAction=I(T,"addPageAction",!0,n.K7.genericEvents),g.recordCustomEvent=I(T,"recordCustomEvent",!0,n.K7.genericEvents),g.setPageViewName=function(t,r){if("string"==typeof t)return"/"!==t.charAt(0)&&(t="/"+t),(0,o.f)(e).customTransaction=(r||"http://custom.transaction")+t,I(T,"setPageViewName",!0)()},g.setCustomAttribute=function(e,t,r=!1){if("string"==typeof e){if(["string","number","boolean"].includes(typeof t)||null===t)return N(e,t,"setCustomAttribute",r);(0,l.R)(40,typeof t)}else(0,l.R)(39,typeof e)},g.setUserId=function(e){if("string"==typeof e||null===e)return N("enduser.id",e,"setUserId",!0);(0,l.R)(41,typeof e)},g.setApplicationVersion=function(e){if("string"==typeof e||null===e)return N("application.version",e,"setApplicationVersion",!1);(0,l.R)(42,typeof e)},g.start=()=>{try{(0,a.p)(f.xV,["API/start/called"],void 0,n.K7.metrics,R),R.emit("manual-start-all")}catch(e){(0,l.R)(23,e)}},g[p.G4.RECORD]=function(){(0,a.p)(f.xV,["API/recordReplay/called"],void 0,n.K7.metrics,R),(0,a.p)(p.G4.RECORD,[],void 0,n.K7.sessionReplay,R)},g[p.G4.PAUSE]=function(){(0,a.p)(f.xV,["API/pauseReplay/called"],void 0,n.K7.metrics,R),(0,a.p)(p.G4.PAUSE,[],void 0,n.K7.sessionReplay,R)},g.interaction=function(e){return(new _).get("object"==typeof e?e:{})};const O=_.prototype={createTracer:function(e,t){var r={},i=this,o="function"==typeof t;return(0,a.p)(f.xV,["API/createTracer/called"],void 0,n.K7.metrics,R),h||(0,a.p)(A+"tracer",[(0,v.t)(),e,r],i,n.K7.spa,R),function(){if(x.emit((o?"":"no-")+"fn-start",[(0,v.t)(),i,o],r),o)try{return t.apply(this,arguments)}catch(e){const t="string"==typeof e?new Error(e):e;throw x.emit("fn-err",[arguments,this,t],r),t}finally{x.emit("fn-end",[(0,v.t)()],r)}}}};function I(e,t,r,i){return function(){return(0,a.p)(f.xV,["API/"+t+"/called"],void 0,n.K7.metrics,R),i&&(0,a.p)(e+t,[r?(0,v.t)():performance.now(),...arguments],r?null:this,i,R),r?void 0:this}}function P(){r.e(478).then(r.bind(r,8778)).then((({setAPI:t})=>{t(e),(0,c.Ze)(e,"api")})).catch((e=>{(0,l.R)(27,e),R.abort()}))}return["actionText","setName","setAttribute","save","ignore","onEnd","getContext","end","get"].forEach((e=>{O[e]=I(A,e,void 0,h?n.K7.softNav:n.K7.spa)})),g.setCurrentRouteName=h?I(A,"routeName",void 0,n.K7.softNav):I(T,"routeName",!0,n.K7.spa),g.noticeError=function(t,r){"string"==typeof t&&(t=new Error(t)),(0,a.p)(f.xV,["API/noticeError/called"],void 0,n.K7.metrics,R),(0,a.p)("err",[t,(0,v.t)(),!1,r,!!S[e]],void 0,n.K7.jserrors,R)},d.RI?(0,u.GG)((()=>P()),!0):P(),g}(e.agentIdentifier,R,e.runSoftNavOverSpa)),void 0===e.exposed&&(e.exposed=k),P=!0}},8374:(e,t,r)=>{r.nc=(()=>{try{return document?.currentScript?.nonce}catch(e){}return""})()},860:(e,t,r)=>{"use strict";r.d(t,{$J:()=>o,K7:()=>n,P3:()=>i});const n={ajax:"ajax",genericEvents:"generic_events",jserrors:"jserrors",logging:"logging",metrics:"metrics",pageAction:"page_action",pageViewEvent:"page_view_event",pageViewTiming:"page_view_timing",sessionReplay:"session_replay",sessionTrace:"session_trace",softNav:"soft_navigations",spa:"spa"},i={[n.pageViewEvent]:1,[n.pageViewTiming]:2,[n.metrics]:3,[n.jserrors]:4,[n.spa]:5,[n.ajax]:6,[n.sessionTrace]:7,[n.softNav]:8,[n.sessionReplay]:9,[n.logging]:10,[n.genericEvents]:11},o={[n.pageViewTiming]:"events",[n.ajax]:"events",[n.spa]:"events",[n.softNav]:"events",[n.metrics]:"jserrors",[n.jserrors]:"jserrors",[n.sessionTrace]:"browser/blobs",[n.sessionReplay]:"browser/blobs",[n.logging]:"browser/logs",[n.genericEvents]:"ins"}}},n={};function i(e){var t=n[e];if(void 0!==t)return t.exports;var o=n[e]={exports:{}};return r[e](o,o.exports,i),o.exports}i.m=r,i.d=(e,t)=>{for(var r in t)i.o(t,r)&&!i.o(e,r)&&Object.defineProperty(e,r,{enumerable:!0,get:t[r]})},i.f={},i.e=e=>Promise.all(Object.keys(i.f).reduce(((t,r)=>(i.f[r](e,t),t)),[])),i.u=e=>({212:"nr-spa-compressor",249:"nr-spa-recorder",478:"nr-spa"}[e]+"-1.277.0.min.js"),i.o=(e,t)=>Object.prototype.hasOwnProperty.call(e,t),e={},t="NRBA-1.277.0.PROD:",i.l=(r,n,o,a)=>{if(e[r])e[r].push(n);else{var s,c;if(void 0!==o)for(var u=document.getElementsByTagName("script"),d=0;d<u.length;d++){var l=u[d];if(l.getAttribute("src")==r||l.getAttribute("data-webpack")==t+o){s=l;break}}if(!s){c=!0;var f={478:"sha512-AgX6f6qOxyV4l/Fg8saiNsK37oY3qvFRTOkwua+LDBTL7KUv+eoUSnunEaP3OvjJ1ZiSn43xQyjf9TWbqq8FVQ==",249:"sha512-43TwsElpnwfBCx+EERv4zX5fDsbQLB0w+NTEOt/flpNK9wKjMch+SQIUgLVqaF8jJt5qUeNPsDi/Zk+jgt3SLw==",212:"sha512-/Y+2vKPi087MH5FY89Cw9ahyQ2qnbVj7M2MganYRhmEg4Xos9v/cFPZviY2a1m17D9zpXkOtPsycYXk2AV0huA=="};(s=document.createElement("script")).charset="utf-8",s.timeout=120,i.nc&&s.setAttribute("nonce",i.nc),s.setAttribute("data-webpack",t+o),s.src=r,0!==s.src.indexOf(window.location.origin+"/")&&(s.crossOrigin="anonymous"),f[a]&&(s.integrity=f[a])}e[r]=[n];var h=(t,n)=>{s.onerror=s.onload=null,clearTimeout(p);var i=e[r];if(delete e[r],s.parentNode&&s.parentNode.removeChild(s),i&&i.forEach((e=>e(n))),t)return t(n)},p=setTimeout(h.bind(null,void 0,{type:"timeout",target:s}),12e4);s.onerror=h.bind(null,s.onerror),s.onload=h.bind(null,s.onload),c&&document.head.appendChild(s)}},i.r=e=>{"undefined"!=typeof Symbol&&Symbol.toStringTag&&Object.defineProperty(e,Symbol.toStringTag,{value:"Module"}),Object.defineProperty(e,"__esModule",{value:!0})},i.p="https://js-agent.newrelic.com/",(()=>{var e={38:0,788:0};i.f.j=(t,r)=>{var n=i.o(e,t)?e[t]:void 0;if(0!==n)if(n)r.push(n[2]);else{var o=new Promise(((r,i)=>n=e[t]=[r,i]));r.push(n[2]=o);var a=i.p+i.u(t),s=new Error;i.l(a,(r=>{if(i.o(e,t)&&(0!==(n=e[t])&&(e[t]=void 0),n)){var o=r&&("load"===r.type?"missing":r.type),a=r&&r.target&&r.target.src;s.message="Loading chunk "+t+" failed.\n("+o+": "+a+")",s.name="ChunkLoadError",s.type=o,s.request=a,n[1](s)}}),"chunk-"+t,t)}};var t=(t,r)=>{var n,o,[a,s,c]=r,u=0;if(a.some((t=>0!==e[t]))){for(n in s)i.o(s,n)&&(i.m[n]=s[n]);if(c)c(i)}for(t&&t(r);u<a.length;u++)o=a[u],i.o(e,o)&&e[o]&&e[o][0](),e[o]=0},r=self["webpackChunk:NRBA-1.277.0.PROD"]=self["webpackChunk:NRBA-1.277.0.PROD"]||[];r.forEach(t.bind(null,0)),r.push=t.bind(null,r.push.bind(r))})(),(()=>{"use strict";i(8374);var e=i(944),t=i(6344),r=i(9566);class n{agentIdentifier;constructor(e=(0,r.LA)(16)){this.agentIdentifier=e}#e(t,...r){if("function"==typeof this.api?.[t])return this.api[t](...r);(0,e.R)(35,t)}addPageAction(e,t){return this.#e("addPageAction",e,t)}recordCustomEvent(e,t){return this.#e("recordCustomEvent",e,t)}setPageViewName(e,t){return this.#e("setPageViewName",e,t)}setCustomAttribute(e,t,r){return this.#e("setCustomAttribute",e,t,r)}noticeError(e,t){return this.#e("noticeError",e,t)}setUserId(e){return this.#e("setUserId",e)}setApplicationVersion(e){return this.#e("setApplicationVersion",e)}setErrorHandler(e){return this.#e("setErrorHandler",e)}addRelease(e,t){return this.#e("addRelease",e,t)}log(e,t){return this.#e("log",e,t)}}class o extends n{#e(t,...r){if("function"==typeof this.api?.[t])return this.api[t](...r);(0,e.R)(35,t)}start(){return this.#e("start")}finished(e){return this.#e("finished",e)}recordReplay(){return this.#e(t.G4.RECORD)}pauseReplay(){return this.#e(t.G4.PAUSE)}addToTrace(e){return this.#e("addToTrace",e)}setCurrentRouteName(e){return this.#e("setCurrentRouteName",e)}interaction(){return this.#e("interaction")}wrapLogger(e,t,r){return this.#e("wrapLogger",e,t,r)}}var a=i(860),s=i(9417);const c=Object.values(a.K7);function u(e){const t={};return c.forEach((r=>{t[r]=function(e,t){return!0===(0,s.gD)(t,"".concat(e,".enabled"))}(r,e)})),t}var d=i(425);var l=i(1687),f=i(4234),h=i(5289),p=i(6154),g=i(5270),m=i(7767),v=i(6389);class b extends f.W{constructor(e,t,r=!0){super(e.agentIdentifier,t),this.auto=r,this.abortHandler=void 0,this.featAggregate=void 0,this.onAggregateImported=void 0,!1===e.init[this.featureName].autoStart&&(this.auto=!1),this.auto?(0,l.Ak)(e.agentIdentifier,t):this.ee.on("manual-start-all",(0,v.J)((()=>{(0,l.Ak)(e.agentIdentifier,this.featureName),this.auto=!0,this.importAggregator(e)})))}importAggregator(t,r={}){if(this.featAggregate||!this.auto)return;let n;this.onAggregateImported=new Promise((e=>{n=e}));const o=async()=>{let o;try{if((0,m.V)(this.agentIdentifier)){const{setupAgentSession:e}=await i.e(478).then(i.bind(i,6526));o=e(t)}}catch(t){(0,e.R)(20,t),this.ee.emit("internal-error",[t]),this.featureName===a.K7.sessionReplay&&this.abortHandler?.()}try{if(t.sharedAggregator)await t.sharedAggregator;else{t.sharedAggregator=i.e(478).then(i.bind(i,9337));const{EventAggregator:e}=await t.sharedAggregator;t.sharedAggregator=new e}if(!this.#t(this.featureName,o))return(0,l.Ze)(this.agentIdentifier,this.featureName),void n(!1);const{lazyFeatureLoader:e}=await i.e(478).then(i.bind(i,6103)),{Aggregate:a}=await e(this.featureName,"aggregate");this.featAggregate=new a(t,r),n(!0)}catch(t){(0,e.R)(34,t),this.abortHandler?.(),(0,l.Ze)(this.agentIdentifier,this.featureName,!0),n(!1),this.ee&&this.ee.abort()}};p.RI?(0,h.GG)((()=>o()),!0):o()}#t(e,t){switch(e){case a.K7.sessionReplay:return(0,g.SR)(this.agentIdentifier)&&!!t;case a.K7.sessionTrace:return!!t;default:return!0}}}var y=i(6630);class w extends b{static featureName=y.T;constructor(e,t=!0){super(e,y.T,t),this.importAggregator(e)}}var R=i(384);var x=i(9908),T=i(2843),E=i(3878),A=i(782),S=i(1863);class N extends b{static featureName=A.T;constructor(e,t=!0){super(e,A.T,t),p.RI&&((0,T.u)((()=>(0,x.p)("docHidden",[(0,S.t)()],void 0,A.T,this.ee)),!0),(0,E.sp)("pagehide",(()=>(0,x.p)("winPagehide",[(0,S.t)()],void 0,A.T,this.ee))),this.importAggregator(e))}}var _=i(3969);class O extends b{static featureName=_.TZ;constructor(e,t=!0){super(e,_.TZ,t),this.importAggregator(e)}}var I=i(6774),P=i(3304);class j{constructor(e,t,r,n,i){this.name="UncaughtError",this.message="string"==typeof e?e:(0,P.A)(e),this.sourceURL=t,this.line=r,this.column=n,this.__newrelic=i}}function C(e){return H(e)?e:new j(void 0!==e?.message?e.message:e,e?.filename||e?.sourceURL,e?.lineno||e?.line,e?.colno||e?.col,e?.__newrelic)}function k(e){const t="Unhandled Promise Rejection";if(!e?.reason)return;if(H(e.reason))try{return e.reason.message=t+": "+e.reason.message,C(e.reason)}catch(t){return C(e.reason)}const r=C(e.reason);return r.message=t+": "+r?.message,r}function L(e){if(e.error instanceof SyntaxError&&!/:\d+$/.test(e.error.stack?.trim())){const t=new j(e.message,e.filename,e.lineno,e.colno,e.error.__newrelic);return t.name=SyntaxError.name,t}return H(e.error)?e.error:C(e)}function H(e){return e instanceof Error&&!!e.stack}class M extends b{static featureName=I.T;#r=!1;constructor(e,r=!0){super(e,I.T,r);try{this.removeOnAbort=new AbortController}catch(e){}this.ee.on("internal-error",((e,t)=>{this.abortHandler&&(0,x.p)("ierr",[C(e),(0,S.t)(),!0,{},this.#r,t],void 0,this.featureName,this.ee)})),this.ee.on(t.G4.REPLAY_RUNNING,(e=>{this.#r=e})),p.gm.addEventListener("unhandledrejection",(e=>{this.abortHandler&&(0,x.p)("err",[k(e),(0,S.t)(),!1,{unhandledPromiseRejection:1},this.#r],void 0,this.featureName,this.ee)}),(0,E.jT)(!1,this.removeOnAbort?.signal)),p.gm.addEventListener("error",(e=>{this.abortHandler&&(0,x.p)("err",[L(e),(0,S.t)(),!1,{},this.#r],void 0,this.featureName,this.ee)}),(0,E.jT)(!1,this.removeOnAbort?.signal)),this.abortHandler=this.#n,this.importAggregator(e)}#n(){this.removeOnAbort?.abort(),this.abortHandler=void 0}}var D=i(8990);let K=1;const U="nr@id";function V(e){const t=typeof e;return!e||"object"!==t&&"function"!==t?-1:e===p.gm?0:(0,D.I)(e,U,(function(){return K++}))}function G(e){if("string"==typeof e&&e.length)return e.length;if("object"==typeof e){if("undefined"!=typeof ArrayBuffer&&e instanceof ArrayBuffer&&e.byteLength)return e.byteLength;if("undefined"!=typeof Blob&&e instanceof Blob&&e.size)return e.size;if(!("undefined"!=typeof FormData&&e instanceof FormData))try{return(0,P.A)(e).length}catch(e){return}}}var F=i(8139),B=i(7836),W=i(3434);const z={},q=["open","send"];function Z(t){var r=t||B.ee;const n=function(e){return(e||B.ee).get("xhr")}(r);if(void 0===p.gm.XMLHttpRequest)return n;if(z[n.debugId]++)return n;z[n.debugId]=1,(0,F.u)(r);var i=(0,W.YM)(n),o=p.gm.XMLHttpRequest,a=p.gm.MutationObserver,s=p.gm.Promise,c=p.gm.setInterval,u="readystatechange",d=["onload","onerror","onabort","onloadstart","onloadend","onprogress","ontimeout"],l=[],f=p.gm.XMLHttpRequest=function(t){const r=new o(t),a=n.context(r);try{n.emit("new-xhr",[r],a),r.addEventListener(u,(s=a,function(){var e=this;e.readyState>3&&!s.resolved&&(s.resolved=!0,n.emit("xhr-resolved",[],e)),i.inPlace(e,d,"fn-",y)}),(0,E.jT)(!1))}catch(t){(0,e.R)(15,t);try{n.emit("internal-error",[t])}catch(e){}}var s;return r};function h(e,t){i.inPlace(t,["onreadystatechange"],"fn-",y)}if(function(e,t){for(var r in e)t[r]=e[r]}(o,f),f.prototype=o.prototype,i.inPlace(f.prototype,q,"-xhr-",y),n.on("send-xhr-start",(function(e,t){h(e,t),function(e){l.push(e),a&&(g?g.then(b):c?c(b):(m=-m,v.data=m))}(t)})),n.on("open-xhr-start",h),a){var g=s&&s.resolve();if(!c&&!s){var m=1,v=document.createTextNode(m);new a(b).observe(v,{characterData:!0})}}else r.on("fn-end",(function(e){e[0]&&e[0].type===u||b()}));function b(){for(var e=0;e<l.length;e++)h(0,l[e]);l.length&&(l=[])}function y(e,t){return t}return n}var Y="fetch-",X=Y+"body-",J=["arrayBuffer","blob","json","text","formData"],Q=p.gm.Request,ee=p.gm.Response,te="prototype";const re={};function ne(e){const t=function(e){return(e||B.ee).get("fetch")}(e);if(!(Q&&ee&&p.gm.fetch))return t;if(re[t.debugId]++)return t;function r(e,r,n){var i=e[r];"function"==typeof i&&(e[r]=function(){var e,r=[...arguments],o={};t.emit(n+"before-start",[r],o),o[B.P]&&o[B.P].dt&&(e=o[B.P].dt);var a=i.apply(this,r);return t.emit(n+"start",[r,e],a),a.then((function(e){return t.emit(n+"end",[null,e],a),e}),(function(e){throw t.emit(n+"end",[e],a),e}))})}return re[t.debugId]=1,J.forEach((e=>{r(Q[te],e,X),r(ee[te],e,X)})),r(p.gm,"fetch",Y),t.on(Y+"end",(function(e,r){var n=this;if(r){var i=r.headers.get("content-length");null!==i&&(n.rxSize=i),t.emit(Y+"done",[null,r],n)}else t.emit(Y+"done",[e],n)})),t}var ie=i(7485),oe=i(5603);class ae{constructor(e){this.agentIdentifier=e}generateTracePayload(e){if(!this.shouldGenerateTrace(e))return null;var t=(0,oe.o)(this.agentIdentifier);if(!t)return null;var n=(t.accountID||"").toString()||null,i=(t.agentID||"").toString()||null,o=(t.trustKey||"").toString()||null;if(!n||!i)return null;var a=(0,r.ZF)(),s=(0,r.el)(),c=Date.now(),u={spanId:a,traceId:s,timestamp:c};return(e.sameOrigin||this.isAllowedOrigin(e)&&this.useTraceContextHeadersForCors())&&(u.traceContextParentHeader=this.generateTraceContextParentHeader(a,s),u.traceContextStateHeader=this.generateTraceContextStateHeader(a,c,n,i,o)),(e.sameOrigin&&!this.excludeNewrelicHeader()||!e.sameOrigin&&this.isAllowedOrigin(e)&&this.useNewrelicHeaderForCors())&&(u.newrelicHeader=this.generateTraceHeader(a,s,c,n,i,o)),u}generateTraceContextParentHeader(e,t){return"00-"+t+"-"+e+"-01"}generateTraceContextStateHeader(e,t,r,n,i){return i+"@nr=0-1-"+r+"-"+n+"-"+e+"----"+t}generateTraceHeader(e,t,r,n,i,o){if(!("function"==typeof p.gm?.btoa))return null;var a={v:[0,1],d:{ty:"Browser",ac:n,ap:i,id:e,tr:t,ti:r}};return o&&n!==o&&(a.d.tk=o),btoa((0,P.A)(a))}shouldGenerateTrace(e){return this.isDtEnabled()&&this.isAllowedOrigin(e)}isAllowedOrigin(e){var t=!1,r={};if((0,s.gD)(this.agentIdentifier,"distributed_tracing")&&(r=(0,s.D0)(this.agentIdentifier).distributed_tracing),e.sameOrigin)t=!0;else if(r.allowed_origins instanceof Array)for(var n=0;n<r.allowed_origins.length;n++){var i=(0,ie.D)(r.allowed_origins[n]);if(e.hostname===i.hostname&&e.protocol===i.protocol&&e.port===i.port){t=!0;break}}return t}isDtEnabled(){var e=(0,s.gD)(this.agentIdentifier,"distributed_tracing");return!!e&&!!e.enabled}excludeNewrelicHeader(){var e=(0,s.gD)(this.agentIdentifier,"distributed_tracing");return!!e&&!!e.exclude_newrelic_header}useNewrelicHeaderForCors(){var e=(0,s.gD)(this.agentIdentifier,"distributed_tracing");return!!e&&!1!==e.cors_use_newrelic_header}useTraceContextHeadersForCors(){var e=(0,s.gD)(this.agentIdentifier,"distributed_tracing");return!!e&&!!e.cors_use_tracecontext_headers}}var se=i(9300),ce=i(7295),ue=["load","error","abort","timeout"],de=ue.length,le=(0,R.dV)().o.REQ,fe=(0,R.dV)().o.XHR;class he extends b{static featureName=se.T;constructor(e,t=!0){super(e,se.T,t),this.dt=new ae(e.agentIdentifier),this.handler=(e,t,r,n)=>(0,x.p)(e,t,r,n,this.ee);try{const e={xmlhttprequest:"xhr",fetch:"fetch",beacon:"beacon"};p.gm?.performance?.getEntriesByType("resource").forEach((t=>{if(t.initiatorType in e&&0!==t.responseStatus){const r={status:t.responseStatus},n={rxSize:t.transferSize,duration:Math.floor(t.duration),cbTime:0};pe(r,t.name),this.handler("xhr",[r,n,t.startTime,t.responseEnd,e[t.initiatorType]],void 0,a.K7.ajax)}}))}catch(e){}ne(this.ee),Z(this.ee),function(e,t,r,n){function i(e){var t=this;t.totalCbs=0,t.called=0,t.cbTime=0,t.end=R,t.ended=!1,t.xhrGuids={},t.lastSize=null,t.loadCaptureCalled=!1,t.params=this.params||{},t.metrics=this.metrics||{},e.addEventListener("load",(function(r){T(t,e)}),(0,E.jT)(!1)),p.lR||e.addEventListener("progress",(function(e){t.lastSize=e.loaded}),(0,E.jT)(!1))}function o(e){this.params={method:e[0]},pe(this,e[1]),this.metrics={}}function s(t,r){e.loader_config.xpid&&this.sameOrigin&&r.setRequestHeader("X-NewRelic-ID",e.loader_config.xpid);var i=n.generateTracePayload(this.parsedOrigin);if(i){var o=!1;i.newrelicHeader&&(r.setRequestHeader("newrelic",i.newrelicHeader),o=!0),i.traceContextParentHeader&&(r.setRequestHeader("traceparent",i.traceContextParentHeader),i.traceContextStateHeader&&r.setRequestHeader("tracestate",i.traceContextStateHeader),o=!0),o&&(this.dt=i)}}function c(e,r){var n=this.metrics,i=e[0],o=this;if(n&&i){var a=G(i);a&&(n.txSize=a)}this.startTime=(0,S.t)(),this.body=i,this.listener=function(e){try{"abort"!==e.type||o.loadCaptureCalled||(o.params.aborted=!0),("load"!==e.type||o.called===o.totalCbs&&(o.onloadCalled||"function"!=typeof r.onload)&&"function"==typeof o.end)&&o.end(r)}catch(e){try{t.emit("internal-error",[e])}catch(e){}}};for(var s=0;s<de;s++)r.addEventListener(ue[s],this.listener,(0,E.jT)(!1))}function u(e,t,r){this.cbTime+=e,t?this.onloadCalled=!0:this.called+=1,this.called!==this.totalCbs||!this.onloadCalled&&"function"==typeof r.onload||"function"!=typeof this.end||this.end(r)}function d(e,t){var r=""+V(e)+!!t;this.xhrGuids&&!this.xhrGuids[r]&&(this.xhrGuids[r]=!0,this.totalCbs+=1)}function l(e,t){var r=""+V(e)+!!t;this.xhrGuids&&this.xhrGuids[r]&&(delete this.xhrGuids[r],this.totalCbs-=1)}function f(){this.endTime=(0,S.t)()}function h(e,r){r instanceof fe&&"load"===e[0]&&t.emit("xhr-load-added",[e[1],e[2]],r)}function g(e,r){r instanceof fe&&"load"===e[0]&&t.emit("xhr-load-removed",[e[1],e[2]],r)}function m(e,t,r){t instanceof fe&&("onload"===r&&(this.onload=!0),("load"===(e[0]&&e[0].type)||this.onload)&&(this.xhrCbStart=(0,S.t)()))}function v(e,r){this.xhrCbStart&&t.emit("xhr-cb-time",[(0,S.t)()-this.xhrCbStart,this.onload,r],r)}function b(e){var t,r=e[1]||{};if("string"==typeof e[0]?0===(t=e[0]).length&&p.RI&&(t=""+p.gm.location.href):e[0]&&e[0].url?t=e[0].url:p.gm?.URL&&e[0]&&e[0]instanceof URL?t=e[0].href:"function"==typeof e[0].toString&&(t=e[0].toString()),"string"==typeof t&&0!==t.length){t&&(this.parsedOrigin=(0,ie.D)(t),this.sameOrigin=this.parsedOrigin.sameOrigin);var i=n.generateTracePayload(this.parsedOrigin);if(i&&(i.newrelicHeader||i.traceContextParentHeader))if(e[0]&&e[0].headers)s(e[0].headers,i)&&(this.dt=i);else{var o={};for(var a in r)o[a]=r[a];o.headers=new Headers(r.headers||{}),s(o.headers,i)&&(this.dt=i),e.length>1?e[1]=o:e.push(o)}}function s(e,t){var r=!1;return t.newrelicHeader&&(e.set("newrelic",t.newrelicHeader),r=!0),t.traceContextParentHeader&&(e.set("traceparent",t.traceContextParentHeader),t.traceContextStateHeader&&e.set("tracestate",t.traceContextStateHeader),r=!0),r}}function y(e,t){this.params={},this.metrics={},this.startTime=(0,S.t)(),this.dt=t,e.length>=1&&(this.target=e[0]),e.length>=2&&(this.opts=e[1]);var r,n=this.opts||{},i=this.target;"string"==typeof i?r=i:"object"==typeof i&&i instanceof le?r=i.url:p.gm?.URL&&"object"==typeof i&&i instanceof URL&&(r=i.href),pe(this,r);var o=(""+(i&&i instanceof le&&i.method||n.method||"GET")).toUpperCase();this.params.method=o,this.body=n.body,this.txSize=G(n.body)||0}function w(e,t){if(this.endTime=(0,S.t)(),this.params||(this.params={}),(0,ce.iW)(this.params))return;let n;this.params.status=t?t.status:0,"string"==typeof this.rxSize&&this.rxSize.length>0&&(n=+this.rxSize);const i={txSize:this.txSize,rxSize:n,duration:(0,S.t)()-this.startTime};r("xhr",[this.params,i,this.startTime,this.endTime,"fetch"],this,a.K7.ajax)}function R(e){const t=this.params,n=this.metrics;if(!this.ended){this.ended=!0;for(let t=0;t<de;t++)e.removeEventListener(ue[t],this.listener,!1);t.aborted||(0,ce.iW)(t)||(n.duration=(0,S.t)()-this.startTime,this.loadCaptureCalled||4!==e.readyState?null==t.status&&(t.status=0):T(this,e),n.cbTime=this.cbTime,r("xhr",[t,n,this.startTime,this.endTime,"xhr"],this,a.K7.ajax))}}function T(e,r){e.params.status=r.status;var n=function(e,t){var r=e.responseType;return"json"===r&&null!==t?t:"arraybuffer"===r||"blob"===r||"json"===r?G(e.response):"text"===r||""===r||void 0===r?G(e.responseText):void 0}(r,e.lastSize);if(n&&(e.metrics.rxSize=n),e.sameOrigin){var i=r.getResponseHeader("X-NewRelic-App-Data");i&&((0,x.p)(_.rs,["Ajax/CrossApplicationTracing/Header/Seen"],void 0,a.K7.metrics,t),e.params.cat=i.split(", ").pop())}e.loadCaptureCalled=!0}t.on("new-xhr",i),t.on("open-xhr-start",o),t.on("open-xhr-end",s),t.on("send-xhr-start",c),t.on("xhr-cb-time",u),t.on("xhr-load-added",d),t.on("xhr-load-removed",l),t.on("xhr-resolved",f),t.on("addEventListener-end",h),t.on("removeEventListener-end",g),t.on("fn-end",v),t.on("fetch-before-start",b),t.on("fetch-start",y),t.on("fn-start",m),t.on("fetch-done",w)}(e,this.ee,this.handler,this.dt),this.importAggregator(e)}}function pe(e,t){var r=(0,ie.D)(t),n=e.params||e;n.hostname=r.hostname,n.port=r.port,n.protocol=r.protocol,n.host=r.hostname+":"+r.port,n.pathname=r.pathname,e.parsedOrigin=r,e.sameOrigin=r.sameOrigin}const ge={},me=["pushState","replaceState"];function ve(e){const t=function(e){return(e||B.ee).get("history")}(e);return!p.RI||ge[t.debugId]++||(ge[t.debugId]=1,(0,W.YM)(t).inPlace(window.history,me,"-")),t}var be=i(3738);const{He:ye,bD:we,d3:Re,Kp:xe,TZ:Te,Lc:Ee,uP:Ae,Rz:Se}=be;class Ne extends b{static featureName=Te;constructor(e,t=!0){super(e,Te,t);if(!(0,m.V)(this.agentIdentifier))return void this.deregisterDrain();const r=this.ee;let n;ve(r),this.eventsEE=(0,F.u)(r),this.eventsEE.on(Ae,(function(e,t){this.bstStart=(0,S.t)()})),this.eventsEE.on(Ee,(function(e,t){(0,x.p)("bst",[e[0],t,this.bstStart,(0,S.t)()],void 0,a.K7.sessionTrace,r)})),r.on(Se+Re,(function(e){this.time=(0,S.t)(),this.startPath=location.pathname+location.hash})),r.on(Se+xe,(function(e){(0,x.p)("bstHist",[location.pathname+location.hash,this.startPath,this.time],void 0,a.K7.sessionTrace,r)}));try{n=new PerformanceObserver((e=>{const t=e.getEntries();(0,x.p)(ye,[t],void 0,a.K7.sessionTrace,r)})),n.observe({type:we,buffered:!0})}catch(e){}this.importAggregator(e,{resourceObserver:n})}}var _e=i(2614);class Oe extends b{static featureName=t.TZ;#i;#o;constructor(e,r=!0){let n;super(e,t.TZ,r),this.replayRunning=!1,this.#o=e;try{n=JSON.parse(localStorage.getItem("".concat(_e.H3,"_").concat(_e.uh)))}catch(e){}(0,g.SR)(e.agentIdentifier)&&this.ee.on(t.G4.RECORD,(()=>this.#a())),this.#s(n)?(this.#i=n?.sessionReplayMode,this.#c()):this.importAggregator(e),this.ee.on("err",(e=>{this.replayRunning&&(this.errorNoticed=!0,(0,x.p)(t.G4.ERROR_DURING_REPLAY,[e],void 0,this.featureName,this.ee))})),this.ee.on(t.G4.REPLAY_RUNNING,(e=>{this.replayRunning=e}))}#s(e){return e&&(e.sessionReplayMode===_e.g.FULL||e.sessionReplayMode===_e.g.ERROR)||(0,g.Aw)(this.agentIdentifier)}#u=!1;async#c(e){if(!this.#u){this.#u=!0;try{const{Recorder:t}=await Promise.all([i.e(478),i.e(249)]).then(i.bind(i,8589));this.recorder??=new t({mode:this.#i,agentIdentifier:this.agentIdentifier,trigger:e,ee:this.ee}),this.recorder.startRecording(),this.abortHandler=this.recorder.stopRecording}catch(e){}this.importAggregator(this.#o,{recorder:this.recorder,errorNoticed:this.errorNoticed})}}#a(){this.featAggregate?this.featAggregate.mode!==_e.g.FULL&&this.featAggregate.initializeRecording(_e.g.FULL,!0):(this.#i=_e.g.FULL,this.#c(t.Qb.API),this.recorder&&this.recorder.parent.mode!==_e.g.FULL&&(this.recorder.parent.mode=_e.g.FULL,this.recorder.stopRecording(),this.recorder.startRecording(),this.abortHandler=this.recorder.stopRecording))}}var Ie=i(3962);class Pe extends b{static featureName=Ie.TZ;constructor(e,t=!0){if(super(e,Ie.TZ,t),!p.RI||!(0,R.dV)().o.MO)return;const r=ve(this.ee);Ie.tC.forEach((e=>{(0,E.sp)(e,(e=>{a(e)}),!0)}));const n=()=>(0,x.p)("newURL",[(0,S.t)(),""+window.location],void 0,this.featureName,this.ee);r.on("pushState-end",n),r.on("replaceState-end",n);try{this.removeOnAbort=new AbortController}catch(e){}(0,E.sp)("popstate",(e=>(0,x.p)("newURL",[e.timeStamp,""+window.location],void 0,this.featureName,this.ee)),!0,this.removeOnAbort?.signal);let i=!1;const o=new((0,R.dV)().o.MO)(((e,t)=>{i||(i=!0,requestAnimationFrame((()=>{(0,x.p)("newDom",[(0,S.t)()],void 0,this.featureName,this.ee),i=!1})))})),a=(0,v.s)((e=>{(0,x.p)("newUIEvent",[e],void 0,this.featureName,this.ee),o.observe(document.body,{attributes:!0,childList:!0,subtree:!0,characterData:!0})}),100,{leading:!0});this.abortHandler=function(){this.removeOnAbort?.abort(),o.disconnect(),this.abortHandler=void 0},this.importAggregator(e,{domObserver:o})}}var je=i(7378);const Ce={},ke=["appendChild","insertBefore","replaceChild"];function Le(e){const t=function(e){return(e||B.ee).get("jsonp")}(e);if(!p.RI||Ce[t.debugId])return t;Ce[t.debugId]=!0;var r=(0,W.YM)(t),n=/[?&](?:callback|cb)=([^&#]+)/,i=/(.*)\.([^.]+)/,o=/^(\w+)(\.|$)(.*)$/;function a(e,t){if(!e)return t;const r=e.match(o),n=r[1];return a(r[3],t[n])}return r.inPlace(Node.prototype,ke,"dom-"),t.on("dom-start",(function(e){!function(e){if(!e||"string"!=typeof e.nodeName||"script"!==e.nodeName.toLowerCase())return;if("function"!=typeof e.addEventListener)return;var o=(s=e.src,c=s.match(n),c?c[1]:null);var s,c;if(!o)return;var u=function(e){var t=e.match(i);if(t&&t.length>=3)return{key:t[2],parent:a(t[1],window)};return{key:e,parent:window}}(o);if("function"!=typeof u.parent[u.key])return;var d={};function l(){t.emit("jsonp-end",[],d),e.removeEventListener("load",l,(0,E.jT)(!1)),e.removeEventListener("error",f,(0,E.jT)(!1))}function f(){t.emit("jsonp-error",[],d),t.emit("jsonp-end",[],d),e.removeEventListener("load",l,(0,E.jT)(!1)),e.removeEventListener("error",f,(0,E.jT)(!1))}r.inPlace(u.parent,[u.key],"cb-",d),e.addEventListener("load",l,(0,E.jT)(!1)),e.addEventListener("error",f,(0,E.jT)(!1)),t.emit("new-jsonp",[e.src],d)}(e[0])})),t}const He={};function Me(e){const t=function(e){return(e||B.ee).get("promise")}(e);if(He[t.debugId])return t;He[t.debugId]=!0;var r=t.context,n=(0,W.YM)(t),i=p.gm.Promise;return i&&function(){function e(r){var o=t.context(),a=n(r,"executor-",o,null,!1);const s=Reflect.construct(i,[a],e);return t.context(s).getCtx=function(){return o},s}p.gm.Promise=e,Object.defineProperty(e,"name",{value:"Promise"}),e.toString=function(){return i.toString()},Object.setPrototypeOf(e,i),["all","race"].forEach((function(r){const n=i[r];e[r]=function(e){let i=!1;[...e||[]].forEach((e=>{this.resolve(e).then(a("all"===r),a(!1))}));const o=n.apply(this,arguments);return o;function a(e){return function(){t.emit("propagate",[null,!i],o,!1,!1),i=i||!e}}}})),["resolve","reject"].forEach((function(r){const n=i[r];e[r]=function(e){const r=n.apply(this,arguments);return e!==r&&t.emit("propagate",[e,!0],r,!1,!1),r}})),e.prototype=i.prototype;const o=i.prototype.then;i.prototype.then=function(...e){var i=this,a=r(i);a.promise=i,e[0]=n(e[0],"cb-",a,null,!1),e[1]=n(e[1],"cb-",a,null,!1);const s=o.apply(this,e);return a.nextPromise=s,t.emit("propagate",[i,!0],s,!1,!1),s},i.prototype.then[W.Jt]=o,t.on("executor-start",(function(e){e[0]=n(e[0],"resolve-",this,null,!1),e[1]=n(e[1],"resolve-",this,null,!1)})),t.on("executor-err",(function(e,t,r){e[1](r)})),t.on("cb-end",(function(e,r,n){t.emit("propagate",[n,!0],this.nextPromise,!1,!1)})),t.on("propagate",(function(e,r,n){this.getCtx&&!r||(this.getCtx=function(){if(e instanceof Promise)var r=t.context(e);return r&&r.getCtx?r.getCtx():this})}))}(),t}const De={},Ke="setTimeout",Ue="setInterval",Ve="clearTimeout",Ge="-start",Fe=[Ke,"setImmediate",Ue,Ve,"clearImmediate"];function Be(e){const t=function(e){return(e||B.ee).get("timer")}(e);if(De[t.debugId]++)return t;De[t.debugId]=1;var r=(0,W.YM)(t);return r.inPlace(p.gm,Fe.slice(0,2),Ke+"-"),r.inPlace(p.gm,Fe.slice(2,3),Ue+"-"),r.inPlace(p.gm,Fe.slice(3),Ve+"-"),t.on(Ue+Ge,(function(e,t,n){e[0]=r(e[0],"fn-",null,n)})),t.on(Ke+Ge,(function(e,t,n){this.method=n,this.timerDuration=isNaN(e[1])?0:+e[1],e[0]=r(e[0],"fn-",this,n)})),t}const We={};function ze(e){const t=function(e){return(e||B.ee).get("mutation")}(e);if(!p.RI||We[t.debugId])return t;We[t.debugId]=!0;var r=(0,W.YM)(t),n=p.gm.MutationObserver;return n&&(window.MutationObserver=function(e){return this instanceof n?new n(r(e,"fn-")):n.apply(this,arguments)},MutationObserver.prototype=n.prototype),t}const{TZ:qe,d3:Ze,Kp:Ye,$p:Xe,wW:$e,e5:Je,tH:Qe,uP:et,rw:tt,Lc:rt}=je;class nt extends b{static featureName=qe;constructor(e,t=!0){if(super(e,qe,t),!p.RI)return;try{this.removeOnAbort=new AbortController}catch(e){}let r,n=0;const i=this.ee.get("tracer"),o=Le(this.ee),a=Me(this.ee),s=Be(this.ee),c=Z(this.ee),u=this.ee.get("events"),d=ne(this.ee),l=ve(this.ee),f=ze(this.ee);function h(e,t){l.emit("newURL",[""+window.location,t])}function g(){n++,r=window.location.hash,this[et]=(0,S.t)()}function m(){n--,window.location.hash!==r&&h(0,!0);var e=(0,S.t)();this[Je]=~~this[Je]+e-this[et],this[rt]=e}function v(e,t){e.on(t,(function(){this[t]=(0,S.t)()}))}this.ee.on(et,g),a.on(tt,g),o.on(tt,g),this.ee.on(rt,m),a.on($e,m),o.on($e,m),this.ee.on("fn-err",((...t)=>{t[2]?.__newrelic?.[e.agentIdentifier]||(0,x.p)("function-err",[...t],void 0,this.featureName,this.ee)})),this.ee.buffer([et,rt,"xhr-resolved"],this.featureName),u.buffer([et],this.featureName),s.buffer(["setTimeout"+Ye,"clearTimeout"+Ze,et],this.featureName),c.buffer([et,"new-xhr","send-xhr"+Ze],this.featureName),d.buffer([Qe+Ze,Qe+"-done",Qe+Xe+Ze,Qe+Xe+Ye],this.featureName),l.buffer(["newURL"],this.featureName),f.buffer([et],this.featureName),a.buffer(["propagate",tt,$e,"executor-err","resolve"+Ze],this.featureName),i.buffer([et,"no-"+et],this.featureName),o.buffer(["new-jsonp","cb-start","jsonp-error","jsonp-end"],this.featureName),v(d,Qe+Ze),v(d,Qe+"-done"),v(o,"new-jsonp"),v(o,"jsonp-end"),v(o,"cb-start"),l.on("pushState-end",h),l.on("replaceState-end",h),window.addEventListener("hashchange",h,(0,E.jT)(!0,this.removeOnAbort?.signal)),window.addEventListener("load",h,(0,E.jT)(!0,this.removeOnAbort?.signal)),window.addEventListener("popstate",(function(){h(0,n>1)}),(0,E.jT)(!0,this.removeOnAbort?.signal)),this.abortHandler=this.#n,this.importAggregator(e)}#n(){this.removeOnAbort?.abort(),this.abortHandler=void 0}}var it=i(3333);class ot extends b{static featureName=it.TZ;constructor(e,t=!0){super(e,it.TZ,t);const r=[e.init.page_action.enabled,e.init.performance.capture_marks,e.init.performance.capture_measures,e.init.user_actions.enabled,e.init.performance.resources.enabled];if(p.RI&&(e.init.user_actions.enabled&&(it.Zp.forEach((e=>(0,E.sp)(e,(e=>(0,x.p)("ua",[e],void 0,this.featureName,this.ee)),!0))),it.qN.forEach((e=>(0,E.sp)(e,(e=>(0,x.p)("ua",[e],void 0,this.featureName,this.ee)))))),e.init.performance.resources.enabled&&p.gm.PerformanceObserver?.supportedEntryTypes.includes("resource"))){new PerformanceObserver((e=>{e.getEntries().forEach((e=>{(0,x.p)("browserPerformance.resource",[e],void 0,this.featureName,this.ee)}))})).observe({type:"resource",buffered:!0})}r.some((e=>e))?this.importAggregator(e):this.deregisterDrain()}}var at=i(993),st=i(3785);class ct extends b{static featureName=at.TZ;constructor(e,t=!0){super(e,at.TZ,t);const r=this.ee;this.ee.on("wrap-logger-end",(function([e]){const{level:t,customAttributes:n}=this;(0,st.R)(r,e,n,t)})),this.importAggregator(e)}}new class extends o{constructor(t,r){super(r),p.gm?(this.features={},(0,R.bQ)(this.agentIdentifier,this),this.desiredFeatures=new Set(t.features||[]),this.desiredFeatures.add(w),this.runSoftNavOverSpa=[...this.desiredFeatures].some((e=>e.featureName===a.K7.softNav)),(0,d.j)(this,t,t.loaderType||"agent"),this.run()):(0,e.R)(21)}get config(){return{info:this.info,init:this.init,loader_config:this.loader_config,runtime:this.runtime}}run(){try{const t=u(this.agentIdentifier),r=[...this.desiredFeatures];r.sort(((e,t)=>a.P3[e.featureName]-a.P3[t.featureName])),r.forEach((r=>{if(!t[r.featureName]&&r.featureName!==a.K7.pageViewEvent)return;if(this.runSoftNavOverSpa&&r.featureName===a.K7.spa)return;if(!this.runSoftNavOverSpa&&r.featureName===a.K7.softNav)return;const n=function(e){switch(e){case a.K7.ajax:return[a.K7.jserrors];case a.K7.sessionTrace:return[a.K7.ajax,a.K7.pageViewEvent];case a.K7.sessionReplay:return[a.K7.sessionTrace];case a.K7.pageViewTiming:return[a.K7.pageViewEvent];default:return[]}}(r.featureName).filter((e=>!(e in this.features)));n.length>0&&(0,e.R)(36,{targetFeature:r.featureName,missingDependencies:n}),this.features[r.featureName]=new r(this)}))}catch(t){(0,e.R)(22,t);for(const e in this.features)this.features[e].abortHandler?.();const r=(0,R.Zm)();delete r.initializedAgents[this.agentIdentifier]?.api,delete r.initializedAgents[this.agentIdentifier]?.features,delete this.sharedAggregator;return r.ee.get(this.agentIdentifier).abort(),!1}}}({features:[he,w,N,Ne,Oe,O,M,ot,ct,Pe,nt],loaderType:"spa"})})()})();</script>
  <meta name="viewport" content="width=device-width, initial-scale=1">
  <meta name="keywords" content="">
  <meta name="description" content="LitMetric - Explore Scientific Literature">
  <!-- css file -->
  <link rel="stylesheet" href="https://www.litmetric.com/css/bootstrap.min.css">
  <link rel="stylesheet" href="https://www.litmetric.com/css/ace-responsive-menu.css">
  <link rel="stylesheet" href="https://www.litmetric.com/css/menu.css">
  <link rel="stylesheet" href="https://www.litmetric.com/css/fontawesome.css">
  <link rel="stylesheet" href="https://www.litmetric.com/css/flaticon.css">
  <link rel="stylesheet" href="https://www.litmetric.com/css/bootstrap-select.min.css">
  <link rel="stylesheet" href="https://www.litmetric.com/css/ud-custom-spacing.css">
  <link rel="stylesheet" href="https://www.litmetric.com/css/animate.css">
  <link rel="stylesheet" href="https://www.litmetric.com/css/jquery-ui.min.css">
  <link rel="stylesheet" href="https://www.litmetric.com/css/style.css?v=1.28">
  <!-- Responsive stylesheet -->
  <link rel="stylesheet" href="https://www.litmetric.com/css/responsive.css">
  <!-- Title -->
    <title>Limitation of WO in Zn-CoO Nanopolyhedra by the Pyrolysis of HPWO@BMZIF: Synergistic Effect of Heterostructure and Oxygen Vacancies for Enhanced Nitrogen Fixation. | LitMetric</title>
  <!-- Favicon -->
  <link href="https://www.litmetric.com/images/favicon.ico?v=1.1" sizes="128x128" rel="shortcut icon" type="image/x-icon" />
  <link href="https://www.litmetric.com/images/favicon.ico?v=1.1" sizes="128x128" rel="shortcut icon" />
  <!-- Apple Touch Icon -->
  <link href="https://www.litmetric.com/images/apple-touch-icon-60x60.png?v=1.1" sizes="60x60" rel="apple-touch-icon">
  <link href="https://www.litmetric.com/images/apple-touch-icon-72x72.png?v=1.1" sizes="72x72" rel="apple-touch-icon">
  <link href="https://www.litmetric.com/images/apple-touch-icon-114x114.png?v=1.1" sizes="114x114" rel="apple-touch-icon">
  <link href="https://www.litmetric.com/images/apple-touch-icon-180x180.png?v=1.1" sizes="180x180" rel="apple-touch-icon">
  
  <!-- HTML5 shim and Respond.js for IE8 support of HTML5 elements and media queries -->
  <!-- WARNING: Respond.js doesn't work if you view the page via file:// -->
  <!--[if lt IE 9]>
  <script src="https://oss.maxcdn.com/html5shiv/3.7.3/html5shiv.min.js"></script>
  <script src="https://oss.maxcdn.com/respond/1.4.2/respond.min.js"></script>
  <![endif]-->

  </head>
  <body>
  <div class="wrapper ovh">
 <!--   <div class="preloader"></div> -->
    
    <!-- Main Header Nav -->
    <header class="header-nav nav-innerpage-style main-menu">
      <!-- Ace Responsive Menu -->
      <nav class="posr"> 
        <div class="container-fluid posr menu_bdrt1">
          <div class="row align-items-center justify-content-between">
            <div class="col-auto pe-0">
              <div class="d-flex align-items-center">
        <a class="header-logo bdrr1 pr30 pr5-xl" href="https://www.litmetric.com/home"><img src="https://www.litmetric.com/images/header-logo-dark.png" alt="LitMetric"></a>
                <div class="home1_style">
                  <div id="mega-menu">
                    <a class="btn-mega fw500" href="https://www.litmetric.com/categories"><span class="pl30 pl10-xl pr5 fz15 vam flaticon-menu"></span>Article  Categories</a>
                    
               <ul class="menu ps-0"><li> <a class="dropdown" href="https://www.litmetric.com/categories/Allergy+and+Immunology"> <span class="menu-icn flaticon-badge"></span>
               <span class="menu-title">Allergy and Immunology</span> </a>
                   </li><li> <a class="dropdown" href="https://www.litmetric.com/categories/Cardiology"> <span class="menu-icn flaticon-badge"></span>
               <span class="menu-title">Cardiology</span> </a>
                   </li><li> <a class="dropdown" href="https://www.litmetric.com/categories/Clinical+Procedures"> <span class="menu-icn flaticon-badge"></span>
               <span class="menu-title">Clinical Procedures</span> </a>
                   </li><li> <a class="dropdown" href="https://www.litmetric.com/categories/Critical+Care"> <span class="menu-icn flaticon-badge"></span>
               <span class="menu-title">Critical Care</span> </a>
                   </li><li> <a class="dropdown" href="https://www.litmetric.com/categories/Dermatology"> <span class="menu-icn flaticon-badge"></span>
               <span class="menu-title">Dermatology</span> </a>
                   </li><li> <a class="dropdown" href="https://www.litmetric.com/categories/Emergency+Medicine"> <span class="menu-icn flaticon-badge"></span>
               <span class="menu-title">Emergency Medicine</span> </a>
                   </li><li> <a class="dropdown" href="https://www.litmetric.com/categories/Endocrinology"> <span class="menu-icn flaticon-badge"></span>
               <span class="menu-title">Endocrinology</span> </a>
                   </li><li> <a class="dropdown" href="https://www.litmetric.com/categories/Gastroenterology"> <span class="menu-icn flaticon-badge"></span>
               <span class="menu-title">Gastroenterology</span> </a>
                   </li><li> <a class="dropdown" href="https://www.litmetric.com/categories/Genomic+Medicine"> <span class="menu-icn flaticon-badge"></span>
               <span class="menu-title">Genomic Medicine</span> </a>
                   </li><li> <a class="dropdown" href="https://www.litmetric.com/categories/Hematology"> <span class="menu-icn flaticon-badge"></span>
               <span class="menu-title">Hematology</span> </a>
                   </li><li> <a class="dropdown" href="https://www.litmetric.com/categories/Infectious+Diseases"> <span class="menu-icn flaticon-badge"></span>
               <span class="menu-title">Infectious Diseases</span> </a>
                   </li><li> <a class="dropdown" href="https://www.litmetric.com/categories/Nephrology"> <span class="menu-icn flaticon-badge"></span>
               <span class="menu-title">Nephrology</span> </a>
                   </li><li> <a class="dropdown" href="https://www.litmetric.com/categories/Neurology"> <span class="menu-icn flaticon-badge"></span>
               <span class="menu-title">Neurology</span> </a>
                   </li><li> <a class="dropdown" href="https://www.litmetric.com/categories/Obstetrics+and+Gynecology"> <span class="menu-icn flaticon-badge"></span>
               <span class="menu-title">Obstetrics and Gynecology</span> </a>
                   </li><li> <a class="dropdown" href="https://www.litmetric.com/categories/Oncology"> <span class="menu-icn flaticon-badge"></span>
               <span class="menu-title">Oncology</span> </a>
                   </li><li> <a class="dropdown" href="https://www.litmetric.com/categories/Pathology"> <span class="menu-icn flaticon-badge"></span>
               <span class="menu-title">Pathology</span> </a>
                   </li><li> <a class="dropdown" href="https://www.litmetric.com/categories/Perioperative+Care"> <span class="menu-icn flaticon-badge"></span>
               <span class="menu-title">Perioperative Care</span> </a>
                   </li><li> <a class="dropdown" href="https://www.litmetric.com/categories/Physical+Medicine+and+Rehabilitation"> <span class="menu-icn flaticon-badge"></span>
               <span class="menu-title">Physical & Rehabilitation</span> </a>
                   </li><li> <a class="dropdown" href="https://www.litmetric.com/categories/Psychiatry"> <span class="menu-icn flaticon-badge"></span>
               <span class="menu-title">Psychiatry</span> </a>
                   </li><li> <a class="dropdown" href="https://www.litmetric.com/categories/Pulmonology"> <span class="menu-icn flaticon-badge"></span>
               <span class="menu-title">Pulmonology</span> </a>
                   </li><li> <a class="dropdown" href="https://www.litmetric.com/categories/Radiology"> <span class="menu-icn flaticon-badge"></span>
               <span class="menu-title">Radiology</span> </a>
                   </li><li> <a class="dropdown" href="https://www.litmetric.com/categories/Rheumatology"> <span class="menu-icn flaticon-badge"></span>
               <span class="menu-title">Rheumatology</span> </a>
                   </li><li> <a class="dropdown" href="https://www.litmetric.com/categories/Sports+Medicine"> <span class="menu-icn flaticon-badge"></span>
               <span class="menu-title">Sports Medicine</span> </a>
                   </li></ul>
                  
                  
                  
                  
                  </div>
                </div>
              </div>
            </div>
            <div class="col-auto">
              <div class="d-flex align-items-center">
                <!-- Responsive Menu Structure-->
                <ul id="respMenu" class="ace-responsive-menu" data-menu-style="horizontal">
                 
                
                <li> <a class="list-item" href="https://www.litmetric.com/categories">Browse Categories</a></li>
                <li> <a class="list-item" href="https://www.litmetric.com/drugs">Browse Drugs</a></li>
                <li> <a class="list-item" href="https://www.litmetric.com/journals">Browse Journals</a></li>
           <!--     <li> <a class="list-item" href="https://www.litmetric.com/authors">Browse Authors</a></li>-->
                </ul>
                <a class="login-info bdrl1 pl15-lg pl30" data-bs-toggle="modal" href="#exampleModalToggle" role="button"><span class="flaticon-loupe"></span></a>
                <div class="login-info mx15-lg mx30" class="login-info mr15-lg mr30"></div>
 <!--
                <a class="login-info mx15-lg mx30" class="login-info mr15-lg mr30" href="page-login.html">Sign in</a>
                <a class="ud-btn btn-thm add-joining" href="page-register.html">Join</a>
                
              -->
              </div>
            </div>
          </div>
        </div>
      </nav>
    </header>



            
            <!-- Search Modal -->
            <div class="search-modal">
              
              <form action="https://www.litmetric.com/search" method="post" >
              <div class="modal fade" id="exampleModalToggle" aria-hidden="true" aria-labelledby="exampleModalToggleLabel" tabindex="-1">
                <div class="modal-dialog modal-lg">
                  <div class="modal-content">
                    <div class="modal-header">
                      <h5 class="modal-title" id="exampleModalToggleLabel"></h5>
                      <button type="button" class="btn-close" data-bs-dismiss="modal" aria-label="Close"><i class="fal fa-xmark"></i></button>
                    </div>
                    <div class="modal-body">
                      <div class="popup-search-field search_area">
                        <input type="text" class="form-control border-0" placeholder="Article title or keywords" name="searchterm" >
                        <label><span class="far fa-magnifying-glass"></span></label>
                        <button class="ud-btn btn-thm" type="submit">Search</button>
                       
                      </div>
                    </div>
                  </div>
                </div>
              </div>
              </form>
            </div>
            
            <div class="hiddenbar-body-ovelay"></div>
            
       <!-- Mobile Nav  -->
<div id="page" class="mobilie_header_nav stylehome1">
  <div class="mobile-menu">
    <div class="header bdrb1">
      <div class="menu_and_widgets">
        <div class="mobile_menu_bar d-flex justify-content-between align-items-center">
          <a class="mobile_logo" href="https://www.litmetric.com/"><img src="https://www.litmetric.com/images/header-logo-dark.png" alt=""></a>
          <div class="right-side text-end">
            
              <a class="" href="https://www.litmetric.com/categories">Browse Categories</a>



            <a class="menubar ml30" href="#menu"><img src="https://www.litmetric.com/images/mobile-dark-nav-icon.svg" alt=""></a>
          </div>
        </div>
      </div>
      <div class="posr"><div class="mobile_menu_close_btn"><span class="far fa-times"></span></div></div>
    </div>
  </div>
  <!-- /.mobile-menu -->
  <nav id="menu" class="">
    <ul>
      <li><span><a href="https://www.litmetric.com/categories">Browse Categories</a></span>
        <ul>
	        <li><a  href="https://www.litmetric.com/categories/Allergy+and+Immunology">Allergy and Immunology</a></li>
	        <li> <a  href="https://www.litmetric.com/categories/Cardiology">Cardiology</a></li>
	        <li> <a  href="https://www.litmetric.com/categories/Clinical+Procedures">Clinical Procedures</a></li>
	        <li> <a  href="https://www.litmetric.com/categories/Critical+Care">Critical Care</a></li>
	        <li> <a  href="https://www.litmetric.com/categories/Dermatology">Dermatology</a></li>
	        <li> <a  href="https://www.litmetric.com/categories/Emergency+Medicine">Emergency Medicine</a></li>
	        <li> <a  href="https://www.litmetric.com/categories/Endocrinology">Endocrinology</a></li>
	        <li> <a  href="https://www.litmetric.com/categories/Gastroenterology">Gastroenterology</a></li>
	        <li> <a  href="https://www.litmetric.com/categories/Genomic+Medicine">Genomic Medicine</a></li>
	        <li> <a  href="https://www.litmetric.com/categories/Hematology">Hematology</a></li>
	        <li> <a  href="https://www.litmetric.com/categories/Infectious+Diseases">Infectious Diseases</a></li>
	        <li> <a  href="https://www.litmetric.com/categories/Nephrology">Nephrology</a></li>
	        <li> <a  href="https://www.litmetric.com/categories/Neurology">Neurology</a></li>
	        <li> <a  href="https://www.litmetric.com/categories/Obstetrics+and+Gynecology">Obstetrics and Gynecology</a></li>
	        <li> <a  href="https://www.litmetric.com/categories/Oncology">Oncology</a></li>
	        <li> <a  href="https://www.litmetric.com/categories/Pathology">Pathology</a></li>
	        <li> <a  href="https://www.litmetric.com/categories/Perioperative+Care">Perioperative Care</a></li>
	        <li> <a  href="https://www.litmetric.com/categories/Physical+Medicine+and+Rehabilitation">Physical & Rehabilitation</a></li>
	        <li> <a  href="https://www.litmetric.com/categories/Psychiatry">Psychiatry</a></li>
	        <li> <a  href="https://www.litmetric.com/categories/Pulmonology">Pulmonology</a></li>
	        <li> <a  href="https://www.litmetric.com/categories/Radiology">Radiology</a></li>
	        <li> <a  href="https://www.litmetric.com/categories/Rheumatology">Rheumatology</a></li>
	        <li> <a  href="https://www.litmetric.com/categories/Sports+Medicine">Sports Medicine</a></li>
	        </ul>
                   
      </li>
      <li><span><a href="https://www.litmetric.com/journals">Browse Journals</a></span>
      <ul>
	        <li></li>
	        </ul>
	        
      </li>
      <!-- Only for Mobile View -->
    </ul>
  </nav>
</div>


 
        
        
         
            <div class="body_content bgc-thm3">
              
               
     
              <!-- Breadcumb Sections -->
              <section class="breadcumb-section">
                <div class="container">
                  <div class="row">
                     
                                  
                  </div>
                </div>
              </section>
              
   
                        

  
           
   <!-- Breadcumb Sections -->
   <section class="breadcumb-section pt-0">
     <div class="cta-service-v1 freelancer-single-style mx-auto maxw1700 pt20 pt60-sm pb20 pb60-sm bdrs16 position-relative overflow-hidden d-flex align-items-center mx20-lg px30-lg" style="height:auto">
       <img class="left-top-img wow zoomIn" src="https://www.litmetric.com/images/vector-img/left-top.png" alt="">
       <img class="right-bottom-img wow zoomIn" src="https://www.litmetric.com/images/vector-img/right-bottom.png" alt="">
       <div class="container">
         <div class="row wow fadeInUp">
           <div class="col-xl-9">
             <div class="position-relative">
               <h2><a href="https://www.litmetric.com/detail/37218148/Limitation-of-WO-in-Zn-CoO-Nanopolyhedra-by-the-Pyrolysis-of-HPWOBMZIF-Synergistic-Effect-of-Heteros" >Limitation of WO in Zn-CoO Nanopolyhedra by the Pyrolysis of HPWO@BMZIF: Synergistic Effect of Heterostructure and Oxygen Vacancies for Enhanced Nitrogen Fixation.</a></h2>
               <div class="list-meta d-sm-flex align-items-center mt15">
             
                 <div class="ml5 ml0-xs">
                <div class="publication-auther"><a href="https://www.litmetric.com/author/Xue+Yang" class="tag" style="margin-bottom: 5px;">Xue Yang</a> <a href="https://www.litmetric.com/author/Mohan+Li" class="tag" style="margin-bottom: 5px;">Mohan Li</a> <a href="https://www.litmetric.com/author/Lin+Xu" class="tag" style="margin-bottom: 5px;">Lin Xu</a> <a href="https://www.litmetric.com/author/Fengyan+Li" class="tag" style="margin-bottom: 5px;">Fengyan Li</a></div>                   
                    <p class="mb-0 dark-color fz15 fw500 list-inline-item ml15 mb5-sm ml0-xs"><i class="flaticon-contract vam fz20 me-2"></i> Inorg Chem</p>
              
                   <p class="mb-0 dark-color fz15 fw500 list-inline-item mr15  mb5-sm ml0-xs"><i class="flaticon-place text-thm2 vam fz20 me-2"></i> Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education, College of Chemistry, <a href='https://www.litmetric.com/search/Northeast+Normal+University%5BAffiliation%5D' style='text-decoration: underline'>Northeast Normal University</a>, Changchun 130024, P. R. China.</p>
                    
                     
                   <p class="mb-0 dark-color fz15 fw500 list-inline-item ml15 mb5-sm ml0-xs"><i class="flaticon-calendar vam fz20 me-2"></i> Published: June 2023</p>
                                    </div>
               </div>
             </div>
           </div>
         </div>
       </div>
     </div>
   </section>
   
   
   
   <!-- Service Details -->
   <section class="pt10 pb90 pb30-md">
     <div class="container">
      
        
        
       <div class="row wow fadeInUp">
	         
         <div class="col-lg-8">
                                     
                                       

                     <div class="service-about">
                       <div class="p30 bdr1 mb30 bg-white bdrs12 wow fadeInUp default-box-shadow1">
                          
                          
                          
                          
                                                            
                                
                   <p class="text mb30"><p class="text mt10">The photocatalytic nitrogen fixation process is a crucial step toward carbon neutrality and sustainable development. The combination of polyoxometalates and metal-organic frameworks is a viable method to achieve high-efficiency photocatalytic nitrogen fixation. In this work, we employed bimetallic ZIF (BMZIF) composed of Co and Zn encapsulated with HPWO (PW) as the precursor to synthesize Zn-doped CoO nanopolyhedra loaded with WO nanoparticles. The NH yield of WO/Zn-CoO-2 with the best photocatalytic performance can reach 231.9 μmol g h under visible light, about 2.4 and 6.4 times those of pure Zn-CoO and WO, respectively. The rhombic dodecahedral geometry of BMZIF is still maintained in the synthesized WO/Zn-CoO nanopolyhedra, with the significant increase in the specific surface area after calcination showing better catalytic performance. At the same time, Zn doping and the formation of WO nanoparticles result in abundant oxygen vacancies in WO/Zn-CoO heterostructures. Oxygen vacancies can supply nitrogen with active sites for adsorption and activation and improve photocarriers' capacity for separation, which can greatly increase the effectiveness of the photocatalytic synthesis of ammonia. This work can easily synthesize the heterostructure based on n-type WO nanoparticles and p-type Zn-doped CoO nanopolyhedra, and the beneficial combination of POMs and metal-organic framework provides new thinking for the synthesis of efficient nitrogen-fixing photocatalysts.</p><table class="table table-bordered table-striped downloadTable" >
							 <thead >
                            <tr> 								
								<th ><h3>Download full-text PDF</h3></th>
								<th >Source</th>								
							</tr></thead>
					
						<tbody><tr><td><i class='icon-doc'></i><a href='http://dx.doi.org/10.1021/acs.inorgchem.3c01016'  rel='nofollow' target='_blank' onClick='ga("send", "event", "fulltextclick_DOI Listing", "click", "article");' style='text-decoration:underline;' class='clickTrack' data-ref='fulltext-37218148-n' >http://dx.doi.org/10.1021/acs.inorgchem.3c01016</a></td><td>DOI Listing</td></tr></tbody></table><div class="publication-dtl-rgt fr"><div class="publication-social"><a href="https://www.facebook.com/sharer/sharer.php?u=https://www.litmetric.com/detail/37218148" target="_blank" onClick='ga("send", "event", "facebook", "share", "article");' title="" class="fb socialShare" id="fb-a-37218148"><i class="icon-facebook"></i></a> 
                    
                      <a href="https://twitter.com/intent/tweet?text=Full+Article+on+PubFacts%3A&url=https://www.litmetric.com/detail/37218148&via=pubfacts_com" target="_blank"  onClick='ga("send", "event", "twitter", "share", "article");' title="" class="tw socialShare" id="tw-a-37218148"><i class="icon-twitter"></i></a>
					 
					 
					 <a  href="http://www.linkedin.com/shareArticle?mini=true&amp;url=https://www.litmetric.com/detail/37218148&amp;title=Limitation+of+WO+in+Zn-CoO+Nanopolyhedra+by+the+Pyrolysis+of+HPWO%40BMZIF%3A+Synergistic+Effect+of+Heterostructure+and+Oxygen+Vacancies+for+Enhanced+Nitrogen+Fixation.&amp;summary=Article+Summary+on+PubFacts.com"  target="_blank" onClick='ga("send", "event", "linkedin", "share", "article");' title="" class="in socialShare" id="in-a-37218148"><i class="icon-linkedin"></i></a></div><div class="row" ><div class="pubfacts-artical-heading right-head" style="margin-bottom:30px; margin-top:30px; " >
      <h2 style="padding-bottom:5px">Publication Analysis</h2>
    </div> <div class="col-md-12"> <h4>Top Keywords</h4> <div class="review-list d-flex align-items-center mb10">
										  <div class="list-number">oxygen vacancies</div>
										   <div class="progress">
											   <div class="progress-bar" style="width: 100%;" role="progressbar" aria-valuenow="100" aria-valuemin="0" aria-valuemax="100"></div>
										   </div>
										   <div class="value text-end">12</div>
										   </div> <div class="review-list d-flex align-items-center mb10">
										  <div class="list-number">nitrogen fixation</div>
										   <div class="progress">
											   <div class="progress-bar" style="width: 100%;" role="progressbar" aria-valuenow="100" aria-valuemin="0" aria-valuemax="100"></div>
										   </div>
										   <div class="value text-end">12</div>
										   </div> <div class="review-list d-flex align-items-center mb10">
										  <div class="list-number">photocatalytic nitrogen</div>
										   <div class="progress">
											   <div class="progress-bar" style="width: 67%;" role="progressbar" aria-valuenow="67" aria-valuemin="0" aria-valuemax="100"></div>
										   </div>
										   <div class="value text-end">8</div>
										   </div> <div class="review-list d-flex align-items-center mb10">
										  <div class="list-number">zn-doped coo</div>
										   <div class="progress">
											   <div class="progress-bar" style="width: 67%;" role="progressbar" aria-valuenow="67" aria-valuemin="0" aria-valuemax="100"></div>
										   </div>
										   <div class="value text-end">8</div>
										   </div> <div class="review-list d-flex align-items-center mb10">
										  <div class="list-number">coo nanopolyhedra</div>
										   <div class="progress">
											   <div class="progress-bar" style="width: 67%;" role="progressbar" aria-valuenow="67" aria-valuemin="0" aria-valuemax="100"></div>
										   </div>
										   <div class="value text-end">8</div>
										   </div> <div class="review-list d-flex align-items-center mb10">
										  <div class="list-number">limitation zn-coo</div>
										   <div class="progress">
											   <div class="progress-bar" style="width: 34%;" role="progressbar" aria-valuenow="34" aria-valuemin="0" aria-valuemax="100"></div>
										   </div>
										   <div class="value text-end">4</div>
										   </div> <div class="review-list d-flex align-items-center mb10">
										  <div class="list-number">nanopolyhedra</div>
										   <div class="progress">
											   <div class="progress-bar" style="width: 34%;" role="progressbar" aria-valuenow="34" aria-valuemin="0" aria-valuemax="100"></div>
										   </div>
										   <div class="value text-end">4</div>
										   </div> <div class="review-list d-flex align-items-center mb10">
										  <div class="list-number">zn-coo nanopolyhedra</div>
										   <div class="progress">
											   <div class="progress-bar" style="width: 34%;" role="progressbar" aria-valuenow="34" aria-valuemin="0" aria-valuemax="100"></div>
										   </div>
										   <div class="value text-end">4</div>
										   </div> <div class="review-list d-flex align-items-center mb10">
										  <div class="list-number">nanopolyhedra pyrolysis</div>
										   <div class="progress">
											   <div class="progress-bar" style="width: 34%;" role="progressbar" aria-valuenow="34" aria-valuemin="0" aria-valuemax="100"></div>
										   </div>
										   <div class="value text-end">4</div>
										   </div> <div class="review-list d-flex align-items-center mb10">
										  <div class="list-number">pyrolysis hpwo@bmzif</div>
										   <div class="progress">
											   <div class="progress-bar" style="width: 34%;" role="progressbar" aria-valuenow="34" aria-valuemin="0" aria-valuemax="100"></div>
										   </div>
										   <div class="value text-end">4</div>
										   </div></div></div></div></div></p>
                     
                       </div>
                       
                  
                    <a name="similarPublications"></a>  
                       <div class="p30 pb0 bdr1 mb30 bg-white bdrs12 wow fadeInUp default-box-shadow1">
                       <h4 class="mb30">Similar Publications</h4>
                       
                              
                      
                                   
           </div>
           
                      
           
           
           
         </div>

                          
                        
                  <div class="col-lg-4">

                        
                     <div class="contact-page-form default-box-shadow1 bdrs8 bdr1 p50 mb30-md bgc-white">
              <h4 class="form-title mb25">Want AI Summaries of new PubMed Abstracts delivered to your In-box?</h4>
              <p class="text mb30">Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!</p>
	              <form class="form-style1" action="https://www.litmetric.com/emailsignup" method="post" id="signupForm">
      
      
                <div class="row">
                  <div class="col-md-12">
                    <div class="mb20">
                      <label class="heading-color ff-heading fw500 mb10" for="">Search Type</label>
                     <div class="bootselect-multiselect">
                  <select class="selectpicker" data-width="100%" name="queryType">
                    <option value="keyword">Keyword</option>
                    <option value="author name">Author Name</option>
                  </select>
                </div>
                    </div>
                  </div>
                  <div class="col-md-12">
                    <div class="mb20">
                      <label class="heading-color ff-heading fw500 mb10" for="">Terms to search for</label>
                                     <input name="terms" type="text" class="form-control" placeholder="cellular transport">
                    </div>
                  </div>
            
                  <div class="col-md-12">
                    <div class="">
              
                      	          <input type="hidden" name="emailSignup" id="emailSignup" value="true">
            <button class="ud-btn btn-thm" type="submit">Review and Schedule<i class="fal fa-arrow-right-long"></i></button>
            
            
                    </div>
                  </div>
                </div>
              </form>
            </div>
                        
            
                </div>
                     
               
                
               
               
               
                
     </div>
   </section>
   
   



            
   
  
    
    

    <!-- Our Footer --> 
    <section class="footer-style1 pt25 pb-0">
      <div class="container">
        <div class="row  pb10">
          <div class="col-md-7">
            <div class="d-block text-center text-md-start justify-content-center justify-content-md-start d-md-flex align-items-center mb-3 mb-md-0">
              <a class="fz17 fw500 text-white mr15-md mr30" href="https://www.litmetric.com/privacypolicy">Privacy Policy</a>
              <a class="fz17 fw500 text-white" href="https://www.litmetric.com/sitemap">Site Map</a>
            </div>
          </div>
          <div class="col-md-5">
            <div class="social-widget text-center text-md-end">
              <div class="social-style1">
                <a class="text-white me-2 fw500 fz17" href="mailto:info@litmetric.com">Contact Us</a>
                <!--
                <a href=""><i class="fab fa-facebook-f list-inline-item"></i></a>
                <a href=""><i class="fab fa-twitter list-inline-item"></i></a>
                <a href=""><i class="fab fa-instagram list-inline-item"></i></a>
                <a href=""><i class="fab fa-linkedin-in list-inline-item"></i></a>
              -->
              </div>
            </div>
          </div>
        </div>
              </div>
      <div class="container white-bdrt1 py-4">
        <div class="row align-items-center">
          <div class="col-md-12">
            <div class="text-center text-lg-start">
              <p class="copyright-text mb-2 mb-md-0 text-white-light ff-heading">© LitMetric 2024. All rights reserved.</p>
            </div>
          </div>
    
        </div>
      </div>
    </section>
    <a class="scrollToHome" href="#"><i class="fas fa-angle-up"></i></a>
  </div>
</div>
<!-- Wrapper End --> 
<script src="https://www.litmetric.com/js/jquery-3.6.4.min.js"></script>
<script src="https://www.litmetric.com/js/jquery-migrate-3.0.0.min.js"></script>
<script src="https://www.litmetric.com/js/popper.min.js"></script>
<script src="https://www.litmetric.com/js/bootstrap.min.js"></script>
<script src="https://www.litmetric.com/js/bootstrap-select.min.js"></script>
<script src="https://www.litmetric.com/js/jquery.mmenu.all.js"></script>
  
  

<script src="https://www.litmetric.com/js/ace-responsive-menu.js"></script>
<script src="https://www.litmetric.com/js/jquery-scrolltofixed-min.js"></script>
<script src="https://www.litmetric.com/js/wow.min.js"></script>
<script src="https://www.litmetric.com/js/scrollbalance.js"></script>
<!-- Custom script for all pages --> 
<script src="https://www.litmetric.com/js/script.js?v=1.47"></script>
</body>
</html>

      <script type="text/javascript">  
	    
	    
	    
	      


      

      

      
    
    
</script>

<script>
//  Fixed sidebar Custom Script For That 
$(function() {
  var cols = $('.wrap .column');
  var enabled = true;
  var scrollbalance = new ScrollBalance(cols, {
    minwidth: 1199
  });
  // bind to scroll and resize events
  scrollbalance.bind();
}); 



</script>




<script type="text/javascript">window.NREUM||(NREUM={});NREUM.info={"beacon":"bam.nr-data.net","licenseKey":"NRJS-750ae8097b9f1344f1a","applicationID":"589630826","transactionName":"ZVZbN0FZXEtUAENfV1wcbBFaF1tWUQZPGEhaQw==","queueTime":0,"applicationTime":656,"atts":"SRFYQQlDT0U=","errorBeacon":"bam.nr-data.net","agent":""}</script></body>
</html>