Using foam fractionation to estimate PFAS air-water interface adsorption behaviour at ng/L and µg/L concentrations.

PFAS are biologically recalcitrant compounds that are persistent in the environment and have subsequently contaminated groundwater, landfill leachate and surface water. Due to their persistence and toxicity, there are environmental concentration limits imposed on some PFAS compounds that extend down to a few nanograms per litre and even proposals for reducing these to picogram per litre levels. Since PFAS concentrates at water-air interfaces as a result of their amphiphilic nature, this characteristic is important for the successful modelling and prediction of transport behaviour of PFAS through various systems. Here we present a procedure for using a foam fractionation method to experimentally determine the PFAS adsorption behaviour at ng/L and µg/L concentrations in the presence of salts. The equilibrium air-water adsorption coefficients for PFHxS and PFOA at different salinities and concentrations are experimentally shown to be constant across the range of PFAS concentrations investigated (approx. 0.1-100 µg/L). The adsorption isotherms may consequently be modelled by Henry or Langmuir style equations at these low concentrations.