AgMoO·2HO nanorods under high pressure: In situ Raman spectroscopy.

This work presents a pressure-dependent behavior of silver trimolybdate dihydrate (AgMoO·2HO) nanorods using in situ Raman scattering. The AgMoO·2HO nanorods were obtained by the hydrothermal method at 140 °C for 6 h. The structural and morphological characterization of the sample was performed by powder X-ray diffraction (XRD) and scanning electron microscopy (SEM). Pressure-dependent Raman scattering studies were performed on AgMoO·2HO nanorods up to 5.0 GPa using a membrane diamond-anvil cell (MDAC). The vibrational spectra under high pressure showed splitting and emergence of new bands above 0.5 GPa and 2.9 GPa. Reversible phase transformations under pressure were observed in silver trimolybdate dihydrate nanorods: Phase I - ambient phase (1 atm - 0.5 GPa) → Phase II (0.8 GPa - 2.9 GPa) → Phase III (above 3.4 GPa).