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Heterogeneous Metallaphotocatalytic C(sp)-C(sp) Cross-Coupling Reactions with Integrated Bipyridyl-Ni(II)-Carbon Nitride. | LitMetric
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Heterogeneous Metallaphotocatalytic C(sp)-C(sp) Cross-Coupling Reactions with Integrated Bipyridyl-Ni(II)-Carbon Nitride.

Xiao Dan Qian Yang Liuzhuang Xing Yurong Tang Wentao Wang Yunfei Cai

Org Lett

School of Chemistry and Chemical Engineering, Chongqing Key Laboratory of Theoretical and Computational Chemistry, Chongqing University, Chongqing 400044, China.

Published: June 2023

A fully heterogeneous metallaphotocatalytic C-C cross-coupling of aryl/vinyl halides with alkyl/allyltrifluoroborates has been developed by employing integrated bipyridyl-Ni(II)-carbon nitride as a stable and recyclable bifunctional catalyst. This visible-light-mediated heterogeneous protocol allows for the sustainable synthesis of diverse valuable diarylmethanes and allylarenes in high efficiency.

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http://dx.doi.org/10.1021/acs.orglett.3c01384DOI Listing

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