The increasing use of pesticides in the agriculture fields strengthen the crop production to meet the needs of increasing population. The residues in water and food materials cause several health hazards. Herein, nitrogen-doped carbon quantum dot (N-CQDs) is designed for determination of methiocarb pesticide in vegetables by fluorescent paper sensor and compared the results with fluorimetry. The fluorescent paper-based detection is performed by recording the change in fluorescence of N-CQDs with introduction of methiocarb using smartphone and ImageJ software. Good linear range was acquired for analysis of methiocarb from 10 to 1000 μgL with a low detection limit (LOD) of 3.5 μgL in fluorimetry; and 700-10,000 μgL with a LOD of 500 μgL in fluorescent paper sensor. A better recovery from 92.0 to 95.4% illustrating the selectivity of both methods for analysis of methiocarb in vegetables. Thus, the advantage of using N-CQDs as a fluorescent sensor for analysis of methiocarb in vegetables is instrument free, portable and user-friendly.
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http://dx.doi.org/10.1016/j.saa.2023.122824 | DOI Listing |
Sci Total Environ
October 2024
Center for Reproductive Medicine, Department of Obstetrics and Gynecology, Peking University Third Hospital, No. 49 North Huayuan Road, Haidian District, Beijing 100191, China; National Clinical Research Center for Obstetrics and Gynecology, Beijing 100191, China; Key Laboratory of Assisted Reproduction (Peking University), Ministry of Education, Beijing 100191, China; Beijing Key Laboratory of Reproductive Endocrinology and Assisted Reproductive Technology, Beijing 100191, China; National Clinical Key Specialty Construction Program, P. R. China (2023), China; State Key Laboratory of Female Fertility Promotion, Center for Reproductive Medicine, Department of Obstetrics and Gynecology, Peking University Third Hospital, China. Electronic address:
Current-use pesticides (CUPs), including insecticides, fungicides, and herbicides, are extensively employed in agriculture to manage pests, diseases, and weeds. Nonetheless, their widespread application raises significant concerns regarding potential impacts on human health, particularly with reproductive health. This study focuses on exploring the landscape of CUP exposure among pre-pregnancy women.
View Article and Find Full Text PDFJ Pharm Biomed Anal
August 2024
Instituto Nacional de Medicina Legal e Ciências Forenses, I.P., Delegação do Sul, Portugal.
Pesticides play an important role in forensic toxicology and are usually classified as a single class of chemicals. Despite their commonly perceived unity, pesticides encompass a spectrum of compounds, including organophosphates, carbamates, pyrethroids or organochlorines, among others, each with varying degrees of toxicity. Pesticide analysis in post-mortem samples can be difficult due to the complexity of the samples and to the high toxicity of these compounds.
View Article and Find Full Text PDFEnviron Res
May 2024
Department of Environmental Sciences, Informatics and Statistics, Ca' Foscari University of Venice, Via Torino, 155, 30172, Venice Mestre (VE), Italy. Electronic address:
This study investigates for the first time the contamination of water and sediment of the Venice Lagoon by twenty Contaminants of Emerging Concern (CECs): three hormones, six pharmaceutical compounds (diclofenac and five antibiotics, three of which are macrolides), nine pesticides (methiocarb, oxadiazon, metaflumizone, triallate, and five neonicotinoids), one antioxidant (BHT), and one UV filter (EHMC). Water and sediment samples were collected in seven sites in four seasons, with the aim of investigating the occurrence, distribution, and possible emission sources of the selected CECs in the studied transitional environment. The most frequently detected contaminants in water were neonicotinoid insecticides (with a frequency of quantification of single contaminants ranging from 73% to 92%), and EHMC (detected in the 77% of samples), followed by BHT (42%), diclofenac (39%), and clarithromycin (35%).
View Article and Find Full Text PDFSci Total Environ
March 2024
Escola Superior Agrária, Instituto Politécnico de Beja, R. Pedro Soares S/N, 7800-295 Beja, Portugal; Instituto de Ciências da Terra (ICT), Universidade de Évora, 7000-671 Évora, Portugal; GeoBioTec, NOVA School of Science and Technology, Campus da Caparica, 2829-516 Caparica, Portugal. Electronic address:
The presence of pesticides in aquatic ecosystems poses significant risks to non-target organisms, necessitating monitoring and environmental risk assessment. This study aimed to evaluate the dynamics and environmental risk of pesticides in a hydro-agricultural area with intensive agricultural practices, in the Mediterranean region (South of Portugal). Seasonality and location influenced pesticide numbers and concentrations, with the highest levels observed during the dry season.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
October 2023
School of Studies in Chemistry, Pt. Ravishanakar Shukla University, Raipur 492010, CG, India.
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