Non-standard thermostatistical formalisms derived from generalizations of the Boltzmann-Gibbs entropy have attracted considerable attention recently. Among the various proposals, the one that has been most intensively studied, and most successfully applied to concrete problems in physics and other areas, is the one associated with the Sq non-additive entropies. The Sq-based thermostatistics exhibits a number of peculiar features that distinguish it from other generalizations of the Boltzmann-Gibbs theory. In particular, there is a close connection between the Sq-canonical distributions and the micro-canonical ensemble. The connection, first pointed out in 1994, has been subsequently explored by several researchers, who elaborated this facet of the Sq-thermo-statistics in a number of interesting directions. In the present work, we provide a brief review of some highlights within this line of inquiry, focusing on micro-canonical scenarios leading to Sq-canonical distributions. We consider works on the micro-canonical ensemble, including historical ones, where the Sq-canonical distributions, although present, were not identified as such, and also more resent works by researchers who explicitly investigated the Sq-micro-canonical connection.
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http://dx.doi.org/10.3390/e25040591 | DOI Listing |
J Mol Model
February 2024
School of Mechanical Engineering, Guizhou University, Guiyang, 550025, China.
Context: In order to study the effect of ultra-precision machining on the surface quality of hydroxyapatite semiconductor materials as well as the material removal mechanism of hydroxyapatite, the mechanical polishing behaviors of hydroxyapatite at different polishing depths were studied by molecular dynamics method. The results show that the subsurface damage of hydroxyapatite increases with increasing polishing depth. The polishing temperature and the polishing force showed a positive correlation with the polishing depth, and the variation of the polishing force was related to the accumulation-release effect of the potential energy of hydroxyapatite material.
View Article and Find Full Text PDFEntropy (Basel)
March 2023
Facultad de Ciencias Exactas, Departamento de Física, UNLP and CONICET-CCT-IFLP, La Plata 1900, Argentina.
Non-standard thermostatistical formalisms derived from generalizations of the Boltzmann-Gibbs entropy have attracted considerable attention recently. Among the various proposals, the one that has been most intensively studied, and most successfully applied to concrete problems in physics and other areas, is the one associated with the Sq non-additive entropies. The Sq-based thermostatistics exhibits a number of peculiar features that distinguish it from other generalizations of the Boltzmann-Gibbs theory.
View Article and Find Full Text PDFEntropy (Basel)
February 2021
Department of Mathematics and Statistics, Texas Tech University, 1108 Memorial Circle, Lubbock, TX 79409, USA.
The micro-canonical, canonical, and grand canonical ensembles of walks defined in finite connected undirected graphs are considered in the thermodynamic limit of . As infinitely long paths are extremely sensitive to structural irregularities and defects, their properties are used to describe the degree of structural imbalance, anisotropy, and navigability in finite graphs. For the first time, we introduce entropic force and pressure describing the effect of graph defects on mobility patterns associated with the very long walks in finite graphs; navigation in graphs and navigability to the nodes by the different types of ergodic walks; as well as node's fugacity in the course of prospective network expansion or shrinking.
View Article and Find Full Text PDFWhile the Landauer viewpoint constitutes a modern basis to understand nanoscale electronic transport and to realize first-principles implementations of the nonequilibrium Green's function (NEGF) formalism, seeking an alternative picture can be beneficial for the fundamental understanding and practical calculations of quantum transport processes. Herein, introducing a micro-canonical picture that maps the finite-bias quantum transport process to a drain-to-source or multi-electrode optical excitation, the multi-space constrained-search density functional theory (MS-DFT) formalism for first-principles electronic structure and quantum transport calculations is developed. Performing MS-DFT calculations for the benzenedithiolate single-molecule junction, it is shown that MS-DFT and standard DFT-NEGF calculations produce practically equivalent electronic and transmission data.
View Article and Find Full Text PDFPhys Rev E
May 2016
Laboratoire de physique théorique, CNRS, UPMC and École normale supérieure, 24, rue Lhomond, Paris, France.
Distributions of abundances or frequencies play an important role in many fields of science, from biology to sociology, as does the Rényi entropy, which measures the diversity of a statistical ensemble. We derive a mathematical relation between the abundance distribution and the Rényi entropy, by analogy with the equivalence of ensembles in thermodynamics. The abundance distribution is mapped onto the density of states, and the Rényi entropy to the free energy.
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