Additive manufacturing has enabled the fabrication of lightweight complex metamaterials that possess high energy absorption and impact resistance properties. Stents, a typical 3D auxetic material, have significant self-expanding behavior, and their mechanical properties can be finely tuned over a wide range. In this study, we systematically analyzed three distinctive elastic-plastic regions using experimental, numerical simulations, and theoretical analysis, focusing on investigating the energy absorption capability of a designed structure by varying tessellated unit cell numbers in two section views in X- and Y-direction. Two batches of 5 specimens each were 3D printed using FDM techniques. The results showed that designing a self-expanding stent with innovative capabilities was possible, with the yield stress ranging between 1.5 MPa and 2.0 MPa and extended effective elastic moduli derived from the deformation mode of tessellated unit cells. The maximum energy absorption for all structures ranged between 7.1J and 18J, with similar capabilities observed for the designed stents. However, increasing unit cells along the X-direction resulted in a significant increase in SEA, while the Y-direction remained unchanged. Therefore, these structures have a significant influence on areas requiring energy absorption. In addition, they are the ideal class of energy absorbers for cushioning applications. Furthermore, their energy-absorption capacity can be easily tailored to meet specific end-use requirements by varying their structural parameters using unit cell tessellation.
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http://dx.doi.org/10.1016/j.jmbbm.2023.105903 | DOI Listing |
J Chem Phys
January 2025
Institute of Chemistry, ELTE Eötvös Loránd University, Pázmány Péter Sétány 1/A, H-1117 Budapest, Hungary.
Accurate rovibrational molecular models are employed to gain insight in high-resolution into the collective effects and intermolecular processes arising when molecules in the gas phase interact with a resonant infrared (IR) radiation mode. An efficient theoretical approach is detailed, and numerical results are presented for the HCl, H2O, and CH4 molecules confined in an IR cavity. It is shown that by employing a rotationally resolved model for the molecules, revealing the various cavity-mediated interactions between the field-free molecular eigenstates, it is possible to obtain a detailed understanding of the physical processes governing the energy level structure, absorption spectra, and dynamic behavior of the confined systems.
View Article and Find Full Text PDFPhys Chem Chem Phys
January 2025
Physics Department, Khalifa University, Abu-Dhabi, United Arab Emirates.
The spectrum of carbon monoxide is important for astrophysical media, such as planetary atmospheres, interstellar space, exoplanetary and stellar atmospheres; it also important in plasma physics, laser physics and combustion. Interpreting its spectral signature requires a deep and thorough understanding of its absorption and emission properties. A new accurate spectroscopic model for the ground and electronically-excited states of the CO molecule computed at the aug-cc-pV5Z CASSCF/MRCI+Q level is reported.
View Article and Find Full Text PDFChempluschem
January 2025
Department of Chemical Engineering, Indian Institute of Science Education and Research Bhopal, Bhopal, 462066, Madhya Pradesh, India.
The agricultural sector of any country plays a pivotal role in its economy. Irrigation and the provision of appropriate nutrient levels in soil are essential for optimizing plant growth and enhancing crop productivity. To support the increasing need for food due to the growing population worldwide, synthetic fertilizers have been widely used in the agricultural sector.
View Article and Find Full Text PDFMater Horiz
January 2025
Institute of Physics and Astronomy, University of Potsdam, Karl-Liebknecht-Straße 24/25, 14476, Germany.
Two-dimensional transition metal dichalcogenides (2D TMDCs) can be combined with organic semiconductors to form hybrid van der Waals heterostructures. Specially, non-fullerene acceptors (NFAs) stand out due to their excellent absorption and exciton diffusion properties. Here, we couple monolayer tungsten diselenide (ML-WSe) with two well performing NFAs, ITIC, and IT-4F (fluorinated ITIC) to achieve hybrid architectures.
View Article and Find Full Text PDFNarra J
December 2024
Eijkman Research Center for Molecular Biology, National Research and Innovation Agency (BRIN), Bogor, Indonesia.
Nephrotic syndrome, a multifaceted medical condition characterized by significant proteinuria, has recently prompted a reorientation of research efforts toward B-cell-mediated mechanisms. This shift underscores the pivotal role played by B-cells in its pathogenesis. The aim of this study was to explore potential therapeutic pathways, with specific attention given to compounds found in , including withanolides, such as physalins, which constitute one of the five distinct withanolide subgroups identified in .
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