AI Article Synopsis
- Carbon anions are created by adding Grignard reagents to vinyl phosphinates, leading to new organophosphorus compounds with varied carbon structures.
- Different electrophilic reagents, such as acids and alkyl halides, were utilized in the modification process, resulting in various products, including bis-alkylated compounds.
- Applying the reaction to vinyl phosphine oxides resulted in substitution reactions or polymerization instead of just addition, highlighting the versatility of the methods.
Article Abstract
Carbon anions formed the addition of Grignard reagents to -vinyl phosphinates were modified with electrophilic reagents to afford organophosphorus compounds with diverse carbon skeletons. The electrophiles included acids, aldehydes, epoxy groups, chalcogens and alkyl halides. When alkyl halides were used, bis-alkylated products were afforded. Substitution reactions or polymerization occurred when the reaction was applied to vinyl phosphine oxides.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC10167796 | PMC |
| http://dx.doi.org/10.1039/d3ra02409a | DOI Listing |
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