Iron(III)-Catalyzed Carboannulations of Homopropargylic Alcohols: A One-Pot General Synthesis of 4-(2,2-Diarylvinyl)quinolines and 4-(2,2-Diarylvinyl)-2-chromenes.

A simple and efficient approach for the general synthesis of 4-(2,2-diarylvinyl)quinolines and 4-(2,2-diarylvinyl)-2-chromenes has been developed using Fe(III)-catalyzed intramolecular annulations of homopropargyl substrates and , respectively. The high yields (up to 98%) achieved using simple substrates, an environmentally benign low-cost catalyst, and less hazardous reaction conditions make the methodology inherently attractive.