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Direct Access to αβ-Alkynylamides via Pd-Catalyzed Carbonylation of Terminal Alkynes with Amines Using Chloroform as the CO Surrogate. | LitMetric

AI Article Synopsis

Article Abstract

We describe the first-time use of a palladium-di(1-adamantyl)--butylphosphine catalytic system for the synthesis of alk-2-ynamides from terminal alkynes via aminocarbonylation reaction. This method avoids the direct use of toxic CO gas by utilizing chloroform as an in situ CO source. The aminocarbonylation of both aromatic and aliphatic electron-rich alkyne nucleophiles is reported for the first time. The mild condition provides alk-2-ynamides within 50 min under microwave irradiation at 80 °C.

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http://dx.doi.org/10.1021/acs.joc.3c00460DOI Listing

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