Ultrasonic electroplating produces various effects, including refinement of the plating film structure, by generating localized agitation through cavitation bubbles. However, details of the agitation mechanism have not been clarified because ultrasonic cavitation is very small in scale and occurs rapidly, and its reproducibility is low. Therefore, using laser-induced cavitation, which can generate cavitation similar to ultrasonic waves with high reproducibility, the author attempted to elucidate the conditions and frequency of cavitation generation that affect the agitation phenomenon in ultrasonic electroplating. By controlling the laser irradiation position, three different cavitation conditions were established, and the microstructures of the plated films produced were compared. Microstructural refinement was the most advanced under the condition of microjet generation. The frequency of cavitation generation at any position in the ultrasonic electroplating was estimated to be < 1 Hz.
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http://dx.doi.org/10.1016/j.ultsonch.2023.106432 | DOI Listing |
ACS Appl Mater Interfaces
December 2024
School of Materials Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang 212000, Jiangsu, China.
Bacterial adhesion, colonization, and spread on aluminum alloy surfaces pose significant risks to human health and public safety. To address these issues, this investigation employed an ultrasonic-assisted electrodeposition method to synthesize long-lasting antibacterial Cu-TiO nanocomposite coatings on porous anodized aluminum oxide (AAO) substrates. Leveraging the cavitation effect of ultrasound, this approach fostered the dispersive incorporation of TiO nanoparticles into the resulting composite coating, thereby expediting the crystallization process of electrodeposition and refining the granular structure.
View Article and Find Full Text PDFJ Hazard Mater
July 2024
School of Environment and Civil Engineering, Research Center for Eco-Environmental Engineering, Dongguan University of Technology, Dongguan 523106, Guangdong, China; Guangdong Provincial Key Laboratory of Intelligent Disaster Prevention and Emergency Technologies for Urban Lifeline Engineering, Dongguan 523106, Guangdong, China. Electronic address:
The complex of heavy metals and organic acids leads to high difficulty in heavy metals separation by traditional technologies. Meanwhile, alkaline precipitation commonly used in industry causes the great consumption of resources and extra pollution. Herein, the effective decomplexation of Cu(Ⅱ)-EDTA and synchronous recycling of Cu were realized by contact-electro-catalysis (CEC) coupled with capacitive deionization (CDI) innovatively.
View Article and Find Full Text PDFUltrason Sonochem
June 2023
New Materials Research Laboratory, Nippon Steel Corporation, Chiba 293-8511, Japan. Electronic address:
Ultrasonic electroplating produces various effects, including refinement of the plating film structure, by generating localized agitation through cavitation bubbles. However, details of the agitation mechanism have not been clarified because ultrasonic cavitation is very small in scale and occurs rapidly, and its reproducibility is low. Therefore, using laser-induced cavitation, which can generate cavitation similar to ultrasonic waves with high reproducibility, the author attempted to elucidate the conditions and frequency of cavitation generation that affect the agitation phenomenon in ultrasonic electroplating.
View Article and Find Full Text PDFACS Appl Mater Interfaces
March 2023
Institute for Multiscale Thermofluids, School of Engineering, The University of Edinburgh, Edinburgh EH9 3FD, Scotland, U.K.
Wetting plays a major role in the close interactions between liquids and solid surfaces, which can be tailored by modifying the chemistry as well as the structures of the surfaces' outermost layer. Several methodologies, such as chemical vapor deposition, physical vapor deposition, electroplating, and chemical reactions, among others, have been adopted for the alteration/modification of such interactions suitable for various applications. However, the fabrication of low-contact line-pinning hydrophobic surfaces via simple and easy methods remains an open challenge.
View Article and Find Full Text PDFMicromachines (Basel)
December 2022
Houzhou Yueqiu Motor Co., Ltd., Houzhou 313009, China.
Electroplating nanocrystallite Ni coating can improve the mechanical properties of the metal structure surface, which is widely used in fabricating metal MEMS devices. Because of the large internal compressive stress caused by the oxidation layer of the substrate surface, the Ni coating easily falls off from the substrate surface. To solve this bonding problem, the ultrasonic assisted electrochemical potential activation method was applied.
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