The first phthalocyanine-manganese-oxo intermediate was successfully generated by visible-light photolysis of chlorate or nitrite manganese(III) precursors, and its reactivity towards organic substrates was kinetically probed and compared with other related porphyrin-metal-oxo intermediates.
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Photochemical generation and reactivity of a new phthalocyanine-manganese-oxo intermediate.
Chem Commun (Camb)
May 2023
Department of Chemistry, Western Kentucky University, 1906 College Heights Blvd., Bowling Green, Kentucky, USA.
The first phthalocyanine-manganese-oxo intermediate was successfully generated by visible-light photolysis of chlorate or nitrite manganese(III) precursors, and its reactivity towards organic substrates was kinetically probed and compared with other related porphyrin-metal-oxo intermediates.
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