Implementing the dual-ligand strategy, a microporous Zn-based MOF 1 with nitro and amino groups was effectively produced. The activated interconnected pores of 1 exhibited high CH uptake capacity and preferential adsorption behaviour for CH over CO, as identified by the experiments and simulations. This work provides a new approach for designing and synthesizing the MOFs with desired structures and properties by optimizing their pore environment the dual-ligand strategy.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/d3cc01566a | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Targeted Delivery Strategy of Indocyanine Green-Mitoxantrone Loaded Liposomes Co-Modified with BTP-7 and BR2 For the Treatment of Glioma.
Pharm Dev Technol
January 2025
Guangxi Key Laboratory of Special Biomedicine; School of Medicine, Guangxi University, Nanning, 530004, China.
Article Synopsis
- The study focuses on creating a new drug delivery system using dual-ligand-modified liposomes to target glioma, with the goal of overcoming the blood-brain barrier and improving drug effectiveness.
- Researchers used a specific technique to prepare liposomes that co-load a photosensitizer (ICG) and a chemotherapeutic drug (MTO), and tested their properties and ability to penetrate the blood-brain barrier while targeting glioma cells.
- Results showed that the modified liposomes were stable, capable of effectively penetrating the blood-brain barrier, concentrating in glioma cells, and exhibited strong anti-tumor effects, highlighting their potential in improving glioma treatment.
Catalyst Improved Stereoselectivity and Regioselectivity Control to Access Completely Alternating Poly(lactic-co-glycolic acid) with Enhanced Properties.
Angew Chem Int Ed Engl
December 2024
Qingdao Institute of BioEnergy and Bioprocess Technology Chinese Academy of Sciences, Bio-based Materials, Songling Road 189., 266101, Qingdao, CHINA.
The poly(lactic-co-glycolic acid) (PLGA) with completely alternating sequence has attracted growing attention as an ideal candidate in controlled drug delivery. However, the approach to completely alternating PLGA remains a challenge. Herein, we report the successful synthesis of completely alternating PLGA via highly regioselective and stereoselective ring-opening polymerization.
View Article and Find Full Text PDFCopper-based fluorescent nanozyme used to construct a ratiometric sensor for visual detection of thiophanate methyl.
Talanta
December 2024
Key Laboratory of Catalytic Conversion and Clean Energy in Universities of Shandong Province, School of Chemistry and Chemical Engineering, Qufu Normal University, Qufu City, 273165, Shandong, China. Electronic address:
Although nanozyme has shown great potential in designing fluorescent assays for pesticide residue, most of them are based on single emission, thus affecting the detection accuracy. Herein, a copper-based fluorescent nanozyme (Cu-BH) synthesized with dual-ligand, integrating fluorescence and oxidase-mimic into one spherical nanomaterial, was used firstly to establish a ratiometric approach for visual detection of thiophanate methyl (TM). Cu-BH possesses excellent oxidase-like activities, triggering the oxidation of colorless o-phenylenediamine (OPD) into yellow luminescent products (oxOPD, λem = 564 nm).
View Article and Find Full Text PDFDual-ligand engineered CoNi alloy/N-doped carbon nanotubes bifunctional ORR/OER electrocatalyst for long-lifespan rechargeable Zn-air batteries.
J Colloid Interface Sci
December 2024
College of Urban and Environmental Sciences, Huangshi Key Laboratory of Prevention and Control of Soil Pollution, Hubei Normal University, Huangshi 435002, PR China. Electronic address:
The development of carbon-encapsulated alloy catalysts, through a rational design that integrates highly active Me-N-C sites, is essential for improving the reaction kinetics of both oxygen reduction (ORR) and oxygen evolution reactions (OER). This advancement is pivotal for the progression of efficient rechargeable zinc-air batteries (RZABs). In this study, we investigates a CoNi alloy decorated N-doped carbon nanotube (CoNi-NCNT) electrocatalyst using a dual-ligand strategy.
View Article and Find Full Text PDFSelective Hydroformylation of 1,3-Butadiene to Adipic Aldehyde Enabled by a Ligand-Relay Catalysis.
J Org Chem
December 2024
Key Laboratory of Photoelectric Conversion and Utilization of Solar Energy, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, China.
Article Synopsis
- * A new dual ligand-relay catalysis approach is proposed, involving a two-step, one-pot process that uses two biphosphite ligands to enhance the reaction efficiency and selectivity.
- * This method achieved up to 65.9% selectivity for adipic aldehyde, with full conversion of 1,3-butadiene, surpassing previous catalysis systems, and also produced 26.5% selectivity for -valeraldehyde as a useful byproduct.
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!