The invariant imbedding (IIM) T-matrix method has shown great potential in light scattering field. However, the T-matrix need to be calculated through the matrix recurrence formula derived from the Helmholtz equation, thus its computational efficiency is much lower than Extended Boundary Condition Method (EBCM). To alleviate this problem, the Dimension-Variable Invariant Imbedding (DVIIM) T-matrix method is presented in this paper. Compared with the traditional IIM T-matrix model, the dimensions of the T-matrix and relevant matrices are gradually increasing as the iteration performed step by step, thus the unnecessary operations of large matrices can be avoided in early iterations. To optimally determine the dimension of these matrices in each iterative calculation, the spheroid-equivalent scheme (SES) is also proposed. The effectiveness of the DVIIM T-matrix method is validated from the modeling accuracy and calculation efficiency. The simulation results show that compared with traditional T-matrix method, its modeling efficiency can be improved notably, especially for the particles with large size and aspect ratio, where for the spheroid with a aspect ratio of 0.5, the computational time is cut down by 25%. Though the dimension of the T matrix is cut down in the early iterations, the computational precision of DVIIM T-matrix model is not decreased notably, and a good agreement is achieved between the calculation results of DVIIM T-matrix method, IIM T-matrix method and other well-validated models (like EBCM and DDACSAT), where the relative errors of the integral scattering parameters (e.g., extinction, absorption, scattering cross sections) are generally less than 1%.
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http://dx.doi.org/10.1364/OE.472809 | DOI Listing |
Sci Rep
September 2024
School of Information Science and Engineering, Henan University of Technology, Zhengzhou, 450001, China.
The existing numerical models generally employ sulfate instead of nitrate to simulate the scattering properties of aerosol, the corresponding radiative deviation needs to be evaluated urgently. Moreover, the sophisticated mixture of nitrate, sulfate, and mineral particles is formed through a series of chemical reactions, which makes it extremely challenging to understand the scattering properties of atmospheric aerosols. In this study, the core-shell ellipsoid model is used to flexibly characterize the morphology and mixed structures of nitrate, sulfate, and mineral in the fine mode radius range.
View Article and Find Full Text PDFThe unique physical and chemical properties make metallic nanoparticles promising for broad applications in many fields. Exploring the dynamics of metallic nanoparticles in optical traps is crucial for exploiting optical tweezers to advance the applications of metallic particles. In this paper, we present a detailed study of the annular optical trapping of gold nanoparticles with azimuthal polarization.
View Article and Find Full Text PDFJ Chem Theory Comput
June 2024
Laboratoire de Chimie et Physique Quantiques (UMR 5626), Université de Toulouse, CNRS, UPS, Toulouse 31062, France.
Upon ionization of an atom or a molecule, another electron (or more) can be simultaneously excited. These concurrently generated states are called "satellites" (or shakeup transitions) as they appear in ionization spectra as higher-energy peaks with weaker intensity and larger width than the main peaks associated with single-particle ionizations. Satellites, which correspond to electronically excited states of the cationic species, are notoriously challenging to model using conventional single-reference methods due to their high excitation degree compared to the neutral reference state.
View Article and Find Full Text PDFParticle dispersed coatings with gradient distributions, resulting from either gravity or artificial control, are frequently encountered in practical applications. However, most current studies investigating the optical properties of coatings use the uniform model (uniform single layer assumption), overlooking the gradient distribution effects. Given the pervasiveness of gradient distributions and the widespread use of the uniform model, it is imperative to evaluate applicability conditions of the uniform model in practical applications.
View Article and Find Full Text PDFJ Environ Sci (China)
April 2024
State Key Laboratory of Atmospheric Boundary Layer Physics and Atmospheric Chemistry, Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing 100029, China; College of Earth and Planetary Sciences, University of Chinese Academy of Sciences, Beijing 100049, China; Center for Excellence in Regional Atmospheric Environment, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China.
We developed a single-particle optical particle counter with polarization detection (SOPC) for the real-time measurement of the optical size and depolarization ratio (defined as the ratio of the vertical component to the parallel component of backward scattering) of atmospheric particles, the polarization ratio (DR) value can reflect the irregularity of the particles. The SOPC can detect aerosol particles with size larger than 500 nm and the maximum particle count rate reaches ∼1.8 × 10 particles per liter.
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