Cryogenically cooled Fe:ZnSe-based chirped pulse amplifier at 4.07 µm.

A femtosecond chirped pulse amplifier based on cryogenically cooled Fe:ZnSe was demonstrated at 333 Hz-33 times higher than previous results achieved at near-room-temperature. The long upper-state lifetime allows free-running, diode-pumped Er:YAG lasers to be used as pump lasers. 250-fs, 4.59-mJ pulses are produced with a center wavelength of 4.07 µm, which avoids strong atmospheric CO absorption that cuts on around 4.2 µm. It is therefore possible to operate the laser in ambient air with good beam quality. By focusing the 18-GW beam in air, harmonics up to the ninth order were observed indicating its potential for use in strong-field experimentation.