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Crystal structure and Hirshfeld surface analysis of bis-(μ-4--but-oxy-4-oxobut-2-en-2-olato)bis-[(4--but-oxy-4-oxobut-2-en-2-olato)ethano-lzinc(II)]. | LitMetric

The mol-ecular and crystal structure of the title binuclear Zn complex, [Zn(CHO)(CHOH)], with enolated anionic -butyl-aceto-acetate and ethanol was analysed. The coordination polyhedra of the Zn atoms are distorted octa-hedra formed by six oxygen atoms that belong to three ligand mol-ecules and a coordinated ethanol mol-ecule. In the crystal phase, alternating layers can be distinguished parallel to the plane. A Hirshfeld surface analysis showed that there are no strong inter-molecular inter-actions in the structure. The most significant contributions to the overall crystal packing are from H⋯H inter-molecular contacts.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC10162079PMC
http://dx.doi.org/10.1107/S2056989023003377DOI Listing

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