The increasing depletion of oil resources and the environmental problems caused by using much fossil energy in the rapid development of society. The bio-oil becomes a promising alternative energy source to fossil. However, bio-oil cannot be directly utilized, owing to its high proportion of oxygenated compounds with low calorific value and poor thermal stability. Catalytic hydrodeoxygenation (HDO) is one of the most effective methods for refining oxygenated compounds from bio-oil. HDO catalysts play a crucial role in the HDO reaction. This review emphasizes the description of the main processing of HDO and various catalytic systems for bio-oil, including noble/non-noble metal catalysts, porous organic polymer catalysts, and polar solvents. A discussion based on recent studies and evaluations of different catalytic materials and mechanisms is considered. Finally, the challenges and future opportunities for the development of catalytic hydrodeoxygenation for bio-oil upgradation are looked forward.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1016/j.ijbiomac.2023.124773 | DOI Listing |
Waste Manag
January 2025
School of Chemical Engineering, University of Birmingham, B15 2TT, Birmingham, UK.
Recycling waste to produce liquid fuels for the automotive and aviation industries is a major global concern, especially in light of the ongoing energy crisis. Because waste is used in thermal conversion processes, the resulting liquid products often require additional processing to reduce their density and viscosity, and to remove oxygenated compounds or pollutants that hinder further utilization. Catalytic hydrogenolytic reactions such as hydrodeoxygenation (HDO) and hydrocracking (HC) have been extensively applied to upgrade pyrolysis oils.
View Article and Find Full Text PDFChemSusChem
January 2025
Department of Chemistry, Materials, and Chemical Engineering "Giulio Natta", Politecnico di Milano, Piazza Leonardo da Vinci 32, IT-20133, Milano, Italy.
The conversion of bio-based molecules into valuable chemicals is essential for advancing sustainable processes and addressing global resource challenges. However, conventional catalytic methods often demand harsh conditions and suffer from low product selectivity. This study introduces a series of bifunctional PdPt catalysts supported on TiO, designed for achieving selective and mild-temperature catalysis in biomass conversion.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023, China.
The hydrodeoxygenation of amide to amine is one of the most important amine synthetic approaches in chemical engineering. However, low amide reactivity and poor amine selectivity remain big challenges for catalytic hydrodeoxygenation of amides. Here, Ru-VO/TiO catalysts with different V/Ru atomic ratios were prepared with the sequential impregnation method.
View Article and Find Full Text PDFDalton Trans
December 2024
Ruprecht-Karls-Universität Heidelberg, Anorganisch-Chemisches Institut, Im Neuenheimer Feld 270, Heidelberg 69120, Germany.
Bis(catecholato)silanes were showcased as strong Lewis acids, while their inherent redox activity remained unexplored in this context. In the present work, we study the oxidation of monomeric bis(3,6-di--butyl-catecholato)silane (1), leading to the Lewis superacidic radicalic silylium ionradical 1˙+ (FIA 784 kJ mol). Oxidation of 1 with [N(-CHBr)][B(CF)] yielded [1][B(CF)], displaying strong catalytic activity in the Friedel-Crafts-dimerization, hydrodeoxygenation and carbonyl-olefin-metathesis.
View Article and Find Full Text PDFJACS Au
November 2024
Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China.
The chemical upcycling of plastic wastes by converting them into valuable fuels and chemicals represents a sustainable approach as opposed to landfilling and incineration. However, it encounters challenges in dealing with mixed plastic wastes due to their complex composition and sorting/cleaning costs. Here, we present a one-pot hydrodeoxygenation (HDO) method for converting mixed plastic wastes containing poly(ethylene terephthalate) (PET), polycarbonate (PC), and poly(phenylene oxide) (PPO) into sustainable naphthenes under mild reaction conditions.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!