Surface Morphing of Azopolymers toward Advanced Anticounterfeiting Enabled by a Two-Step Method: Light Writing and Then Reading in Liquid.

Surface morphing of organic materials is necessary for advances in semiconductor processing, optical gratings, anticounterfeiting etc., but it is still challenging, especially for its fundamental explanation and further applications like advanced anticounterfeiting. Here, we report one strategy to acquire surface deformation of the liquid-crystalline azopolymer film using a two-step method: selective photoisomerization of azopolymers and then solvent development. In the first step, surface tension of the polymer film can be patterned by the selective photoisomerization of azopolymers, and then in the second step, the flowing solvent drags the underlying polymer to transport, leading to the formation of surface deformation. Interestingly, the direction of mass transport is opposite to the traditional Marangoni flow, and the principle of solvents' choice is the matching of surface tensions between the azopolymer and the solvent. The two-step method shows characteristics of efficient surface morphing, which could be applied in advanced anticounterfeiting by the way of photomask-assistant information writing or microscale direct writing, and then reading in a specific liquid environment. This paves a new way for understanding the mechanism of mass transport toward numerous unprecedented applications using various photoresponsive materials.