Correction for 'Self-assembly of tripyrazolate-linked [ML] cages for the selective sensing of HSO and gaseous SO by turn-on fluorescence' by Peipei Wang , , 2023, https://doi.org/10.1039/d3dt00083d.
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Correction: Self-assembly of tripyrazolate-linked [ML] cages for the selective sensing of HSO and gaseous SO by turn-on fluorescence.
Dalton Trans
May 2023
Analysis and Testing Center, Beijing Institute of Technology, Beijing 102488, China.
Correction for 'Self-assembly of tripyrazolate-linked [ML] cages for the selective sensing of HSO and gaseous SO by turn-on fluorescence' by Peipei Wang , , 2023, https://doi.org/10.1039/d3dt00083d.
View Article and Find Full Text PDFSelf-assembly of tripyrazolate-linked [ML] cages for the selective sensing of HSO and gaseous SO by turn-on fluorescence.
Dalton Trans
May 2023
Center of Excellence for Environmental Safety and Biological Effects, Beijing Key Laboratory for Green Catalysis and Separation, Department of Chemistry and Biology, School of Life Science and Chemistry, Faculty of Environment and Life, Beijing University of Technology, Beijing, 100124, China.
Owing to their structural designability and tuneable properties, supramolecular metal-organic complexes have recently emerged as promising candidates for the sensing and detection of molecules and anions. Herein, we synthesised three tripyrazolate-linked [ML] metallocages with the formulas [(bpyPd)L](NO) (1), [(dmbpyPd)L](NO) (2), and [(phenPd)L](NO) (3) (HL = tris(4-(5-(trifluoromethyl)-1-pyrazol-3-yl)phenyl)amine, bpy = 2,2'-bipyridine, dmbpy = 4,4'-dimethylbipyridine, phen = 1,10-phenanthroline). Crystallography revealed that metal-directed coordination and the bidentate chelate behaviour of the ligand induced the self-assembly of supramolecular metal-organic cages.
View Article and Find Full Text PDFSelf-assembly of tripyrazolate-linked macrotricyclic M(12)L(4) cages with dimetallic clips.
Org Lett
March 2007
State Key Laboratory of Polymer Physics and Chemistry, Institute of Chemistry, and Graduate School of the Chinese Academy of Sciences, Beijing, China.
[structure: see text]. The self-assembly in aqueous solution of tripyrazolate trianion linkers (H3L = 1 and 2) with coordinated dimetallic clips leads to the formation of Pd12L4 cages with interior cavities of 1800 Angstroms3 and 1500 Angstroms3, respectively, confirmed by 1H NMR, 13C NMR, cold spray ionization mass spectrometry (CSI-MS), and single-crystal X-ray analysis.
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