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Glass Transition Temperatures of Organic Mixtures from Isoprene Epoxydiol-Derived Secondary Organic Aerosol. | LitMetric

Glass Transition Temperatures of Organic Mixtures from Isoprene Epoxydiol-Derived Secondary Organic Aerosol.

J Phys Chem A

Department of Atmospheric Sciences, Texas A&M University, Eller O&M Building, 1204, 3150 TAMU, 797 Lamar Street, College Station, Texas 77843, United States.

Published: May 2023

AI Article Synopsis

Article Abstract

The phase states and glass transition temperatures () of secondary organic aerosol (SOA) particles are important to resolve for understanding the formation, growth, and fate of SOA as well as their cloud formation properties. Currently, there is a limited understanding of how changes with the composition of organic and inorganic components of atmospheric aerosol. Using broadband dielectric spectroscopy, we measured the of organic mixtures containing isoprene epoxydiol (IEPOX)-derived SOA components, including 2-methyltetrols (2-MT), 2-methyltetrol-sulfate (2-MTS), and 3-methyltetrol-sulfate (3-MTS). The results demonstrate that the of mixtures depends on their composition. The Kwei equation, a modified Gordon-Taylor equation with an added quadratic term and a fitting parameter representing strong intermolecular interactions, provides a good fit for the -composition relationship of complex mixtures. By combining Raman spectroscopy with geometry optimization simulations obtained using density functional theory, we demonstrate that the non-linear deviation of as a function of composition may be caused by changes in the extent of hydrogen bonding in the mixture.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC10863072PMC
http://dx.doi.org/10.1021/acs.jpca.2c08936DOI Listing

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