The front cover artwork is provided by Prof. Si-Dian Li's group at Shanxi University, China. The image shows the smallest perfect core-shell octahedral borospherene O B@B and its endohedral metallo-borospherene analogs O Be@B and O Zn@B obtained at first-principles theory. Read the full text of the Research Article at 10.1002/cphc.202200947.
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http://dx.doi.org/10.1002/cphc.202300222 | DOI Listing |
ACS Appl Mater Interfaces
December 2024
Food Science Program, University of Missouri, Columbia, Missouri 65211, United States.
The widespread use of pesticides in agriculture poses food safety and environmental risks, highlighting the need for rapid detection techniques to mitigate contamination. Surface-enhanced Raman spectroscopy (SERS) coupled with machine learning provides a powerful approach for the detection and quantification of multiple pesticides in agricultural products. This study introduces the SERSFormer-2.
View Article and Find Full Text PDFSmall
December 2024
Department of Chemical Engineering & Applied Chemistry, Chungnam National University, Daejeon, 34134, Republic of Korea.
Lithium-sulfur (Li-S) battery is a potential next-generation energy storage technology over lithium-ion batteries for high capacity, cost-effective, and environmentally friendly solutions. However, several issues including polysulfides shuttle, low conductivity and limited rate-capability have hampered its practical application. Herein, a new class of cathode active material with perfect core-shell structure is reported, in which sulfur is fully encapsulated by conductivity-enhancing FeS (named as S@FeS), for high-rate application.
View Article and Find Full Text PDFJ Colloid Interface Sci
January 2025
MOE Key Laboratory of Material Physics and Chemistry under Extraordinary Conditions, School of Chemistry and Chemical Engineering, Northwestern Polytechnical University, Xi'an 710072, PR China.
The unique design of the core-shell heterostructure is significant for obtaining electrode materials with excellent electrochemical properties. In this paper, porous carbon nanofibers (NPC@PPZ) embedded with N-doped porous carbon nanoparticles are used to construct flexible electrodes (NPC@PPZ@BiO). Zeolite imidazole skeleton (ZIF)-8 and poly(methyl methacrylate) (PMMA) derived porous carbon fibers and BiO nanosheets, were utilized as the porous core and multilayer shell, respectively.
View Article and Find Full Text PDFChemphyschem
October 2024
School of Physics and Electronic Science, Guizhou Education University, Guiyang, 550018, China.
In a recent paper (ChemPhysChem, 2023, 24, e202200947), based on the results computed using DFT method, the perfect core-shell octahedral configuration Be@B and Zn@B was reported to be the global minima of the MB(M=Be and Zn) clusters. However, this paper presents the lower energy structures of MB(M=Be and Zn) clusters as a quasi-planar configuration, the Be atom is found to reside on the convex surface of the quasi-planar B isomer, while the Zn atom tends to be attached to the top three B atoms of the quasi-planar B isomer. Our results show that quasi-planar MB(M=Be and Zn) at DFT method have lower energy than core-shell octahedral configuration M@B(M=Be and Zn).
View Article and Find Full Text PDFNanomaterials (Basel)
June 2024
Department of Information Display Engineering, Hanyang University, Seoul 04763, Republic of Korea.
This work highlights the novel approach of incorporating potassium iodide (KI) doping during the synthesis of InP core quantum dots (QDs) to significantly reduce the concentration of vacancies (i.e., In vacancies; ) within the bulk of the core QD and inhibit the formation of InPO at the core QD-ZnSe shell interfaces.
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