To overcome the problem of minority carrier storage time in bipolar transistors, a hot electron transistor (HET) has been proposed. This device has the advantage of high working speed and some complex logic functions can be completed by using one component. Here, we demonstrate a mixed-dimensional HET composed of GaN/AlN microwires, graphene (Gr), and Si. The electrons between GaN/AlN are injected into graphene by an F-N tunneling mechanism to achieve high speed hot electrons, then cross graphene by ballistic transport, and are collected in a nearly lossless manner through a low-barrier Si. Therefore, the device shows a record DC gain of 16.2, a collection efficiency close to the limit of 99.9% based on the graphene hot electron transistor (GHET), an emitter current density of about 68.7 A/cm, and a high on/off current ratio reaching ∼10. Meanwhile, the current saturation range is wide, beyond those of most GHETs. It has potential applications as a power amplifier.
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http://dx.doi.org/10.1021/acsnano.2c12435 | DOI Listing |
Sci Immunol
January 2025
IDIBAPS Biomedical Research Institute, Barcelona, Spain.
Patient-derived NMDAR mAbs combined with single-particle cryo-electron microscopy reveal multiple GluN1 epitopes and distinct functional effects.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
School of Materials, Shenzhen Campus of Sun Yat-sen University, No. 66, Gongchang Road, Guangming District, Shenzhen, Guangdong 518107, P.R. China.
Indium (In) reduction is a hot topic in transparent conductive oxide (TCO) research. So far, most strategies have been focused on reducing the layer thickness of In-based TCO films and exploring TCOs. However, no promising industrial solution has been obtained yet.
View Article and Find Full Text PDFJ Chem Phys
January 2025
MOE Key Laboratory for Non-Equilibrium Synthesis and Modulation of Condensed Matter, School of Physics, Xi'an Jiaotong University, Xi'an 710049, People's Republic of China.
Endohedral and exohedral fullerenes have both been employed as electron acceptors in polymer solar cells (PSCs). However, their differences in hot-electron relaxation dynamics remain unclear. Previous studies have shown that the location of a single atom, whether inside or outside the fullerene cage, results in significant differences in charge distribution.
View Article and Find Full Text PDFSmall
January 2025
Hefei National Research Center for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei, Anhui, 230026, P. R. China.
The ligands in metal-organic framework (MOF) play as light absorption center and transfer photogenerated electrons to metal node through ligand-to-metal charge transfer (LMCT) during photocatalysis, and energy utilization efficiency is strongly restricted by the light inertness of ligands. Herein, a ligand updating strategy is proposed by inserting energy centers to MOFs to activate the inherent ligands, realizing boosting hot electron generation and photocatalytic activities via the cascaded proceeding of energy transfer and charge transfer. By taking PCN-777 (a zeotype mesoporous Zr-containing MOF) as an example, this study shows that the embedded energy center of 1-pyrenecarboxylic acid (PCA) can activate the inherent ligand of PCN-777 through triplet-triplet energy transfer, where triplet excitons would dissociate into photocarriers migrating to the Zr metal cluster via LMCT process.
View Article and Find Full Text PDFACS Nano
January 2025
Department of Chemistry, Emory University, Atlanta, Georgia 30322, United States.
Plasmonic semiconductors exhibit significant potential for harvesting near-IR solar energy, although their mechanisms of plasmon-induced hot electron transfer (HET) are poorly understood. We report a transient absorption study of plasmon-induced HET in p-CuS/CdS type II heterojunctions. Near-IR excitation of the p-CuS plasmon band at ∼1400 nm leads to ultrafast HET into the CdS conduction band with a time constant of <150 fs and a quantum efficiency of ∼0.
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