The nutritional benefits of soluble dietary fiber were mainly attributed to its viscosity and hydration capacity. This study was aimed to investigate the effects of the interaction between konjac glucomannan (KGM) and dihydromyricetin (DMY) on the viscosity and hydration capacity of KGM and the thermal stability of DMY. In contrary to most reports, the addition of DMY to KGM resulted in an increase of viscosity and hydration capacity determined via rheology and nuclear magnetic resonance spectroscopy characterization. Meanwhile the prototype retention of DMY in the presence of heating condition at 60 °C and 100 °C were improved. The radical scavenging capacity of DMY under heating condition was improved at 100 °C via the quantification of ABTS and DPPH. KGM-DMY complex was a non-covalent compound connected by hydrogen bonds which was characterized with particle size analyses, zeta potential analyses, transmission electron microscopy, infrared spectroscopy, X-ray diffraction, and isothermal titration calorimetry. This study was beneficial to the development of polyphenol-enriched nutrition based on KGM, especially in the aspects of satiety, appetite regulation and glucose regulation.
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http://dx.doi.org/10.1016/j.ijbiomac.2023.124666 | DOI Listing |
ACS Nano
January 2025
Centre de recherche du Centre hospitalier de l'Université de Montréal (CRCHUM), Montréal, Québec H2X 0A9, Canada.
The abnormally viscous and thick mucus is a hallmark of cystic fibrosis (CF). How the mutated CF gene causes abnormal mucus remains an unanswered question of paramount interest. Mucus is produced by the hydration of gel-forming mucin macromolecules that are stored in intracellular granules prior to release.
View Article and Find Full Text PDFJ Chem Phys
January 2025
Institute of Theoretical and Applied Mechanics of the Czech Academy of Sciences, Centre Telč, 58856 Telč, Czech Republic.
The time-evolution of dynamics as well as microstructure and mechanical response of phosphate-based geopolymers was probed using x-ray photon correlation spectroscopy and rheological tests. The analyzed relaxation processes in the freshly prepared geopolymer mixes evidenced a q-independent mode of the autocorrelation function, ascribed to density fluctuations of the already established molecular network, undergoing reconfiguration without significant mass transport. Upon curing, the detected motions are localized and depict a system evolving toward structural arrest dominated by slower hyperdiffusive dynamics, characterized by a compressed exponential regime, pointing to a structural relaxation process subjected to internal stresses, in a context of marked dynamical and structural heterogeneity.
View Article and Find Full Text PDFJ Phys Chem B
January 2025
Graduate School of Engineering, Nagoya University, Chikusa, Nagoya 464-8603, Japan.
Molecular dynamics simulation of an aqueous solution of lithium bis(trifluoromethanesulfonyl)amide, LiTFSA, was performed at various concentrations to relate its liquid structure with frequency-dependent shear viscosity. The structure factor exhibited a low- peak that represents a heterogeneous structure composed of water and anion domains, and the lithium ion existed in the water domain due to its strong hydration. The frequency-dependent shear viscosity showed bimodal relaxation, and the relative contribution of the slower mode increased with an increase in the salt concentration.
View Article and Find Full Text PDFMolecules
December 2024
National Key Laboratory of Petroleum Resources and Engineering, China University of Petroleum, Beijing 102249, China.
Hydraulic fracturing of deep, high-temperature reservoirs poses challenges due to elevated temperatures and high fracture pressures. Conventional polymer fracturing fluid (QCL) has high viscosity upon adding cross-linking agents and significantly increases wellbore friction. This paper examines a polymer fracturing fluid with pH response and low friction.
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