All-in-one strategy to prepare molded biochar with magnetism from sewage sludge for high-efficiency removal of Cd(Ⅱ).

Biochar in powder could lead to the separation difficulties after using and easy dispersion by wind with non-necessary consumption during the practical application. The current method for preparing molded biochar is multi-step, tedious, and required exogenous reagents. Moreover, the dehydration of sewage sludge with high water content (>85%) causes expensive production cost, limiting its secondary utilization. Therefore, an "all-in-one" strategy was developed to prepare molded biochar with magnetism by using sewage sludge as endogenetic binder, water source, carbon source, as well as magnetic source, and biomass wastes as water moderator and pore-forming agent. The molded biochar showed high removal capacity towards Cd(Ⅱ) of 456.2 mg/g, which was 6 times higher than the commercial activated carbon in powder (69.1 mg/g). The excellent removal performance of the molded biochar was in linear correlation the O/C ratio (R =0.855), resulting in the complexation with Cd(Ⅱ). DFT calculations indicated the amounts and species of oxygen changed the electron distribution and electron-donation properties of biochar for Cd(Ⅱ). Moreover, the Na exchanges with Cd(Ⅱ) were also an important removal mechanism. This study provided a novel synthesis strategy for the molded biochar with both high particle density and high adsorption capability.