Low-chlorinated fullerenes, dimeric (CCl) and one-dimensional, polymeric (CCl), were obtained by high-temperature (270 °C) chlorination of C with a SbCl/SbCl mixture, as revealed by X-ray crystallography. The compounds were characterized by IR and Raman spectroscopy and theoretical calculations. This is the first observation of a fullerene polymer with single C-C bonding and neutral building blocks.
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http://dx.doi.org/10.1039/d3dt00887h | DOI Listing |
Dalton Trans
May 2023
Chemistry Department, Moscow State University, Leninskie gory, 119991 Moscow, Russia.
Low-chlorinated fullerenes, dimeric (CCl) and one-dimensional, polymeric (CCl), were obtained by high-temperature (270 °C) chlorination of C with a SbCl/SbCl mixture, as revealed by X-ray crystallography. The compounds were characterized by IR and Raman spectroscopy and theoretical calculations. This is the first observation of a fullerene polymer with single C-C bonding and neutral building blocks.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
July 2015
State Key Laboratory of Clean Energy Utilization, The College of Energy Engineering, Zhejiang University, Zheda Road 38#, Hangzhou, 310027, China.
Porous carbon-based materials are commonly used to remove various organic and inorganic pollutants from gaseous and liquid effluents and products. In this study, the adsorption of dioxins on both activated carbons and multi-walled carbon nanotube was internally compared, via series of bench scale experiments. A laboratory-scale dioxin generator was applied to generate PCDD/Fs with constant concentration (8.
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