Phase Transformation and Performance of Mg-Based Hydrogen Storage Material by Adding ZnO Nanoparticles.

ZnO nanoparticles in a spherical-like structure were synthesized via filtration and calcination methods, and different amounts of ZnO nanoparticles were added to MgH via ball milling. The SEM images revealed that the size of the composites was about 2 μm. The composites of different states were composed of large particles with small particles covering them. After the absorption and desorption cycle, the phase of composites changed. The MgH-2.5 wt% ZnO composite reveals excellent performance among the three samples. The results show that the MgH-2.5 wt% ZnO sample can swiftly absorb 3.77 wt% H in 20 min at 523 K and even at 473 K for 1 h can absorb 1.91 wt% H. Meanwhile, the sample of MgH-2.5 wt% ZnO can release 5.05 wt% H at 573 K within 30 min. Furthermore, the activation energies (E) of hydrogen absorption and desorption of the MgH-2.5 wt% ZnO composite are 72.00 and 107.58 KJ/mol H, respectively. This work reveals that the phase changes and the catalytic action of MgH in the cycle after the addition of ZnO, and the facile synthesis of the ZnO can provide direction for the better synthesis of catalyst materials.