This study investigates the enhancement of dairy wastewater treatment using chemical and physical pre-treatments coupled with membrane separation techniques to reduce membrane fouling. Two mathematical models, namely the Hermia and resistance-in-series module, were utilized to comprehend the mechanisms of ultrafiltration (UF) membrane fouling. The predominant fouling mechanism was identified by fitting experimental data into four models. The study calculated and compared permeate flux, membrane rejection, and membrane reversible and irreversible resistance values. The gas formation was also evaluated as a post-treatment. The results showed that the pre-treatments improved UF efficiency for flux, retention, and resistance values compared to the control. Chemical pre-treatment was identified as the most effective approach to improve filtration efficiency. Physical treatments after microfiltration (MF) and UF showed better fluxes, retention, and resistance results than ultrasonic pre-treatment followed by UF. The efficacy of a three-dimensionally printed (3DP) turbulence promoter was also examined to mitigate membrane fouling. The integration of the 3DP turbulence promoter enhanced hydrodynamic conditions and increased the shear rate on the membrane surface, shortening filtration time and increasing permeate flux values. This study provides valuable insights into optimizing dairy wastewater treatment and membrane separation techniques, which can have significant implications for sustainable water resource management. The present outcomes clearly recommend the application of hybrid pre-, main- and post-treatments coupled with module-integrated turbulence promoters in dairy wastewater ultrafiltration membrane modules to increase membrane separation efficiencies.
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http://dx.doi.org/10.3390/ma16083117 | DOI Listing |
J Environ Manage
December 2024
College of Resources and Environment, Chengdu University of Information Technology, Chengdu, 610225, China.
Submerged membrane bioreactor (SMBR) is a promising technology in municipal wastewater treatment, but the membrane fouling has restricted its development. In this study, an integrated submerged ceramic membrane bioreactor (C-SMBR) was constructed to treat domestic wastewater, and the characteristics of membrane fouling and the microbial community structure were investigated. The results showed that the average removal efficiencies of COD, TN, NH-N reached 94.
View Article and Find Full Text PDFChemosphere
December 2024
Department of Environmental Research, Korea Institute of Civil Engineering and Building Technology, Gorang-Daero 283, Ilsanseo-Gu, Goyang, Gyeonggi, 10223, Republic of Korea; Department of Civil and Environment Engineering, University of Science and Technology (UST), 217 Gajeong-Ro, Yuseong-Gu, Daejeon, 34113, Republic of Korea. Electronic address:
Gravity-driven membrane (GDM) systems are increasingly recognized as sustainable and energy-efficient solutions for decentralized water treatment. However, membrane fouling, particularly by organic matter, remains a significant operational challenge, necessitating regular chemical cleaning to maintain performance. The present study was undertaken to investigate the cleaning efficiency of sodium dichloroisocyanurate (NaDCC) tablets, a novel solid-state alternative to conventional liquid cleaning agents such as sodium hypochlorite (NaOCl), sodium lauryl sulfate (SLS), acetic acid, and citric acid.
View Article and Find Full Text PDFEnviron Res
December 2024
School of Environmental Science and Engineering, Tiangong University, State Key Laboratory of Separation Membranes and Membrane Processes, Binshui West Road 399, Xiqing District, Tianjin, 300387, PR China; Cangzhou Institute of Tiangong University, Cangzhou 061000, China. Electronic address:
Biofouling has been one of the major challenges impacting the long-term stable operation of ultrafiltration processes. Irreversible biofouling is considerably more harmful than reversible biofouling. Conductive membrane, as a new technology to effectively mitigate membrane fouling, lack research of controlling irreversible biofouling.
View Article and Find Full Text PDFWater Res
December 2024
Department of Sanitation and Environmental Engineering, School of Engineering, Federal University of Minas Gerais, Avenue Antônio Carlos, 6627, Campus Pampulha, Belo Horizonte, MG, Brazil. Electronic address:
Arsenic (As) enrichment in groundwater stems from natural and hydrogeochemical factors, leading to geological contamination. Groundwater and surface water are interconnected, allowing As migration and surface water contamination. The As contamination poses health risks through contaminated water consumption.
View Article and Find Full Text PDFWater Res
December 2024
Institute for Advanced Membrane Technology (IAMT), Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany. Electronic address:
Calcium (Ca)-enhanced organic matter (OM) fouling of nanofiltration (NF) membranes leads to reduced flux during desalination and requires frequent cleaning. Fouling mechanisms are not fully understood, which limits the development of targeted fouling control methods. This study employed synchrotron-based X-ray fluorescence (XRF) and X-ray absorption near-edge structure (XANES) spectroscopy to quantify the spatial distribution and mass of Ca deposition as well as changes in the Ca coordination environment characteristic of specific fouling mechanisms, respectively.
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