Selecting resonances in molecular scattering by anti-Zeno effect.

J Chem Phys

State Key Laboratory for Mesoscopic Physics and Collaborative Innovation Center of Quantum Matter, School of Physics, Peking University, Beijing 100871, China.

Published: April 2023

Utilizing the anti-Zeno effect, we demonstrate that the resonances of ultracold molecular interactions can be selectively controlled by modulating the energy levels of molecules with a dynamic magnetic field. We show numerically that the inelastic scattering cross section of the selected isotopic molecules in the mixed isotopic molecular gas can be boosted for 2-3 orders of magnitude by modulation of Zeeman splittings. The mechanism of the resonant anti-Zeno effect in the ultracold scattering is based on matching the spectral modulation function of the magnetic field with the Floquet-engineered resonance of the molecular collision. The resulting insight provides a recipe to implement resonant anti-Zeno effect in control of molecular interactions, such as the selection of reaction channels between molecules involving shape and Feshbach resonances, and external field-assisted separation of isotopes.

Download full-text PDF

Source
http://dx.doi.org/10.1063/5.0144665DOI Listing

Publication Analysis

Top Keywords

molecular interactions
8
magnetic field
8
resonant anti-zeno
8
molecular
5
selecting resonances
4
resonances molecular
4
molecular scattering
4
anti-zeno
4
scattering anti-zeno
4
anti-zeno utilizing
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!