Ultramicroporous MOFs enable tight packing of the active functional groups, directly impacting the selective guest-framework interactions. MOFs with pores simultaneously lined by methyl and amine may serve as the ultimate humid CO sorbent. However, structural complexity prevents taking full advantage even in a simple zinc-triazolato-acetate layered-pillared MOF.
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| http://dx.doi.org/10.1039/d3cc01157g | DOI Listing |
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