In this work, we give a characterization of the reservoir computer (RC) by the network structure, especially the probability distribution of random coupling constants. First, based on the path integral method, we clarify the universal behavior of the random network dynamics in the thermodynamic limit, which depends only on the asymptotic behavior of the second cumulant generating functions of the network coupling constants. This result enables us to classify the random networks into several universality classes, according to the distribution function of coupling constants chosen for the networks. Interestingly, it is revealed that such a classification has a close relationship with the distribution of eigenvalues of the random coupling matrix. We also comment on the relation between our theory and some practical choices of random connectivity in the RC. Subsequently, we investigate the relationship between the RC's computational power and the network parameters for several universality classes. We perform several numerical simulations to evaluate the phase diagrams of the steady reservoir states, common-signal-induced synchronization, and the computational power in the chaotic time series inference tasks. As a result, we clarify the close relationship between these quantities, especially a remarkable computational performance near the phase transitions, which is realized even near a nonchaotic transition boundary. These results may provide us with a new perspective on the designing principle for the RC.
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http://dx.doi.org/10.1103/PhysRevE.107.034306 | DOI Listing |
ACS Omega
January 2025
Department of Physics, National Sun Yat-Sen University, Kaohsiung 80424, Taiwan.
Zintl compounds have garnered research interest due to their diverse technological applications. Utilizing first-principles calculations, we performed a systematic study of ABX (A = Li, Na, K, Rb, or Cs; B = Si, Ge, Sn, or Pb; and X = P, As, Sb, or Bi) Zintl materials with the 6 KSnSb-type structure. Notably, six ABX Zintl compounds (RbSiBi, CsSiBi, LiGeBi, KGeBi, RbGeBi, and CsGeBi) were found to have topologically nontrivial phases, as demonstrated by the invariant computed using the hybrid functional HSE06.
View Article and Find Full Text PDFAnal Methods
January 2025
Key Laboratory of Xin'an Medicine of the Ministry of Education, College of Chinese Medicine, School of Pharmacy, Anhui University of Chinese Medicine, Hefei, 230038, P. R. China.
4-Amidogen-1,8-naphthalimide (ANA), a novel pre-column derivatization reagent, has been successfully synthesized and utilized for the highly sensitive analysis of monosaccharides. ANA reacts with the reducing carbonyl groups of saccharides, facilitating monosaccharide detection. The resulting monosaccharide derivatives were meticulously investigated using High-Performance Liquid Chromatography (HPLC) coupled with ultraviolet (UV) spectroscopy.
View Article and Find Full Text PDFLangmuir
January 2025
CNNFM Lab, School of Mechanical Engineering, College of Engineering, University of Tehran, P.O. Box 11155-4563 Tehran, Iran.
This study investigates the impact of cell dynamics on mixing efficiency within a microfluidic droplet, emphasizing the relationship between cell motion, deformability, and resultant asymmetry in velocity and concentration fields. Simulations were conducted for droplets containing encapsulated cells at varying Peclet numbers ( = 100-800) and coupling constants ( = 0.0025, 0.
View Article and Find Full Text PDFJ Phys Chem A
January 2025
University of Göttingen, Institute for Physical Chemistry, Tammannstraße 6, 37077,Göttingen Germany.
Rotational spectroscopy is an excellent tool for structure determination, which can provide additional insights into local electronic structure by investigating the hyperfine pattern due to nuclear quadrupole coupling. Jet-cooled molecules are good experimental benchmark targets for electronic structure calculations, as they are free of environmental effects. We report the rotational spectra of 2-chlorobenzaldehyde, 3-chlorobenzaldehyde, and 4-chlorobenzaldehyde, including a complete experimental description of the nuclear quadrupole coupling constants, which were previously not experimentally determined.
View Article and Find Full Text PDFBiometals
January 2025
I.M. Sechenov First Moscow State Medical University (Sechenov University), Moscow, 119991, Russia.
The objective of the present study was to assess serum and cancerous tissue biometal levels in colorectal cancer (CRC) patients, and its relation to disease severity. A total of 90 CRC patients and 97 controls were involved in the present study. The level of biometals in blood serum and colon tissues (only in CRC cases) was evaluated by inductively-coupled plasma mass-spectrometry.
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