Separating films with both high efficiency and large flux are desperately needed to meet the rising demand for the treatment of oily wastewater, while traditional oil/water separation papers with high separation efficiency usually suffered from low flux due to the unsuitable size of filtration pores. Herein, we report a bio-based porous, superhydrophobic, and antimicrobial hybrid cellulose paper with tunable porous structures for high flux oil/water separation. The size of pores in the hybrid paper can be tuned by both physical supports provided by the chitosan fibers and the chemical shielding supplied by the hydrophobic modification. The hybrid paper with increased porosity (20.73 μm; 35.15 %) and excellent antibacterial properties can efficiently separate a wide range of oil/water mixtures, solely by gravity, with outstanding flux (maximum of 23,692.69 L m h), tiny oil interception, and high efficiency of over 99 %. This work provides new sights in the development of durable and low-cost functional papers for rapid and efficient oil/water separation.
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http://dx.doi.org/10.1016/j.carbpol.2023.120794 | DOI Listing |
ACS Omega
January 2025
Engineering Research Center for Waste Oil Recovery Technology and Equipment, Ministry of Education, Chongqing Technology and Business University, Chongqing 400067, P. R. China.
Numerous oil-water mixtures produced through industrial production processes and daily activities pollute the ecological environment and pose risks to human health. The development of materials with high oil-water mixture separation efficiency can promote the recycling of oil and water resources and effectively prevent environmental pollution caused by their direct discharge. Most of the current oil-water separation materials consist of foam, aerogel, and other porous materials.
View Article and Find Full Text PDFWaste Manag
January 2025
School of Chemistry and Chemical Engineering, Shanxi University, Taiyuan, 030006, China. Electronic address:
Coal fly ash, a waste byproduct of coal-fired power plants rich in silica, is produced in vast quantities, exceeding 750 million tons annually. This abundance underscores the importance of finding sustainable and value-added applications for its reuse. Silver nanoparticle-silica composites represent a class of inorganically hybrid antimicrobial agents as the protection layer of cotton fabrics.
View Article and Find Full Text PDFLangmuir
January 2025
School of Textile Science and Engineering, Tiangong University, Tianjin 300387, China.
Aerogels hold great potential in thermal insulation, catalytic supports, adsorption, and separation, due to their low density, high porosity, and low thermal conductivity. However, their inherent mechanical fragility and limited control functionality pose substantial challenges that hinder their practical use. In this study, a strategy is developed for the fabrication of cross-linked aramid nanofiber aerogels (cANFAs) by combining internanofiber surface cross-linking with ice-templating techniques.
View Article and Find Full Text PDFNano Lett
January 2025
Department of Chemistry, Institute of Biomimetic Materials & Chemistry, Anhui Engineering Laboratory of Biomimetic Materials, Division of Nanomaterials & Chemistry, Hefei National Research Center for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei 230026, China.
The development of viscous-crude oil and water separation technology is important for overcoming pollution caused by oil spills. Although some separators responding to light, electric, and temperature have been proposed, their poor structural homogeneity and inferior controllability, together with weak capillary forces, hinder the rapid salvage of viscous crude oil. Herein, a Joule-heated hydrophobic porous oil/water separator is reported, which has advantages of low energy consumption (169.
View Article and Find Full Text PDFLangmuir
January 2025
State Key Laboratory of Heavy Oil Processing, College of Chemistry and Chemical Engineering, China University of Petroleum (East China), Qingdao 266580, China.
Oil spills and industrial oily wastewater pose serious threats to the environment. A series of modified membranes with special wettability have been widely used for separating oil/water mixtures and emulsions. However, these membranes still face challenges such as the detachment of the modified coatings and membrane fouling.
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