In the title compound, CHNO·CHNO, the bi-cyclo[3.3.1]nonane ring sys-tem adopts a half-chair/twist-boat conformation, with the phenyl rings in equatorial orientations with respect to the piperidine ring. The two oxane rings of the 2-oxabi-cyclo-[2.2.2]octane ring system exhibit a distorted boat conformation. Inter-molecular C-H⋯O and C-H⋯N hydrogen bonds connect the mol-ecules in the crystal, generating layers extending parallel to (100). These layers are connected by C-H⋯π inter-actions. A Hirshfeld surface analysis was per-formed to qu-antify the contributions of the different inter-molecular inter-actions, indicating that the most important contributions to the crystal packing are from H⋯H (52.5%), N⋯H/H⋯N (19.2%), C⋯H/H⋯C (18.8%) and O⋯H/H⋯O (8.3%) inter-actions.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC10088326PMC
http://dx.doi.org/10.1107/S2056989023001718DOI Listing

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