One-Step Synthesis of a Binder-Free, Stable, and High-Performance Electrode; Cu-O|CuP Heterostructure for the Electrocatalytic Methanol Oxidation Reaction (MOR).

Although direct methanol fuel cells (DMFCs) have been spotlighted in the past decade, their commercialization has been hampered by the poor efficiency of the methanol oxidation reaction (MOR) due to the unsatisfactory performance of currently available electrocatalysts. Herein, we developed a binder-free, copper-based, self-supported electrode consisting of a heterostructure of CuP and mixed copper oxides, i.e., cuprous-cupric oxide (Cu-O), as a high-performance catalyst for the electro-oxidation of methanol. We synthesized a self-supported electrode composed of Cu-O|CuP using a two-furnace atmospheric pressure-chemical vapor deposition (AP-CVD) process. High-resolution transmission electron microscopy analysis revealed the formation of 3D nanocrystals with defects and pores. Cu-O|CuP outperformed the MOR activity of individual CuP and Cu-O owing to the synergistic interaction between them. CuP|Cu-O exhibited a highest anodic current density of 232.5 mAcm at the low potential of 0.65 V vs. Hg/HgO, which is impressive and superior to the electrocatalytic activity of its individual counterparts. The formation of defects, 3D morphology, and the synergistic effect between CuP and Cu-O play a crucial role in facilitating the electron transport between electrode and electrolyte to obtain the optimal MOR activity. Cu-O|CuP shows outstanding MOR stability for about 3600 s with 100% retention of the current density, which proves its robustness alongside CO intermediate.