It has been found that the mechanic-electric response of cement-based piezoelectric composites under impact loading is nonlinear. Herein, we prepared a 2-2 cement-based piezoelectric composite material using cutting, pouring, and re-cutting. Then, we obtained the stress-strain and stress-electric displacement curves for this piezoelectric composite under impact loading using a modified split Hopkinson pressure bar (SHPB) experimental apparatus and an additional electrical output measurement system. Based on the micromechanics of the composite materials, we assumed that damage occurred only in the cement paste. The mechanical response relationship of the piezoelectric composite was calculated as the product of the viscoelastic constitutive relationship of the cement paste and a constant, where the constant was determined based on the reinforcement properties of the mechanical response of the piezoelectric composite. Using a modified nonlinear viscoelastic Zhu-Wang-Tang (ZWT) model, we characterized the stress-strain curves of the piezoelectric composite with different strain rates. The dynamic sensitivity and stress threshold of the linear response of the samples were calibrated and fitted. Thus, a mechanic-electric response equation was established for the 2-2 type cement-based piezoelectric composite considering the strain rate effects.
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http://dx.doi.org/10.3390/ma16072702 | DOI Listing |
Biomaterials
January 2025
Department of Orthodontics, Shanghai Ninth People's Hospital, Shanghai Jiao Tong University School of Medicine, Shanghai Jiao Tong University, 500 Quxi Road, Shanghai, 200011, China. Electronic address:
Addressing the concurrent repair of cartilage and subchondral bone presents a significant challenge yet is crucial for the effective treatment of severe joint injuries. This study introduces a novel biodegradable composite scaffold, integrating piezoelectric poly-l-lactic acid (pPLLA) with strontium-enriched silicate bioceramic (SrSiO). This innovative scaffold continually releases bioactive Sr and SiO ions while generating an electrical charge under low-intensity pulsed ultrasound (LIPUS) stimulation, a clinically recognized method.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Guangxi Key Lab of Optical and Electronic Functional Materials and Devices; Collaborative Innovation Center for Exploration of Nonferrous Metal Deposits and Efficient Utilization of Resources; College of Materials Science and Engineering, Guilin University of Technology, Guilin, Guangxi 541004, China.
Piezoelectric energy harvesters (PEHs) have attracted much attention due to their efficient harvesting of vibrational energy from the ambient environment, which demonstrates great potential applications. Unfortunately, their low energy density severely hinders the further development of PEHs. Therefore, it is highly desirable to search for piezoelectric materials with a high transduction coefficient ( × ).
View Article and Find Full Text PDFSmall
December 2024
College of Materials Science and Engineering, Sichuan University, Chengdu, 610064, China.
Piezoelectric materials are increasingly used in portable smart electronics and Internet of Things sensors. Among them, piezoelectric macro fiber composites (MFCs) have attracted much attention due to their architectural simplicity, scalability, and high-power density. However, most MFCs currently use toxic lead-based piezoelectric materials, hindering their applications for bio-friendly intelligent electronics.
View Article and Find Full Text PDFJ Colloid Interface Sci
December 2024
Guangdong Provincial Key Laboratory of New Energy Materials Service Safety, Shenzhen Key Laboratory of Special Functional Materials, College of Materials Science and Engineering, Shenzhen University, Shenzhen 518060, PR China. Electronic address:
Photocatalytic removal of antibiotic such as ciprofloxacin from polluted water is of great value for eco-environment protection. To further enhance the piezoelectric effect in photocatalysis, we designed and synthesized a ternary heterojunction piezoelectric photocatalyst through uniformly loading MoS nanosheets onto BiFeO (BFO) nanofibers, namely MoS/BiS/BFO. Piezoresponse force microscopy and Kelvin probe force microscopy demonstrated its enhanced piezoelectric properties, showing a maximum amplitude displacement of 395.
View Article and Find Full Text PDFAdv Mater
December 2024
Materdicine Lab, School of Life Sciences, Shanghai University, Shanghai, 200444, P. R. China.
The precise manipulation of PANoptosis, a newly defined cell death pathway encompassing pyroptosis, apoptosis, and necroptosis, is highly desired to achieve safer cancer immunotherapy with tumor-specific inflammatory responses and minimal side effects. Nonetheless, this objective remains a formidable challenge. Herein, an "AND" logic-gated strategy for accurately localized PANoptosis activation, utilizing composite 3D-printed bioactive glasses scaffolds integrated with epigenetic regulator-loaded porous piezoelectric SrTiO nanoparticles is proposed.
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