The role of baseflow and stormwater in transport of tire and bitumen particles in Tehran city: A dense urban environment.

Urban stormwater runoff is the main terrestrial source of tire and bitumen particles as emerging pollutants, which have adverse effects on receiving aquatic and terrestrial environments. In this study, the occurrence and characteristics of tire and bitumen particles in four rainfall events and three baseflow had been measured at the end of a dense urban catchment in Tehran metropolis. Particles were classified to 37-300, 300-500, and 500-5000 μm with stainless steel sieves, and hydrogen peroxide 30% was used for digestion of organic matter, following density separation with ZnCl (1.7-1.75 g/mL) to separate tire and bitumen particles from minerals. The type of tire and bitumen particles was determined by Micro-Raman and FTIR ATR. The number of tire and bitumen particles in rainfall events was 3.3-60.5 and 3.5-73 particles/L, respectively, and in the base flow were 0.5-3 and 0.8-6.5 particles/L, respectively. The most abundant size of tire and bitumen particles was 37-300 μm. The highest abundance of tire and bitumen particles was observed during a rainfall event in peak discharge. The results indicate the important role of urban stormwater runoff, where there are high vehicle traffic and high road density, in the release into the environment of bitumen and rubber.