Floating treatment wetlands (FTWs) are a cost-effective ecological engineering tool for the restoration of polluted water bodies. The aims of this work were to evaluate the removal of Cr(III) and Cr(VI) by FTWs using , and to assess Cr accumulation and distribution in plant tissues and sediment. Treatments were 5 and 10 mg L of Cr(III), and 5 and 10 mg L of Cr(VI), with and without FTWs, and biological control (BC) with FTW without Cr addition. Both Cr species were efficiently removed from water in all treatments (Cr removal > 80%). Cr concentration in sediments of treatment without FTWs was significantly higher than in sediments of treatments with FTWs, indicating that was directly involved in Cr removal. In sediment, Cr was mainly bound to the organic matter in all treatments with a low risk of future release under FTW conditions. demonstrated tolerance to both Cr species at 5 and 10 mg L with Cr accumulated mainly in the roots in all treatments. The use of FTWs planted with is a suitable tool to remediate water bodies contaminated with Cr.
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http://dx.doi.org/10.1080/15226514.2023.2199877 | DOI Listing |
Sci Total Environ
January 2025
Department of Chemistry, Physics, Environmental and Soil Sciences, University of Lleida - AGROTECNIO-CERCA Center, Rovira Roure 191, 25198 Lleida, Spain.
There is limited research on the influence of environmental variables on the interactions of biodegradable microplastics with chromium. This study reports the results of adsorption experiments with Cr and poly(lactic acid) (PLA) in synthetic aqueous solutions. It addresses the influence of the initial oxidation state, Cr(III) or Cr(VI), the effects of UV irradiation and the presence of organic matter.
View Article and Find Full Text PDFEnviron Pollut
January 2025
Xi'an Center of Mineral Resources Survey, China Geological Survey, Xi'an, China.
Understanding the geochemical mechanisms governing hexavalent chromium (Cr(VI)) in groundwater is essential for mitigating health risks. However, the processes driving Cr(VI) accumulation and migration in loess regions remain insufficiently understood. This study investigated the occurrence, release, and migration mechanisms of Cr(VI) across different groundwater environmental units (GEUs) in the south-central Loess Plateau, China.
View Article and Find Full Text PDFJ Hazard Mater
December 2024
School of Environment and Resource, Southwest University of Science and Technology, Mianyang, Sichuan 621010, China; Key Laboratory of Solid Waste Treatment and Resource Recycle, Southwest University of Science and Technology, Mianyang, Sichuan 621010, China. Electronic address:
Chromium [Cr(VI)]-induced soil pollution is a serious environmental threat. Bioremediation utilizes specific microbes capable of transforming Cr(VI) into the less toxic Cr(III), however, microbial efficacy can be inhibited by elevated pollutant concentrations and competition from indigenous microbial communities. Thus, this study explored the potential of single and multi-domain microbial consortia encapsulated in alginate to overcome these shortcomings.
View Article and Find Full Text PDFJ Colloid Interface Sci
December 2024
Institute of Chemistry, University of São Paulo, Av. Prof. Lineu Prestes 748, São Paulo 05508-000, Brazil. Electronic address:
In this study, kapok fiber (KF) a hollow and hydrophobic fiber, was modified with cetyltrimethylammonium bromide (CTAB) or cetylpyridinium chloride (CPC), rendering adsorbed amount of ∼0.75 × 10 mol/g. Small-angle X-ray scattering (SAXS) measurements of dry KF/CTAB and KF/CPC evidenced a periodic distance of ∼2.
View Article and Find Full Text PDFMass Spectrom (Tokyo)
December 2024
Department of Applied Chemistry for Environment, School of Science and Technology, Kwansei Gakuin University, Gakuen-Uegahara-1, Sanda, Hyogo 669-1330, Japan.
A simple and rapid analytical method was developed for the simultaneous determination of two chromium species, Cr(III) and Cr(VI), in the environmental waters by high-performance liquid chromatography-inductively coupled plasma-mass spectrometry (HPLC-ICP-MS). This study incorporated a chelating pretreatment with 2,6-pyridinedicarboxylic acid (PDCA) to convert Cr(III) species into a stable Cr(III)-PDCA anion complex, which was then separated from Cr(VI) oxyanion using an anion exchange column. Building on the fundamental analytical approach proposed by Shigeta .
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