While ice has very low solubility for salts compared to water, small amounts of ions are doped into ice crystals. These small ion dopants can alter the fundamental physical and chemical properties of ice, such as its structure and electrical conductivity. Therefore, these results could have a direct impact on the chemical reactivity of ice and ice surfaces. Here, we examine the influence of the uptake of three salts-ammonium chloride (NHCl), sodium chloride (NaCl), and ammonium sulfate [(NH)SO]-on ice Ih formation using capillary electrophoresis. Using both cation and anion modes, we observed and quantified the uptake of individual ions into the ice. Our results indicate that anions have a higher propensity for uptake into ice Ih crystals.
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http://dx.doi.org/10.1063/5.0141057 | DOI Listing |
Nano Lett
January 2025
Department of Physics and Astronomy, Rutgers University, Piscataway, New Jersey 08854, United States.
Pyrochlore materials are known for their exotic magnetic and topological phases arising from complex interactions among electron correlations, band topology, and geometric frustration. Interfaces between different pyrochlore crystals characterized by complex many-body ground states hold immense potential for novel interfacial phenomena due to the strong interactions between these phases. However, the realization of such interfaces has been severely hindered by limitations in material synthesis methods.
View Article and Find Full Text PDFSmall
December 2024
State Key Laboratory of Crystal Materials, Shandong University, Jinan, 250100, P. R. China.
Gel electrolytes have emerged as a promising solution for enhancing the performance of zinc-ion batteries (ZIBs), particularly in flexible devices. However, they face challenges such as low-temperature inefficiency, constrained ionic conductivity, and poor mechanical strength. To address these issues, this study presents a novel PAMCD gel electrolyte with tunable freezing point and mechanical properties for ZIBs, blending the high ionic conductivity of polyacrylamide with the anion interaction capability of β-cyclodextrin.
View Article and Find Full Text PDFFront Endocrinol (Lausanne)
December 2024
Department of Assisted Reproduction, Shanghai Ninth People's Hospital, Shanghai Jiao Tong University School of Medicine, Shanghai, China.
Background: Techniques for sperm cryopreservation have exhibited their potential in male fertility preservation. The use of frozen-thawed sperm in fertilization (IVF) cycles is widespread today. However, many studies reported that cryopreservation might have adverse effects on sperm DNA integrity, motility, and fertilization, probably due to cold shock, intra- and extracellular ice crystals, and excess reactive oxygen species (ROS).
View Article and Find Full Text PDFFood Chem
December 2024
State Key Laboratory of Marine Food Processing and Safety Control, College of Food Science and Engineering, Ocean University of China, Qingdao 266404, PR China; Laboratory for Marine Drugs and Bioproducts, Qingdao Marine Science and Technology Centre, Qingdao 266237, PR China; Qingdao Key Laboratory of Food Biotechnology, Qingdao 266404, PR China; Key Laboratory of Biological Processing of Aquatic Products, China National Light Industry, Qingdao 266404, PR China. Electronic address:
Temperature fluctuations can negatively affect the quality of frozen shrimp. Research on novel cryoprotectants to replace traditional agents (phosphate, etc.) has become a hotspot.
View Article and Find Full Text PDFAdv Mater
December 2024
Department of Chemical and Biological Engineering, Korea University, Seoul, 02841, Republic of Korea.
In this study, a novel phenomenon is identified where precise control of topology and generation of polyglycerol induce the retention of Na ions in biological buffer systems, effectively inhibiting ice crystal growth during cryopreservation. Unlike linear and hyperbranched counterparts, densely-packed hydroxyl and ether groups in 4th-generation dendritic polyglycerol interact with the ions, activating the formation of hydrogen bonding at the ice interface. By inhibiting both intra- and extracellular ice growth and recrystallization, this biocompatible dendritic polyglycerol proves highly effective as a cryoprotectant; hence, achieving the cell recovery rates of ≈134-147%, relative to those of 10% dimethyl sulfoxide, which is a conventional cryoprotectant for human tongue squamous carcinoma (HSC-3) cell line and human umbilical vein endothelial (HUVEC) cells.
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