The first germole-ligated single-molecule magnets are reported, with contrasting properties found for the near-linear sandwich complexes [(η -COT)Ln(η -Cp ] , where Ln=Dy (1 ) or Er (1 ), COT is cyclo-octatetraenyl and Cp is [GeC -2,5-(SiMe ) -3,4-Me ] . Whereas 1 has an energy barrier of 120(1) cm in zero applied field and open hysteresis loops up to 10 K, the relaxation in 1 is characterized by quantum tunneling within the ground state.
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC10947301 | PMC |
| http://dx.doi.org/10.1002/chem.202300567 | DOI Listing |
Publication Analysis
Top Keywords
sandwich complexes
8
dynamic magnetic
4
magnetic properties
4
properties germole-ligated
4
germole-ligated lanthanide
4
lanthanide sandwich
4
complexes germole-ligated
4
germole-ligated single-molecule
4
single-molecule magnets
4
magnets reported
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!