Synergistic coupling of IrNi/Ni(OH)nanosheets with polypyrrole and iron oxyhydroxide layers for efficient electrochemical overall water splitting.

The design of electrocatalysts with excellent activity and stability for overall water splitting is highly desirable, and remains a challenge. Constructing heterojunctions onto the same substrate is beneficial for the integration of a water-splitting reaction. Herein, self-supported IrNi/Ni(OH)@PPy and IrNi/Ni(OH)@FeOOH are fabricated by coupling polypyrrole (PPy) and iron oxyhydroxide (FeOOH) on IrNi/Ni(OH)nanosheets array, respectively. Benefiting from the nanosheet structure, composition, and heterogeneous interface, the as-constructed IrNi/Ni(OH)@PPy and IrNi/Ni(OH)@FeOOH catalysts can efficiently drive the hydrogen evolution reaction and oxygen evolution reaction, respectively. Moreover, the electrolyzer consisting of IrNi/Ni(OH)@PPy and IrNi/Ni(OH)@FeOOH for water splitting requires only a low cell voltage of 1.49 V to deliver 10 mA cm. This study provides a useful strategy for constructing efficient electrocatalysts by synergistic composition modulation and interface engineering.