AI Article Synopsis

  • Researchers successfully installed linkers in thorium-based metal-organic frameworks (Th-MOFs) using a method that preserves the crystalline structure.
  • This process led to a unique observation of framework de-interpenetration, which is a rare phenomenon in these materials.
  • The new technique also significantly increased the ability of the frameworks to adsorb iodine, showcasing its potential for enhancing material properties.

Article Abstract

Post-synthetic linker installation in a single-crystal-to-single-crystal manner was crystallographically demonstrated in thorium-based metal-organic frameworks (Th-MOFs), not only leading to the discovery of an extremely rare framework de-interpenetration, but also representing an unprecedented strategy for boosting iodine adsorption capacity.

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http://dx.doi.org/10.1039/d3cc00278kDOI Listing

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