A general synthetic method towards conjugated microporous polymers with ordered bicontinuous mesostructures.

Chem Commun (Camb)

School of Chemistry and Chemical Engineering, Frontiers Science Center for Transformative Molecules, Shanghai Key Laboratory of Electrical Insulation and Thermal Ageing, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai 200240, China.

Published: April 2023

This work demonstrates a universal approach, based on the self-assembly of block copolymers, for the synthesis of novel conjugated microporous polymers (CMPs) with bicontinuous mesostructures. Three hexaazatriphenylene (Aza)-fused CMPs (Aza-CMPs) with double diamond structures were synthesized. The study broadens the spectrum of bicontinuous porous materials and opens a new route for synthesizing CMPs with new topologies.

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Source
http://dx.doi.org/10.1039/d3cc00481cDOI Listing

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