Restoring and protecting historic buildings worldwide are important because heritage buildings are records of the civilizations of various countries. Herein, nanotechnology was used to restore historic adobe walls. According to the Iran Patent and Trademark Office (IRPATENT) 102665, nanomontmorillonite clay has been selected as a natural and compatible material with adobe. Furthermore, it has been used as nanospray to be a minimally invasive method to fill cavities and cracks in the adobe surface. Various percentages of nanomontmorillonite clay (1-4%) in the ethanol solvent and the frequency of spraying on the wall surface were evaluated. Scanning electron microscopy and atomic force microscopy images, porosity tests, water capillary absorption, and compressive strength tests were used to evaluate the efficiency of the method, analyze cavity filling, and detect the optimal percentage of nanomontmorillonite clay. Results indicate that the double use of the 1% nanomontmorillonite clay solution exhibited the best results, filled the cavities, and reduced the pores on the surface of the adobe, increasing compressive strength and reducing water absorption and hydraulic conductivity. The use of a more dilute solution causes the nanomontmorillonite clay to penetrate deeply into the wall. This innovative method can help mitigate the existing disadvantages of historic adobe walls.
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http://dx.doi.org/10.1021/acsomega.3c00124 | DOI Listing |
Front Chem
August 2024
Department of Biology, College of Science, Imam Mohammad Ibn Saud Islamic University (IMSIU), Riyadh, Saudi Arabia.
Uncontrolled or improperly managed wastewater is considered toxic and dangerous to plants, animals, and people, as well as negatively impacting the ecosystem. In this research, the use of we aimed to prepare polymer nanocomposites (guar gum/polyvinyl alcohol, and nano-montmorillonite clay) for eliminating heavy metals from water-based systems, especially Cu and Cd ions. The synthesis of nanocomposites was done by the green method with different ratios of guar gum to PVA (50/50), (60/40), and (80/20) wt%, in addition to glycerol that acts as a cross-linker.
View Article and Find Full Text PDFPhys Chem Chem Phys
November 2023
Department of Physics and Astrophysics, University of North Dakota, Grand Forks, North Dakota 58202, USA.
We investigated the interaction between biomimetic Fe and Mg co-doped montmorillonite nanoclay and eleven unnatural amino acids. Employing three different functionals (PBE-GGA, PBE-GGA + U, and HSE06), we examined the clay's structural, electronic, and magnetic properties. Our results revealed the necessity of using PBE-GGA + U with ≥ 4 eV to accurately describe key clay properties.
View Article and Find Full Text PDFACS Omega
March 2023
Department of Geotechnical and Hydraulic Engineering, Faculty of Civil and Environmental Engineering, Gdansk University of Technology, Gdansk 80-233, Poland.
Restoring and protecting historic buildings worldwide are important because heritage buildings are records of the civilizations of various countries. Herein, nanotechnology was used to restore historic adobe walls. According to the Iran Patent and Trademark Office (IRPATENT) 102665, nanomontmorillonite clay has been selected as a natural and compatible material with adobe.
View Article and Find Full Text PDFAnimals (Basel)
October 2021
Animal and Fish Production Department, Faculty of Agriculture, Alexandria University, Alexandria 21545, Egypt.
Two types of modified nano-montmorillonite (MNM) were developed by ion-exchange reactions using two different surfactants; sodium dodecyl sulfate (SDS) and cetyltrimethylammonium bromide (CETAB), to prepare MNM and MNM, respectively. Both MNM types were on the nano-scale and had higher cation-exchange capacity values than NM clay. The MNM had the highest zeta potential (-27 mV) compared with the other clays.
View Article and Find Full Text PDFAnal Chim Acta
January 2013
Key Laboratory of Chemical Sensing & Analysis in Universities of Shandong, School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, China.
Nano-montmorillonites belong to aluminosilicate clay minerals with innocuity, high specific surface area, ion exchange, and favorable adsorption property. Due to the excellent properties, montmorillonites can be used as labels for the electrochemical immunosensors. In this study, nano-montmorillonites were converted to sodium montmorillonites (Na-Mont) and further utilized for the immobilization of thionine (TH), horseradish peroxidase (HRP) and the secondary anti-zeranol antibody (Ab(2)).
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