Development of composite optical waveguide based on azobenzene-modified titanium metal-organic framework film for study of gas adsorption kinetics.

This study investigates the fabrication and gas adsorption kinetics of an azobenzene (AZB)-modified titanium metal-organic framework (AZB@Ti-MOF) film composite optical waveguide (COWG) that recognizes ethylenediamine (EDA) gas. After modification with AZB, the surface of the Ti-MOF film became rough and evolved from a hemispherical structure to a petal-like structure; a large pore size and small specific surface area accompanied the evolution of the surface morphology. The AZB@Ti-MOF film COWG exhibited a positive response to EDA gas co-existing with the same concentration (1000 ppm) of benzenes, amines, and acidic gases. It is postulated that charge transfer occurs when the AZB@Ti-MOF film COWG adsorbs EDA gas, leading to significant strengthening of the intramolecular hydrogen bonds as EDA works as an electron donor. Incomplete or prolonged EDA desorption from the film surface at room temperature resulted in a decrease in the surface sensitivity of the COWG AZB@Ti-MOF film. The kinetics of EDA adsorption were examined using pseudo-first-order and pseudo-second-order (PSO) kinetic models. The EDA adsorption kinetics fit well with the PSO model. As measured at room temperature, the adsorption capacity (q) per unit surface of the AZB@Ti-MOF films was 46.50 × 10 µg·cm.