Using a practical GC-MS dataset containing approximately 4000 suspected arson cases, three machine-learning based classification models were developed and their performances were evaluated. All models trained for classifying the data from fire residue into six categories; no fire accelerants detected or else one of fire accelerants was used within gasoline, kerosene, diesel, solvents, or candle. The classification accuracies of the random forest, supporting vector machine, and convolutional neural network model were 0.88, 0.88, and 0.92, respectively. By calculating feature importance of the random forest model, several potential chemical fingerprints of fire accelerants were discovered.
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http://dx.doi.org/10.1016/j.forsciint.2023.111646 | DOI Listing |
Sci Justice
September 2024
Centre for Forensic Science, Department of Pure and Applied Chemistry, University of Strathclyde, 204 George Street, Glasgow G1 1XW, United Kingdom. Electronic address:
Previous literature has established that recovering heat damaged body fluids is possible, however with little investigation into the effect of accelerants used in initiating arson fires. This study therefore aimed to determine whether presumptive blood detection was affected by heat damage resulting from accelerant facilitated fires. Another objective was to examine various techniques for removing soot, which is a noted barrier to blood detection.
View Article and Find Full Text PDFForensic Sci Int
November 2024
Istanbul University - Cerrahpaşa Institute of Forensic Sciences and Legal Medicine Department of Science, Buyukcekmece, Istanbul 34500, Turkiye. Electronic address:
Detection of ignitable liquid residues in a fire scene is essential for determining the origin. Although studies are focused on the detection of residues of accelerants depending on time or matrices, the time-dependent effect of the water extinguishing method in a fire has not yet been investigated. Experimental studies are needed to determine how long ignitable liquid residues can be detected in water-extinguished evidence compared to the smothering method.
View Article and Find Full Text PDFClin Ter
July 2024
Section of Forensic Medicine, Department of Clinical and Experimental Medicine, University of Foggia, Foggia, Italy.
Background: Homicide by burning is rare, involving victims exposed to direct flames, often with accelerants. This demonstrates excessive force by the assaulter. A thorough investigation is vital as fire can conceal pathological findings.
View Article and Find Full Text PDFForensic Sci Int
August 2024
Research Center, China People's Police University, LangFang, China. Electronic address:
Species categorical authentication of accelerants has traditionally relied on fire debris analysis. To explore a novel method for identifying the accelerants species, four commonly used accelerants for arson were loaded onto different substrates and ignited at different locations. The entire combustion process was recorded and flame characteristics were analyzed.
View Article and Find Full Text PDFForensic Sci Int
August 2024
Jazz Pharma, Unit 840 Broadoak Rd, Sittingbourne ME9 8AG, United Kingdom.
In the forensic science context petrol is considered the most common fire accelerant. However, the identification and classification of petrol sources through the years has been proven to be a challenge in the investigation of fire related incidents. This research explored the possibility of identification and classification of petrol sources using high field NMR spectroscopy.
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