Boron carbon nitride (BCN) ternary compounds are attractive due to their wide applications in adsorption, catalysis, protective coatings, etc. A simple way is provided to synthesize BCN materials with multistage modulation of hydrophilic-hydrophobic properties. Hydrophilic BCN nanoparticles with a contact angle of 31° and nearly superhydrophobic BCN sheets with a contact angle of 145° are obtained. The participation of a CuO additive in the synthesis process has the role of tuning morphologies, components, and properties of BCN materials. The addition of CuO would improve the hydrophobicity of BCN due to its microstructure with enhanced surface roughness. The interaction between melamine and boric acid on the surface of CuO(111) is investigated by first-principles calculations based on density functional theory (DFT). The tuned BCN materials have different photoelectric properties also, and their performance as photocatalysts has been verified in photocatalytic reactions for hydrogen from water. The achieved uniform hydrophilic BCN nanoparticles and hydrophobic BCN sheets have the potential for further practical applications.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1021/acs.langmuir.3c00369 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Density Functional Theory Investigation of 2D Phase Separated Graphene/Hexagonal Boron Nitride Monolayers; Band Gap, Band Edge Positions, and Photo Activity.
J Phys Chem C Nanomater Interfaces
January 2025
Institute de Quimica Computacional i Catálisi, Universitat de Girona, Girona 17003 Spain.
Creating sustainable and stable semiconductors for energy conversion via catalysis, such as water splitting and carbon dioxide reduction, is a major challenge in modern materials chemistry, propelled by the limited and dwindling reserves of platinum group metals. Two-dimensional hexagonal borocarbonitride (h-BCN) is a metal-free alternative and ternary semiconductor, possessing tunable electronic properties between that of hexagonal boron nitride (h-BN) and graphene, and has attracted significant attention as a nonmetallic catalyst for a host of technologically relevant chemical reactions. Herein, we use density functional theory to investigate the stability and optoelectronic properties of phase-separated monolayer h-BCN structures, varying carbon concentration and domain size.
View Article and Find Full Text PDFTuning Electronic Structure and Optical Properties of Monolayered h-BN by Doping C, Cu and Al.
Molecules
January 2025
College of Metallurgy and Energy, North China University of Science and Technology, Tangshan 063210, China.
As a graphene-like material, h-BN has stimulated great research interest recently due to its potential application for next-generation electronic devices. Herein, a systematic theoretical investigation of electronic structures and optical properties of C-doped and Cu-Al co-doped h-BN is carried out by the first-principles calculations. Firstly, two different C-doped h-BN structures for the para-position and ortho-position are constructed.
View Article and Find Full Text PDFRetrospective Clinical Outcomes of Keratoplasty Using Human Donor Corneas Preserved in Eusol-C Hypothermic Storage Medium.
J Clin Med
December 2024
Ophthalmology Unit-Eye Bank of Rome, San Giovanni Addolorata Hospital, 00184 Rome, Italy.
To evaluate the clinical outcomes of cornea transplantation (penetrating keratoplasty, Descemet membrane endothelial keratoplasty, Descemet stripping automated endothelial keratoplasty, and deep anterior lamellar keratoplasty) using donor corneas stored in Eusol-C hypothermic storage medium compared to corneas stored in organ-culture. : The clinical outcomes of 92 patients who underwent corneal transplantation with human donor corneas stored in Eusol-C medium at 2-8 °C were retrospectively evaluated. The control group consisted of 169 patients who received corneas organ-cultured at 31 °C.
View Article and Find Full Text PDFUnravelling the potential of a hybrid borocarbonitride biphenylene 2D network for thermoelectric applications: a first principles study.
Nanoscale
January 2025
Department of Physics, Indian Institute of Technology Patna, Bihta, Bihar, 801106, India.
In this study, we investigate a novel hybrid borocarbonitride (bpn-BCN) 2D material inspired by recent advances in carbon biphenylene synthesis, using first-principles calculations and semi-classical Boltzmann transport theory. Our analysis confirms the structural stability of bpn-BCN through formation energy, elastic coefficients, phonon dispersion, and molecular dynamics simulations at 300 K and 800 K. The material exhibits an indirect band gap of 0.
View Article and Find Full Text PDFPhotothermal Self-Healing Black g-CN Nanosheet-Based Coatings: A Novel Approach for Enhanced Anticorrosion and Antibiofouling Protection.
Small
January 2025
School of Material Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang, Jiangsu, 212003, P. R. China.
Multifunctional coatings have great application value in the protection of Marine equipment, ships and ship facilities, but they still suffer from the disadvantages of high preparation cost and complicated synthesis methods. Herein, employing a simple method to synthesize black carbon nitride (BCN), as the filler in polydimethylsiloxane (PDMS) to construct BCN/PDMS composite coating with a multifunctional anti-corrosion/antifouling coating capable of photothermal self-healing property. Experimental results exhibit that the BCN/PDMS coating can still possesses excellent corrosion resistance after 28 d of immersion in the simulated seawater, and the impedance modulus still manages to reach 6.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!