Elastomeric bearings are widely used in bridges to support the superstructure, to transfer loads to substructures, and to accommodate movements induced by, for example, temperature changes. Bearing mechanical properties affect the bridge's performance and its response to permanent and variable loadings (e.g., traffic). This paper describes the research carried out at Strathclyde towards the development of smart elastomeric bearings that can be used as a low-cost sensing technology for bridge and/or weigh-in-motion monitoring. An experimental campaign was performed, under laboratory conditions, on various natural rubber (NR) specimens enhanced with different conductive fillers. Each specimen was characterized under loading conditions that replicated in-situ bearings to determine their mechanical and piezoresistive properties. Relatively simple models can be used to describe the relationship between rubber bearing resistivity and deformation changes. Gauge factors (s) in the range between 2 and 11 are obtained, depending on the compound and the applied loading. Experiments were also carried out to show that the developed model can be used to predict the state of deformation of the bearings under random loadings of different amplitudes that are characteristic of the passage of traffic over a bridge.
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http://dx.doi.org/10.3390/s23063150 | DOI Listing |
BMC Oral Health
June 2024
Faculty of Dentistry, Thammasat University, Pathum Thani, 12120, Thailand.
Background: Low mechanical properties are the main limitation of glass ionomer cements (GICs). The incorporation of elastomeric micelles is expected to enhance the strength of GICs without detrimentally affecting their physical properties and biocompatibility. This study compared the chemical and mechanical properties, as well as the cytotoxicity, of elastomeric micelles-containing glass ionomer cement (DeltaFil, DT) with commonly used materials, including EQUIA Forte Fil (EF), Fuji IX GP Extra (F9), and Ketac Molar (KT).
View Article and Find Full Text PDFAngew Chem Int Ed Engl
August 2024
School of Chemistry and Chemical Engineering, Center on Nanoenergy Research, School of Physical Science and Technology, Guangxi University, Nanning, 530004, China.
Elastomeric solid polymer electrolytes (SPEs) are highly promising to address the solid-solid-interface issues of solid-state lithium metal batteries (LMBs), but compromises have to be made to balance the intrinsic trade-offs among their conductive, resilient and recyclable properties. Here, we propose a dual-bond crosslinking strategy for SPEs to realize simultaneously high ionic conductivity, elastic resilience and recyclability. An elastomeric SPE is therefore designed with hemiaminal dynamic covalent networks and Li-dissociation co-polymer chains, where the -C-N- bond maintains the load-bearing covalent network under stress but is chemically reversible through a non-spontaneous reaction, the weaker intramolecular hydrogen bond is mechanically reversible, and the soft chains endow the rapid ion conduction.
View Article and Find Full Text PDFMolecules
February 2024
Department of Chemistry, Materials and Chemical Engineering "G. Natta", Politecnico di Milano, Via Mancinelli 7, 20131 Milano, Italy.
A one-pot, two-step process was developed for the preparation of pyrrole compounds from 2,5-dimethylfuran. The first step was the acid-catalyzed ring-opening reaction of 2,5-dimethylfuran (DF), leading to the formation of 2,5-hexanedione (HD). A stoichiometric amount of water and a sub-stoichiometric amount of sulfuric acid were used by heating at 50 °C for 24 h.
View Article and Find Full Text PDFPolymers (Basel)
November 2023
Department of Chemical Engineering, Daegu University, Gyeongsan 712-714, Republic of Korea.
A series of robust energetic polyurethane binders was developed by in situ grafting reactive spiranes to achieve the migration-resistant processing aid and compensate for the energy output. The reactive grafting spiranes (RGSs), bearing two highly ring-strained spiranes, were synthesized sequentially to provide a promising ring strain energy up to a maximum value of 290 kJ mol. The thermodynamic compatibility of the RGS with uncured glycidyl azido polymer (GAP) was studied quantitatively by analyzing the glass transition temperature of their blendings.
View Article and Find Full Text PDFPolymers (Basel)
November 2023
Institute of Technology, University of Tartu, Nooruse 1, 50411 Tartu, Estonia.
Water, alcohols, diols, and glycerol are low-cost blowing agents that can be used to create the desired silicone foam structures. Although their combined use can be beneficial, it remains unclear how it affects the physical properties of the resulting materials. We conducted a comparative study of these hydroxyl-bearing blowing agents in fumed silica- and mica-filled polymer composite systems for simultaneous blowing and crosslinking to obtain a low-density, uniform porosity and superior mechanical properties.
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