AI Article Synopsis
- Interest in gold-catalysed reactions has surged over the past 20 years due to their versatility and ability to activate various unsaturated groups.
- This review highlights gold-catalysed cycloisomerisation reactions of ynamides, diynes, and 1-enynes, which allow for the synthesis of complex polycyclic compounds in a single step.
- These reactions are particularly useful for creating various unique structures, such as fused spiro carbocycles and other complex ring systems.
Article Abstract
In the last two decades, interest in reactions catalysed by gold complexes has tremendously increased due to their ability to tolerate a variety of functional groups and their capability to activate various unsaturated groups. In this review, gold-catalysed cycloisomerisation reactions of ynamides, diynes and 1,-enynes have been summarized. These gold-catalysed cycloisomerisation reactions open new opportunities for synthesising a range of new complex polycyclic chemical moieties in one step. Gold-catalysed cycloisomerisation is a valuable way for synthesising fused spiro carbocycles, BODIPY cores, bicyclo[3.2.1]oct-2-ene, dihydro benzo[]thiepine, disubstituted furans, spiroindolines, bridged [.2.1] skeletons, .
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| http://dx.doi.org/10.1039/d2ob02015g | DOI Listing |
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