A luminescent three-dimensional coordination polymer (CP) of [Cd(pmd){Ag(CN)}] (1; pmd = pyrimidine) comprising two different coordination modes of Ag ions was synthesised herein. 1 exhibited thermochromic luminescence, accompanied by positive thermal elongation of the Ag⋯Ag distance. Moreover, 1 showed a bright phosphorescence with the highest photoluminescence quantum yield (), approximately 60% at room temperature, among previously reported phosphorescent Ag-based CPs or metal-organic frameworks.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/d3cc00179b | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
The development of materials from renewable resources has been increasing, intending to reduce the consumption of fossil sources, with terpenes being one of the main families that reduce the consumption of isoprene. The study of the binary catalytic system neodymium versatate/dibutyl magnesium (NdV/Mg(-Bu)), for the coordination homopolymerization of β-myrcene and β-farnesene, was carried out analysing different [Nd] : [Mg] ratios (between 4 and 10). Reporting conversions of 92% and 83% at an [Nd] : [Mg] ratio of 8 for polymyrcene (PMy) and polyfarnesene (PFa), respectively, and microstructures comprising 1,4 content above 80% for both polymers (PMy, -59% and PFa, -83%).
View Article and Find Full Text PDFConformation Regulation of Perylene Diimide Derivatives by Lanthanide Coordination for Turn-On Fluorescence Sensing of Sarin Simulants.
Inorg Chem
January 2025
Key Laboratory of Applied Surface and Colloid Chemistry (MOE), School of Chemistry & Chemical Engineering, Shaanxi Normal University, Xi'an, Shaanxi 710062, China.
Fluorescent metal-organic frameworks (MOFs) are promising sensing materials that have received much attention in recent years, in which the organic ligand conformation changes usually lead to variations of their sensing behavior. Based on this, in the present work, perylene diimide (PDI) derivatives with excellent photochemical properties closely related to their conformation and molecule packing fashion were selected as organic linkers to detect sarin simulant diethyl chlorophosphate (DCP). By the coordination interactions with large lanthanide cations through terminal carboxylate groups from the PDI derivative, a series of one-dimensional coordination polymers, named [Ln(PDICl-2COO)(μ-O)(DMF)] (SNNU-112, Ln = Yb/Tb/Sm/Nd/Pr/Gd/Eu/Er/Ce, PDICl-2COOH = ,'-bis(4-benzoic acid)-1,2,6,7-tetrachlorohydrazone-3,4,9,10-tetracarboxylic acid diimide) were synthesized.
View Article and Find Full Text PDFAntimonotungstate-Based Heterometallic Framework Formed by the Synergistic Strategy of In Situ-Generated Krebs-Type Building Units and the Substitution Reaction and Its High-Efficiency Biosensing KRAS Gene.
Inorg Chem
January 2025
MOE Key Laboratory of Cluster Science, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 102488, China.
A novel antimonotungstate (AT)-based heterometallic framework {[Er(HO)][Fe(Hpdc)(B-β-SbWO)]}·50HO (, Hpdc = pyridine-2,5-dicarboxylic acid) was obtained through a synergistic strategy of in situ-generated transition-metal-encapsulated polyoxometalate (POM) building units and the substitution reaction. Its structural unit is composed of a tetra-Fe-substituted Krebs-type [Fe(Hpdc)(B-β-SbWO)] subunit and two [Er(HO)] cations. This subunit can be regarded as a product of carboxylic oxygen atoms of Hpdc ligands replacing active water ligands in the [Fe(HO)(B-β-SbWO)] species.
View Article and Find Full Text PDFHigh-Efficiency Intrinsically Thermoplastic Semiconducting Polymer with Excellent Strain-Tolerance Capacity for Flexible Ultra-Deep-Blue Polymer Light-Emitting Diodes.
Adv Mater
January 2025
The Institute of Flexible Electronics (IFE Future Technologies), Xiamen University, 422 Siming South Road, Xiamen, 361005, China.
Complex internal stresses that appear in flexible thin-film electronic devices under long-term deformation operation are associated with incompatible mechanical properties of the multiple layers, which potentially cause intralayer fracture and separation. These defects may result in device instability, performance loss, and failure. Herein, a thermoplastic functional strategy is proposed for manufacturing high-performance stretchable semiconducting polymers with excellent strain-tolerance capacities for flexible electronic devices.
View Article and Find Full Text PDFOptimizing the Coordination Energy of Co-N Sites by Co Nanoparticles Integrated with Fe-NCNTs for Boosting PEMFC and Zn-Air Battery Performance.
Small
January 2025
School of Materials Science and Engineering, Tianjin Key Laboratory of Composite and Functional Materials Key Laboratory of Advanced Ceramics and Machining Technology (Ministry of Education), Tianjin University, Tianjin, 300072, China.
Enhancing the catalytic performance and durability of M-N─C catalyst is crucial for the efficient operation of proton exchange membrane fuel cells (PEMFCs) and Zn-Air batteries (ZABs). Herein, an approach is developed for the in situ fabrication of a MOFs-derived porous carbon material, co-loaded with Co nanoparticles (NPs) and Co-N sites and integrated onto Fe-doped carbon nanotubes (CNTs), named Co-NC/Fe-NCNTs. Incorporating polymer-wrapped CNTs improves MOFs dispersion annealing at high temperature, which amplifies the three-phase boundary (TPB) by generating much more mesopores and exposing additional active sites within the catalysts layer.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!