AI Article Synopsis
- Transition metal di-chalcogenides (TMCDs), particularly tungsten disulfide (WS), are explored for their great optoelectronic properties that make them suitable as photovoltaic materials in thin-film solar cells.
- Researchers have replaced the traditional buffer and window layers in CdTe solar cells with non-toxic WS and SnO, using the SCAPS-1D solar simulator to assess their performance compared to standard structures.
- The study reveals that while the proposed WS-based solar cell achieves a conversion efficiency of 20.55%, it suffers from structural robustness and thermal stability issues, suggesting avenues for developing environmentally friendly and cost-effective solar cell technologies.
Article Abstract
Transition metal di-chalcogenides (TMCDs)-Tungsten disulfide (WS) exhibit excellent optoelectronic properties such as suitable bandgap, high absorption coefficient, good conductivity, high carrier mobility, etc. to be used as a photovoltaic material for thin-film solar cells. In the present work, we have replaced the traditional buffer CdS and ITO/ZnO window layer in CdTe solar cells with the non-toxic, earth-abundant WS buffer and SnO window layer, respectively. The SCAPS-1D solar simulator is used to investigate the potentiality of WS as buffer material in CdTe solar cells. This numerical study provides a comparison of the performances between the proposed structure: SnO/WS/CdTe/Au and the baseline structure: ITO/ZnO/CdS/CdTe/Au. The impacts of the charge carrier generation rate, spectral response, current-voltage characteristics, bulk defect density, defect density at buffer/absorber interface, operating temperature, and capacitance-voltage characteristics on the solar cell performance parameters have also been analyzed. The tolerance level of defect density in WS bulk and WS/CdTe interface are found to be 10 cm and 10 cm, respectively. The temperature study reveals the poor structural robustness and thermal stability of the proposed cell. The conversion efficiency of the proposed cell has found to be 20.55% at the optimized device structure. Nevertheles, these findings may provide an insight to fabricate viable, environment friendly, and inexpensive CdTe thin-film solar cells.
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|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC10025914 | PMC |
| http://dx.doi.org/10.1016/j.heliyon.2023.e14438 | DOI Listing |
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