Development of a high-rate-capable O3-structured 'layered' Na transition metal oxide by tuning the cation-oxygen bond covalency.

Chem Commun (Camb)

Advanced Batteries and Ceramics Laboratory, Department of Metallurgical Engineering and Materials Science, Indian Institute of Technology Bombay, Mumbai 400076, India.

Published: April 2023

AI Article Synopsis

  • Developed a new O3-structured Na(LiNiSiTiCuMg)O-based cathode for Na-ion batteries to improve efficiency.
  • Substituted Si for Ti in the metal layer, which altered the properties of the Na-O bond and made it weaker and longer.
  • Increased 'inter-slab' spacing boosts the movement of sodium ions, improving transport kinetics for better battery performance.

Article Abstract

By developing a high-rate-capable O3-structured Na(LiNiSiTiCuMg)O-based cathode material for Na-ion batteries, wherein partial substitution of more electronegative Si for Ti in the transition metal layer has weakened-cum-lengthened the Na-O bond, enlarged the 'inter-slab' spacing and, thus, enhanced the Na-transport kinetics, a design criterion has been laid-out in the above context.

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Source
http://dx.doi.org/10.1039/d3cc00079fDOI Listing

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Development of a high-rate-capable O3-structured 'layered' Na transition metal oxide by tuning the cation-oxygen bond covalency.

Chem Commun (Camb)

April 2023

Advanced Batteries and Ceramics Laboratory, Department of Metallurgical Engineering and Materials Science, Indian Institute of Technology Bombay, Mumbai 400076, India.

Article Synopsis
  • Developed a new O3-structured Na(LiNiSiTiCuMg)O-based cathode for Na-ion batteries to improve efficiency.
  • Substituted Si for Ti in the metal layer, which altered the properties of the Na-O bond and made it weaker and longer.
  • Increased 'inter-slab' spacing boosts the movement of sodium ions, improving transport kinetics for better battery performance.
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